International Nuclear Information System (INIS)

This study started with a comprehensive and critical review of the published information of relevance to the different methods to produce uranium dioxide from raw materials. we have chosen this method 'flame denitration' or flame process to produce Uo_2. from its compounds, uranyl nitrate Uo_2 ( NO_3) _2 .6H_2o) prepared from raw uranium 'yellow cake'. This method in short produces uranium dioxide from aqueous uranyl nitrate by contacting the atomized liquid which has 40 #mu# in diameter with hot reducing gases (butane and oxygen mixture) till we obtain a suitable and yellow red colour light for the flame and this is a prof that there is carbon monoxide and hydrogen, the temperature of the reactor at is least 950 degree C.

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2,6-Dinitrotoluene (2,6-DNT) and pentachlorophenol (PCP) are used for industrial purposes and are found in the environment as hazardous contaminants. Because concurrent exposure to both compounds can occur, it is of interest to determine if organochlorine compounds potentiate the effect of nitroaromatic chemicals. A significant increase in mutagenicity was observed in urines from mice treated with 2,6-DNT alone and in combination with PCP. By week 4, mice that received both 2,6-DNT and PCP excreted urine that was more mutagenic than that from animals which received only 2,6-DNT. At weeks 2 and 4, mice were sacrificed and intestinal enzyme activities (nitroreductase, azo reductase, {beta}-glucuronidase, dechlorinase, and dehydrochlorinase) were quantitated. The enhanced genotoxicity observed in urines from ...

International Nuclear Information System (INIS)

... odd nuclei organic compounds radiation effects radioisotopes synthesis

International Nuclear Information System (INIS)

... compounds plants radiation effects radioisotopes reaction kinetics trees

International Nuclear Information System (INIS)

Luminescence and reflection spectra as well as luminescence kinetics of the 1 mol% Sm3+-doped crystalline lanthanum magnesium meta borate (LaMgB5O10) and gadolinium magnesium meta borate (GdMgB5O10) were analyzed. Materials were synthesized by conventional solid state route and showed bright orange-red emission under UV excitation. Emission spectra contain sharp and well resolved Sm3+4G5/2#->#6HJ transitions indicating a strong crystal-field effect. In case of gadolinium compound energy transfer between Gd3+ and Sm3+ was detected. The luminescent kinetics of the Sm3+ in analyzed powders is characterized by single exponential decay and experimental values vary in the range 2.2-2.4 ms. - Research highlights: ? Phosphorescence of samarium-doped lanthanide magnesium meta borates. ? Bright and well resolved orange-red emission of Sm3+ under UV excitation. ? Energy transfer from Gd3+ to Sm3+ in gadolinium magnesium meta borate ...

British Library Electronic Table of Contents (United Kingdom)

2,6-Diacetyl pyridine based ligand was synthesized by the reaction of 2,6-diacetyl pyridine with thiocarbohydrazide in presence of acetic acid. The coordination compounds with Cr(III) and Ni(II) metal ions having [Cr(L)X]X2 and [Ni(L)X]X compositions (where L=ligand and X=NO3^-, Cl^- and CH3COO^-) were synthesized and characterized by physicochemical and spectral studies. The studies like elemental analyses, molar conductance measurements, magnetic susceptibility measurements, IR, UV-Vis, NMR, mass and EPR reveal that the complexes are octahedral. The compounds were examined against the pathogenic fungal and bacterial strains like Alternaria brassicae, Aspergillus niger, Fusarium oxysporum, Xanthomonas compestris and Pseudomonas aeruginosa. A. niger causes the diseases Apergillosis and Oto...

International Nuclear Information System (INIS)

Superconductivity in A-15 compounds is examined in terms of electron pairing induced by exchange of acoustic plasmons. The electronic band structure of Nb_3Sn, V_3Si, and similar materials favor transition temperatures of Tsub(c)approximately20 K. (Auth.).

British Library Electronic Table of Contents (United Kingdom)

Metalloid cluster compounds of group 14 of the general formulae EnRm with n > m (E = Si, Ge, Sn, Pb; R = ligand), where naked as well as ligand bound tetrel atoms are present, represent a novel class of cluster compounds in group 14 chemistry and can be seen as intermediates on the way to the elemental state. Therefore, interesting properties are expected for these compounds, which might complement results from nanotechnology. In this article, first results for germanium are discussed, together with novel build-up reactions on the way to novel materials based on metalloid cluster compounds. GRAPHICAL ABSTRACT[image omitted

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Analytical procedures are described for the determination of organic compounds, metals and radioisotopes in environmental materials, human tissues, urine, feces, and waste water.

International Nuclear Information System (INIS)

The influence of irradiation with 2.6 MeV H and He nuclei on the superconducting properties (critical temperature Tsub(c), critical current Isub(c)) of the intermetallic compound Nb_3Sn was studied. Irradiation led to a significant lowering of Tsub(c), while Isub(c) is increasing with the radiation dose. This is assumed to be due to the formation of active pinning centres in the lattice. There is a fast drop of Isub(c) after a peak value has been reached. Annealing of the samples (600-1,000"0C) led to an almost complete recovery of the initial value of Tsub(c). X-ray diffraction showed that irradiation causes considerable distortions of the lattice while the A15 crystal structure is retained. The causes of the radiation effects related to structural defects are discussed. (GSCH).

International Nuclear Information System (INIS)

Measurements are presented of indoor radon levels made in a prototype house constructed partly of bauxite waste (red mud) and partly of conventional materials. The mud used contains higher than the average amounts of "2"2"6Ra and "2"3"2Th found in local building materials. The rates of exhalation of radon from the material used in the construction of the house are measured and employed with measured air change rates to make estimates of the average contribution of the various materials to the measured radon levels indoors. There is fairly good agreement between the two. The increment of radon related dose equivalents above background are also estimated and these are combined with previously determined gamma dose equivalents and used as a basis for assessing the acceptability of the practice of using red mud as a building material. (author)

Science.gov (United States)

Partial Contents: Ternary Compounds; Granular Superconductors; Superconductivity in (SN)x and its Halogen Derivative (SNBr0.4)x; Studies of cuCl at Elevated Pressures; Superconducting Properties of Hydride Systems; Thin Film Superconducting Materials Research; Synthesis of Superconducting Nb3Si using High Pressures; Synthesis of Unstable A-15 Compounds by Epitaxial Recrystallization of Ion Implanted Layers; and Sputtering of Nb3Si.

International Nuclear Information System (INIS)

A nation-wide survey of natural radioactivity in building materials was conducted during 1982-1984. Samples including industrial wastes, by-products and common building materials were collected from main building material manufactories in 29 provinces except Taiwan. The results of exposure rates, specific activities and release rate for "2"2"2Rn are presented. The specific activities of common materials are listed in declining order as follows: clay bricks > common concrete and sandstones > limes and ordinary cement. The highest level was found in breeze bricks made of stone coal, phosphogypsum and red mud with high intrinsic radioactivity. Therefore, these raw materials should be strictly controlled in manufacturing building materials. The measurement results also showed that the typical specific activities of common building ...

Energy Technology Data Exchange (ETDEWEB)

Cathode materials for rechargeable rocking chair or lithium-ion batteries, are reviewed. The emphasis is placed on the comparison between specific capacities and rechargeability of lithium-containing high voltage cathode materials such as manganese oxides and LiMO{sub 2} compounds, where M is Co or Ni. It is generally found that the maximum reversible capacities for the most promising materials fall in the range 100-120 mAh/g, and decaying to around 75 mAh/g after several hundred cycles. The rechargeability is similar for the most commonly considered materials: LiMn{sub 2}O{sub 4}, LiCoO{sub 2} and LiNiO{sub 2}. No improvements in capacity or rechargeability, beyond what have been found for these materials, is observed by substitution of other elements into these compounds

International Nuclear Information System (INIS)

The aim of this work is to describe the processes during plasma nitriding of Nb-containing, powder metallurgy prepared (PM) tool steel. PM steel was studied containing 2.5% C, 3.3% Si, 6.2% Cr, 2.2% Mo, 2.6% V, 2.6% Nb and 1.0% W, produced by melt atomization and hot isostatic pressing. The hardened and tempered steel was plasma nitrided at temperatures ranging from 470 to 530 deg. C. The nitriding time was 30-180 min. Optical microscopy, electron microscopy, XRD, EDS, WDS and hardness measurements were used to study the steel's properties, microstructure, phases and chemical composition. The nitriding temperature of 470 deg. C was found to be unsuitable for practical use because the layers prepared at this temperature were non-uniform. The compound layer formed by M_2_,_3(C,N) and M_4N was found after nitriding at temperatures of 500 and 530 deg. C for at least 60 min. The effect of niobium on the formation of this layer ...

International Nuclear Information System (INIS)

The paramagnetic susceptibilities of all the RCo_2 compounds for which measurements are available are found to obey a Curie-Weiss law consistent with the modified indirect exchange model. The rare-earth ions are in a well defined tripositive valence state. Paramagnetic moments and paramagnetic Curie temperatures are obtained for these materials for the first time. The paramagnetic moments of these materials are changed from their free-ion values by the effects of itinerant electron polarisation, an effect which is particularly large for SmCo_2 whose paramagnetic moment is almost three times greater than the free-ion value. The modified indirect exchange model is found to be able to give a full description of the magnitude of the rare-earth, cobalt and diffuse moments in polarised neutron experiments. The band structures of the light RCo_2 compounds are found to be distinctly different to those of the ...

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Red mud is a waste product of the aluminium refining industry. It is composed of aluminium hydroxide and iron oxide. This study examined the feasibility of using red mud as a catalyst to eliminate volatile organic compounds in atmospheric pollutants. Volatile organic compounds can be eliminated by thermal oxidation between 600 and 1100 degrees C. However, the oxidation of volatile organic compounds can also be accomplished at lower temperatures (200 to 450 degrees C) if a catalyst is present. Currently, the low temperature destruction of volatile organic compounds is not widespread because of the difficulty in deactivating the catalyst. In this study, red mud was calcined in air at 500 degrees C. Under such conditions, the red mud converts to aluminium oxide and iron oxide. These 2 oxides are active and are carbon dioxide selective in the oxidation of volatile organic compounds. The ...

International Nuclear Information System (INIS)

The proceedings of these seminars form an impressive chronicle of the continued progress in the understanding of refractory metals and cemented carbides and in their manufacture and application. The 15"t"h Plansee Seminar was convened under the general theme 'Powder Metallurgy High Performance Materials'. Under this broadened perspective the seminar will strive to look beyond the refractory metals and cemented carbides, which remain at its focus, to novel classes of materials, such as intermetallic compounds, with potential for high temperature applications. (boteke)

International Nuclear Information System (INIS)

Structural instabilities are now being found in many high-temperature superconductors. Compounds with the A-15 (#beta#-W) structure comprise the most important group of these materials, and their properties have been extensively studied for over 15 years. A review is given of some of these results, particularly those relating to the elastic behavior. The empirical relation of the structural instability and the anharmonicity to the high superconducting transition temperature is discussed.

International Nuclear Information System (INIS)

Germanium coordination compounds (GCC) with oxiethilidendyphosphonic acid (Ge-Oedph) film structures electrophysical, optical, structural and adsorptive properties investigation results are represented. This structure concerns to a new perspective class of functional materials. The mechanism GCC films electric conductivity is investigated and explained. GCC possible application fields are specified.

UK PubMed Central (United Kingdom)

Alternative energy resources such as hydrogen and methane gases are becoming increasingly important for the future economy. A major challenge for using hydrogen is to develop suitable materials to store...Full Text Available

International Nuclear Information System (INIS)

The critical superconducting paramters of A-15 compounds are reviewed, and the trends analysed in order to predict maximum values. Experimental data on critical temperature is summarized and compared with theory. The ability to form the stoichiometric, well-ordered materials required for maximum Tsub(c) is discussed in terms of the thermodynamic stability of the A-15 phase. It is concluded that critical temperatures in excess of 25 K, in the A-15 structure, are unlikely. The upper critical field data show that, whereas the vanadium-based compounds are paramagnetically limited, the niobium-based compounds are not. The relation between critical current and microstructure is explored. Best data on critical current densities and ac losses is presented. Finally an account is given of the various methods by which actual conductors, both tapes and multifilamentary wires, are made. (author).

British Library Electronic Table of Contents (United Kingdom)

Many important advances in the physics of strongly correlated electron systems have been driven by the development of new materials: for instance the filled skutterudites Formula Not Shown ( Formula Not Shown metal, alkaline earth, lanthanide, or actinide; Formula Not Shown , Ru, or Os; Formula Not Shown , As, or Sb), certain lanthanide and actinide intermetallic compounds such as Formula Not Shown and Formula Not Shown ( Formula Not Shown , Rh, or Ir), and layered oxypnictides and related materials. These types of complex multinary d- and f-electron compounds have proven to be a vast reservoir of novel strongly correlated electron ground states and phenomena. In these materials, the occurrence of such a wide range of ground states and phenomena arises from a delicate interplay between com...

International Nuclear Information System (INIS)

The problem of search for new materials for spectrally positioned laser sources, which is central for modern photonics, is discussed. The use of the stimulated Raman scattering effect in crystals offers a highly efficient way to the design of such sources. The recent results of investigations into this effect for a large number of various types of crystalline materials are presented. The most promising compounds, as regards the realisation of different laser operation modes, are considered, including calcium, strontium, barium and lead molybdates and tungstates. Several examples of functioning efficient lasers based on novel materials exhibiting the stimulated Raman light scattering effect are given.

International Nuclear Information System (INIS)

Many important advances in the physics of strongly correlated electron systems have been driven by the development of new materials: for instance the filled skutterudites MT4X12 (M=alkali metal, alkaline earth, lanthanide, or actinide; T=Fe, Ru, or Os; X=P, As, or Sb), certain lanthanide and actinide intermetallic compounds such as URu2-xRexSi2 and CeTIn5 (T=Co, Rh, or Ir), and layered oxypnictides and related materials. These types of complex multinary d- and f-electron compounds have proven to be a vast reservoir of novel strongly correlated electron ground states and phenomena. In these materials, the occurrence of such a wide range of ground states and phenomena arises from a delicate interplay between competing interactions that can be tuned by partial or complete substitution of one element for another, as well as the application of pressure, and magnetic fields, resulting in ...

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Titanium and aluminum alkoxide derivatives with polymerizable ligands such as 2-(methacryloyloxy)ethylacetoacetate (HAAEMA), oleic acid and geraniol (HOGE) have been obtained. The various compounds have been characterized by FT-IR and NMR {sup 1}H. Copolymerization with styrene and divinylbenzene affords porous doped organic materials which have been characterized by scanning electron microscopy (SEM), elemental analysis, density measurements.

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This experiment is carried out in the series of the investigation on the damage mechanism of carbon steel. In this paper, the damage situation is considered by structure observations. The test were carried out in 600degC-1200degC temperature range, in blowing an argon gas. The reagents are Na{sub 2}O, Na{sub 2}O{sub 2} and NaOH. From structure observations, the holes are observed on the surface of iron-base material in some test conditions. This result is indicated that the selective reaction occurs. The selective reaction is more obvious as the time exposed to the high temperature is longer. It is considered that the selective reaction occurs after the chemical reaction between iron-base material and sodium compound. The areas, in which Mn-concentration is higher, are observed in products on the surface of specimen. (author)

International Nuclear Information System (INIS)

The purpose of the present study is to develop a new method for chemical state analysis by means of EPMA(Electron probe microanalyser). The measured X-ray intensity of Si-K#beta# characteristic X-ray spectra were read-out by a 16 bit microcomputer with a RS-232C interface. And using the curve fitting method the quantitative analysis of chemical compositions in a ternary compound that constituted of the same element has been established. The present method was applied to analyse of the friction and wear properties of Si-base ceramics sliding materials. It was found that the wear debris contains both the compositions of the sliding materials and SiO_2, and the SiO_2 contents in wear debris was changed with relative humidity. The results clearly showed that the proposed method is very useful for determing the compositions in the ternary compound. (author).

Science.gov (United States)

... 2.5.6 Development of Observation Equations . . . . . 25 2.6 Inertial Navigation Error Model . . . . . ... 2 , as expected. 2.6 Inertial Navigation Error Model ...

International Nuclear Information System (INIS)

The effects of neutron irradiation on the superconducting and normal state properties of alloys and compounds are presented. Particular emphasis is placed on the A-15 compounds where the effects of neutron irradiation on Tsub(c), Hsub(c_2), long range order parameter and lattice parameter are described. Large depressions (up to 80%) in Tsub(c) are observed for all the A-15 compounds studied with the exception of Mo_3Os where much smaller decreases in Tsub(c) are seen. Along with the decrease in Tsub(c) and increase in lattice parameter, the degree of long range order, as measured by X-ray and neutron diffraction, decreases. Also presented are the results of isothermal and isochronal anneals up to 900"0C. The unirradiated value of Tsub(c) can be restored by annealing, and for those systems where measurements have been made, recovery of the lattice parameter and order parameter also takes place. The effects observed in ...

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An experimental investigation was conducted to evaluate the effect of three different oxygenated compounds, diglyme, diethyl maleate and dibutyl maleate, on emissions from a Volkswagen 1.9 litre, turbocharged, direct injection diesel engine. Sampling was performed using a mini-dilution tunnel technique to obtain particulate matter and a Fourier transform infrared (FTIR) spectrometer for gaseous emissions. The particulate samples were analysed using thermal analysis and Soxhlet extraction to determine the fraction of volatile and soluble organic material respectively. All three oxygenated compounds were found to be effective at reducing particulate emissions, with the maleate compounds being more effective overall than the diglyme. Analysis of the relative contributions of changes in the soot and soluble organic fraction (SOF) to the reduction of particulate matter indicated that, for diethyl maleate and ...

Energy Technology Data Exchange (ETDEWEB)

The production of many important commercial materials involves the evolution of a complex fluid through a cooling phase into a hardened product. Textile fibers, high-strength fibers(KEVLAR, VECTRAN), plastics, chopped-fiber compounds, and fiber optical cable are such materials. Industry desires to replace experiments with on-line, real time models of these processes. Solutions to the problems are not just a matter of technology transfer, but require a fundamental description and simulation of the processes. Goals of the project are to develop models that can be used to optimize macroscopic properties of the solid product, to identify sources of undesirable defects, and to seek boundary-temperature and flow-and-material controls to optimize desired properties.

Science.gov (United States)

A process is provided for conducting organic compound conversion over a catalyst composition comprising a specially treated crystalline zeolite having a high initial silica-to-alumina mole ratio, said zeolite having been synthesized from a reaction mixture comprising a diamine as a cation source. The treatment of the zeolite material comprises the sequential steps of reacting the zeolite with a dilute hydrogen fluoride solution, contacting the hydrogen fluoride solution reacted material with aluminum chloride vapor, and then treating the aluminum chloride contacted material to convert it to hydrogen form.

International Nuclear Information System (INIS)

It is pointed out that a recently claimed result regarding the removal of sharp structure in the electronic density of states N(E) of A-15 superconducting compounds at T approximately equal to Tsub(c) was in fact, shown earlier by one of the present authors (M.N.M.). Merely the variation of N(E) with energy in the vicinity of the Fermi level in these materials cannot explain their anomalous normal state properties and high values of lambda and Tsub(c). Rather a non-varying N(E) accompanied by phonon softening is in better agreement with experiment. (author).

Energy Technology Data Exchange (ETDEWEB)

The authors present the results of their investigation of the effect of phosphorus compounds on the activity of tungsten-containing catalysts in the oxidation of ethane. They investigated tungsten-phosphorus catalysts with different phosphorus concentrations (calculated on the basis of P/sub 2/O/sub 5/). The catalysts were prepared by heat decomposition of the starting compounds at 750/sup 0/C for 4 h. As their starting compounds, they used two types of materials: heteropoly acids mixtures of monosubstituted ammonium phosphoric and tungstic acids. The specific surface area of the catalysts was determined using the nitrogen desorption method. The x-ray phase analysis was carried out using a DRON-1.5 diffractometer. The catalytic activity was determined using the impulse method in a reactor with a vibrofluidized catalyst layer.

International Nuclear Information System (INIS)

It has recently been shown that the superconducting properties of Nb-base A-15 compounds, A_3B, are severely degraded when exposed to high-energy (E>1 MeV) neutron irradiation at ambient reactor temperatures. In each case, superconducting transition temperatures, Tsub(c), and the Bragg Williams order parameters, S, were observed to decrease steadily with irradiations in excess of 10"1"8 nvt. During irradiation the A-15 structure is retained and subsequent isothermal annealing restores almost completely the compound's original Tsub(c) value. In this letter a correlation between B atom diameter and the recovery rates of Tsub(c) for the irradiated materials Nb_3Ge, Nb_3Ga, Nb_3Al and Nb_3Sn is reported. (Auth.).

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An ever first attempt has been made to investigate the possible anode performance characteristics of LiFePO{sub 4}, popularly known so far as an environmentally compatible and economically viable lithium battery cathode material. The compound LiFePO{sub 4} has been synthesized via solid state method and explored for the first time as an anode material against lithium metal through the present study. Surprisingly, an initial capacity of circa 620 mAh/g has been exhibited by LiFePO{sub 4} anode, which is about 4-5 times higher than the capacity of the corresponding LiFePO{sub 4} cathodes. Also an excellent coulombic efficiency value of 99% has been shown by the compound, especially upon extended cycling. The extraordinarily higher specific capacity values of LiFePO{sub 4} anodes may be exploited suitably for practical lithium battery applications.

International Nuclear Information System (INIS)

Uranium and thorium ores are the source of natural radionuclides. Briefly described are the original and current methods of long-lived nuclide separation ("2"3"8U, "2"3"5U, "2"2"6Ra, "2"3"0Th, "2"3"1Pa, "2"2"7Ac, "2"3"2Th, "2"2"8Ra+"2"2"8Ac, "2"2"8Th), some short-lived nuclides ("2"3"4Th and "2"2"8Ac), radon, short-lived radon daughter products and long-lived radon daughter products ("2"1"0Pb, "2"1"0Bi, "2"1"0Po). Some nuclides, such as "2"1"0Po or "2"3"1Pa can more easily be producedin reactors. (Ha).

Energy Technology Data Exchange (ETDEWEB)

The electrochemical performances of orthorhombic LiMnO{sub 2} compounds are analyzed in order to find a structural and/or morphological origin to the differences of electrochemical behaviours observed in compounds with different size of crystallites and different amounts of lattice defects. Energy capacity performances of 200 Ah/kg are reached for materials with crystallites of about 10{sup 7} Angstrom{sup 3} and with about 7% of defects, while energy capacities of only 80 Ah/kg are obtained for materials with ten times bigger crystallites. (J.S.) 3 refs.

International Nuclear Information System (INIS)

This study was the analyse the relationship between properties of ion nitrided Fe sintered material and parameters of plasma nitriding process. Pure fe sintered materials (relative density : 92%) were fabricated by hot-pressing and nitrided under pulsed DC plasma for 4 hours. The large number of parameters in plasma diffusion treatment allows close control of the process so that surface layers with defined microstructures and properties can be obtained. The number of micropores in nitriding layer can be reduced in pulsed DC plasma by reducing the plasma power and by varying the gas mixture. The phase constitution of compound layer of nitrided Fe sintered material were influenced by gas mixture (N_2 : H_2) and pulsed ratio (pulse on/off time ratio).

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Removal of sulfonamide (SAs) and tetracycline (TAs) classes of antibiotic compound from deionized water and DOC water by powdered activated carbon (PAC) adsorption was evaluated in this study. According to the study results, TAs were more easily adsorbed than SAs although TAs were more hydrophilic than SAs. The phenolic compounds in TAs might be responsible for their high adsorption. Complex formation of TAs with metal and metal oxide on the surface of activated carbon might also contribute to higher adsorption. The hydrophobic effect was important for removal of SAs. More hydrophobic SAs were removed more easily. The carbon type was not important for adsorption of SAs and TAs. Coal based carbon and coconut based carbon showed similar removal efficiencies for these antibiotics. Dissolved organic materials interfered with adsorption of SAs and TAs. Organic interference was more significant for the antibiotic ...

International Nuclear Information System (INIS)

Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. This paper describes the roles on corrosion. A corrosion test on precipitate-containing and precipitate-free materials made from pure zirconium and a small quantity of iron and chromium, rest potential measurements on an intermetallic compound of Zr(FeCr)_2 and zirconium matrix, and a galvanic coupling test of those were performed. Results showed that corrosion behavior of zirconium alloys could be attributed to the electrochemical properties of intermetallic compounds precipitated in each alloy. Namely, the cathodic and anodic polarization characteristics were associated with anodic protection provided by the precipitates on the alloys and the precipitates degradation in the ...

International Nuclear Information System (INIS)

Solid oxide fuel cell (SOFC) is a promising source of power generation in terms of conversion efficiency which is higher than the conventional one, as it is not limited by the Carnot efficiency. Theoretically, the SOFC have an efficiency of the order of 60-80 % but it is limited by the number of active side available for the reaction i.e. TPB (triple phase boundary) at the electrode-electrolyte interface which depends on the particle size of the materials employed during the fabrication of SOFC components (i.e. the method employed during the synthesis). Literally, there are several methods used in the syntheses of oxide materials such as conventional solid-state reaction, co-precipitation, hydrothermal rout, sol-gel and Glycine nitrate process (GNP) but among these GNP found to be effective over the other because of homogeneity, phase purity and smaller particle size of final product. In this work, the Nano-crystalline ...

Energy Technology Data Exchange (ETDEWEB)

A singular stress field can occur at the edge of the joint plane in a thermally or mechanically loaded material compound. This stress field was calculated analytically and was compared with the results from the finite element method. If one of the two partners consists of ceramic material, unstable crack spread starting from faults in this strongly stressed area can lead to failure. In linear elastic material, the behaviour of a crack is clearly described by the stress intensity factors. These can be calculated for a known stress distribution in the uncracked structure by the method of the weight function. The corresponding weight functions for surface cracks parallel to the boundary surface were determined with the aid of suitable reference load cases. The effect of the position of the crack in the compound and the elastic constants of the compound are ...

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the work on high field superconducting materials and processes performed at the Materials and Molecular Research Division of the Lawrence Berkeley Laboratory. Two major interrelated focal points characterize this research. One was the decision to restrict the effort to A-15 compounds because of their superior critical temperatures and critical fields. The inherent brittleness of these compounds along with the requirement for a filamentary morphology led to the second focal point: a heavy reliance on a powder approach for the fabrication of superconducting tapes and wires. There have been exceptions to the use of powder techniques where special circumstances such as the nature of a particular alloy system suggested on alternative approach. The quench-age technique described herein is an example of a non-powder approach. Here the niobium-aluminum system is involved and the ...

International Nuclear Information System (INIS)

Any transport of nuclear material is associated with the risk of contamination after release into working areas or environment. stationary installed safe geometry vessels with pneumatic transfer between them offer unique safety features and reduce operating costs. The article describes the case of HTR fuel spheres, where a specially designed conveying system has been developed and the prototype conveyor has been tested.

Science.gov (United States)

Anthraquinones are widely present in plant kingdom, and clinically used as laxatives. Environmental contaminants, dioxins, develop various adverse effects through transformation of a cytosolic aryl hydrocarbon receptor (AhR). We investigated the effects of 18 anthraquinones and 7 of their structurally related compounds on transformation of the AhR estimated by its DNA-binding activity in the cell-free system. 1,4-Dihydroxyanthraquinone (quinizarin), 1,5-dihydroxyanthraquinone (anthrarufin), 1,8-dihydroxyanthraquinone (danthron), and 5-hydroxy-1,4-naphthoquinone (juglone) strongly suppressed DNA-binding activity of the AhR induced by 0.1 nM 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD), with their IC(50) values around 1 muM. On the other hand, anthraquinone, 2,6-dihydroxyanthraquinone (anthraflavic acid), and 2-hydroxy-1,4-naphthalendione (lawsone) showed moderate effects. Quantitative structure-activity relationships analysis demonstrated that ...

Energy Technology Data Exchange (ETDEWEB)

New results for two types of nano-size silicon, prepared via thermal vapour deposition either with or without a graphite substrate are presented. Their superior reversible charge capacity and cycle life as negative electrode material for lithium-ion batteries have already been shown in previous work. Here the lithiation reaction of the materials is investigated more closely via different electrochemical in situ techniques: Raman spectroscopy, dilatometry and differential electrochemical mass spectrometry (DEMS). The Si/graphite compound material shows relatively high kinetics upon discharge. The moderate relative volume change and low gas evolution of the nano silicon based electrode, both being important points for a possible future use in real batteries, are discussed with respect to a standard graphite electrode. (author)

British Library Electronic Table of Contents (United Kingdom)

Abstract BACKGROUND: Dietary plant materials have attracted much attention because of their health benefits to humans. Acrylamide is found in various heated carbohydrate-rich foods. Our previous results showed that crude aqueous extracts from diverse dietary plants and some phenolic compounds could mitigate acrylamide formation in an asparagine-glucose model system. Based on our previous study, several plant materials were selected to further investigate their inhibitory effects on acrylamide formation in cookies and starch-based model systems. RESULTS: Addition of raw powders from selected dietary plants and their crude aqueous extracts could considerably reduce acrylamide formation in both cookie and potato starch-based models. Aqueous extracts of clove at 4% caused the largest reduction...

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Coal liquefaction investigations required the availability of model compounds for mechanistic investigations. Towards this end, IITRI was funded to develop an approach for the synthesis of one of the target compound. This study was carried out in several phases as outlined here. Initial synthetic investigations on obtaining 2-tetrolol was carried out using high pressure and temperature reduction with Raney nickel catalyst. The next step consisted in incorporation of a hydroxymethyelene group at the C-3 position. This was successfully carried out utilizing 2-tetrolol, formaldehyde, and calcium oxide. An alternate improved method was developed using 3-carboxyl-2-naphthol. This required less time, gave a cheer product in higher yield. Efforts at the introduction of a chloromethylene group only yielded polymeric material or starting material in spite of protection the phenolic group by various groups. They ...

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The Department of Toxic Substance Control (DTSC) requested that Lawrence Livermore National Laboratory (LLNL) evaluate the treatment process currently employed at the Department's Stringfellow Superfund Site Pretreatment Plant (PTP) site to determine if wastes originating from the site were properly managed with regards to their radioactivity. In order to evaluate the current management strategy, LLNL suggested that DTSC characterize the effluents from the waste treatment system for radionuclide content. A sampling plan was developed; samples were collected and analyzed for radioactive constituents. Following is brief summary of those results and what implications for waste characterization may be made. (1) The sampling and analysis provides strong evidence that the radionuclides present are Naturally Occurring Radioactive Material (NORM). (2) The greatest source of radioactivity in the samples was naturally occurring uranium. The sample results indicate ...

Energy Technology Data Exchange (ETDEWEB)

In this paper, the influence of plasma nitriding at temperature 720 deg. C for 20 h on the surface microstructure and interface microstructure of electroplated chromium coating was investigated. In these conditions, interdiffusion, mixing and reaction phenomena of elements originating from the substrate and coating material are more likely to occur, thus increasing the bonding strength between the coating and carbon steel substrate. The change of the structures from the substrate side to the coating surface, and the effect of the substrate steel on the interface structure were studied by cross-sectional transmission electron microscope observation (XTEM). The nitride layer formed on the surface was analyzed by X-ray diffraction method (XRD). After treatment at above conditions a 6-7 {mu}m thick nitride compound layer was formed in surface region and the same thick carbide compound layer was also formed in the interface ...

International Nuclear Information System (INIS)

Interaction of Yb-Pd-Si system components is studied, isothermal cross section of this system state diagram at 870 K is constructed. Five new ternary silicides are detected in the system: YbPd_5Si_3, Yb_3Pd_2_0Si_6, YbPd_2Si, YbPd_0_,_6_7Si_1_,_3_3, YbPdSi; the existence of one more -YbPd_2Si_2, earlier known, is confirmed. Crystal structure for all the compounds detected is determined and examined. Data on the materials magnetic properties are obtained. It is assumed that YbPd_2Si, YbPd_2Si_2 and YbPdSi compounds appear to be the Condo-systems. 10 refs., 3 figs., 3 tabs.

Energy Technology Data Exchange (ETDEWEB)

Red mud has been activated by dissolution in hydrochloric acid and reprecipitation with ammonia. The activated material has been evaluated as a catalyst for the hydrogenation of naphthalene, phenanthrene and pyrene and in the hydroliquefaction of both a high and low rank coal utilizing solvents of high and low hydrogen donating ability. Activation led to a substantial increase in the ability to hydrogenate the model compounds and a significant increase in oil yield was obtained in the hydroliquefaction of a low rank coal in the presence of a poor donor solvent. However, activation did not lead to significant increases in overall yields of liquids in other cases and the activated red mud was significantly less active than a commercial nickel-molybdenum-sulphur catalyst. 27 refs., 1 fig., 5 tabs.

Energy Technology Data Exchange (ETDEWEB)

Many important advances in the physics of strongly correlated electron systems have been driven by the development of new materials: for instance the filled skutterudites MT{sub 4}X{sub 12} (M=alkali metal, alkaline earth, lanthanide, or actinide; T=Fe, Ru, or Os; X=P, As, or Sb), certain lanthanide and actinide intermetallic compounds such as URu{sub 2-x}Re{sub x}Si{sub 2} and CeTIn{sub 5} (T=Co, Rh, or Ir), and layered oxypnictides and related materials. These types of complex multinary d- and f-electron compounds have proven to be a vast reservoir of novel strongly correlated electron ground states and phenomena. In these materials, the occurrence of such a wide range of ground states and phenomena arises from a delicate interplay between competing interactions that can be tuned by partial or complete substitution of one element for another, as well as the application of ...

Environmental Research Database

Objectives~%~ To quantify the volatile organic compound (VOC) emissions arising from the composting of a range of municipal and~%~ industrial wastes.~%~~%~ To relate the VOC emissions to the material being processed and the process conditions.~%~~%~ To confirm the findings of the above activites by monitoring full-scale composting operations.~%~~%~ To develop predictive models of VOC emissions in relation to waste feedstock and process conditions.~%~~%~ To produce guidance for plant designers, operators a [continued...]DescriptionA recent study of three composting plants undertaken for the Environment Agency has confirmed earlier work suggesting that waste composting can be a source of volatile organic compound (VOC) emissions. However, these experiments were restricted to garden and kitchen waste composting schemes and it was not possible to measure ...

Energy Technology Data Exchange (ETDEWEB)

In case of airplane engine, technical development like increase of temperature at the turbine entrance or high speed rotation with a purpose of thrust up, and reduction of structural part single substance mass or reduction of number of parts in order to achieve lightness and so forth, has been promoted in order to improve the performance that is evaluated by thrust weight ratio (thrust/weight). Accordingly, research and development of high heat resistance, high strength, lightness and so forth of each material of the parts are in demand. As a representative material corresponding to such demand, L10 type {nu}-TiAl intermetallic compound which is light and has improved high temperature strength properties is paid attention and its development is promotes. The authors were successful for the first time in the world to manufacture composite material with CVD type SiC fiber that was difficult so far by ...

Energy Technology Data Exchange (ETDEWEB)

Glass-ceramic materials containing 0-60% glass, 0-40% cordierite and 0-40% mullite were developed with dielectric constant lower than of Al{sub 2}O{sub 3} (5.2-6.7). The following glasses were used: SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}, CaO-ZnO-B{sub 2}O{sub 3}, CaO-ZnO-Al{sub 2}O{sub 3}B{sub 2}O{sub 3}, BaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2} and BaO-ZnO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}. The influence of the content of the particular components on the value of dielectric constant of the ceramics was investigated. (author). 9 refs, 3 tabs.

Science.gov (United States)

... PADS(CUSHIONS), OBTURATION(BALLISTICS), BUTYL RUBBER, COMBUSTIBLE CARTRIDGE CASES, PHOSPHORUS COMPOUNDS. ...

International Nuclear Information System (INIS)

We present a comprehensive, up-to-date compilation of band parameters for the technologically important III - V zinc blende and wurtzite compound semiconductors: GaAs, GaSb, GaP, GaN, AlAs, AlSb, AlP, AlN, InAs, InSb, InP, and InN, along with their ternary and quaternary alloys. Based on a review of the existing literature, complete and consistent parameter sets are given for all materials. Emphasizing the quantities required for band structure calculations, we tabulate the direct and indirect energy gaps, spin-orbit, and crystal-field splittings, alloy bowing parameters, effective masses for electrons, heavy, light, and split-off holes, Luttinger parameters, interband momentum matrix elements, and deformation potentials, including temperature and alloy-composition dependences where available. Heterostructure band offsets are also given, on an absolute scale that allows any material to be aligned relative to any other. ...

Energy Technology Data Exchange (ETDEWEB)

Gasification experiments were performed using urban waste wood (Altholz) with additions of polymers typical for separately collected waste plastics. The resulting tar product distributions are discussed in this paper. The amount of tars is shown to be a function of operation parameters of the gasifier as well as the fuel. Plastics admixture yields higher concentrations of aromatic tar compounds in the gases, even if the plastic used is not aromatic in its structure. Such mixtures can be gasified for the production of synthesis gas, but clearly a larger effort will be required in cleaning the gases. (author)

Energy Technology Data Exchange (ETDEWEB)

The authors experimentally study the separate stages of the determination of iodine in thyroidin by the combustion method in a flask with oxygen. The monotypic, conventional procedures and the procedure of Kolii and Pakhomov were studied. With addition of potassium iodide, a sixfold amount (compared with the initial) of iodine is liberated. Further, the liberated iodine is titrated by sodium thiosulfate. The authors find the degree of influence of a high nitrogen content on the determination of iodine in organic compounds. The procedure developed for the quantitative determination of the iodine in thyroidin by the combustion method is simple, fairly rapid, and can be used for the reliable control of the quality of thyroidin preparations and its starting raw material.

Energy Technology Data Exchange (ETDEWEB)

High-T/sub c/ superconductivity is due to the action of two mechanisms: (1) plasmon mechanism, i.e., exchange of two-dimensional (2-D) plasmons and (2) strong electron--phonon coupling. The low dimensionality and the small value of the carrier concentration make the plasmon mechanism favorable. The small value of the coherence length leads to a unique opportunity to observe a multigap structure. The proximity effect can be used in order to increase T/sub c/ of A-15 compounds.

CERN Document Server

A surface may provide a useful pumping action when able to retain adsorbed gas molecules for the duration of a given experiment. To fulfil this condition at room temperature, strong binding forces, as those resulting from chemical reactions, are required. Materials able to react with gases to form stable chemical compounds are called getters. The two main families of getters (evaporable and non-evaporable, or NEG) are presented and discussed. Special emphasis is placed on the NEG strips currently used for the vacuum systems of particle accelerators, and on the newly developed NEG thin-film coatings, in view of their possible future applications.

International Nuclear Information System (INIS)

The composite wave variational version of the APW (augmented plane wave) method is used to obtain the electronic band structure of the compounds boron phosphide and boron arsenide at the high symmetry points #GAMMA#, X, and L. The tight binding interpolation scheme of Slater and Koster is used to calculate the rest of the band structure. The results show that both these materials are indirect band gap semiconductors. The density of states, and the imaginary part of the dielectric constant is also calculated. The theoretical results are compared with the reported experimental and theoretical data. (author).

Science.gov (United States)

The anisotropy of H/sub c2/ was measured in a V$sub 3$Si monocrystal and was found to be much larger than in other materials. The max elementary pinning force f/sub p/ is estimated to be approximately 0.01 dyn/cm at the reduced field H/H/sub c/ = 0.25 and 4.2$sup 0$K. Control of texture as well as of grain size is important for improving J/sub c/ in A-15 compounds. (DLC)

Science.gov (United States)

An interest in electronic materials has led me to investigate new synthetic approaches to III-V' type semiconducting (13-15, current IUPAC designation for B and N groups in the Periodic Table) and magnetic (3-15) compounds. It is now possible to prepare binary (GaAs and GdP) and ternary mixed-metal (Al[sub x]Ga[sub 1-x]As) and mixed-pnictide (GaP[sub x]As[sub 1-x]) compounds in seconds from rapid, low-temperature-initiated metathesis reactions between a metal (III) trihalide and a trisodium pnictide, exemplified by MX[sub 3] + Na[sub 3]Pn [yields] MPn + 3 NaX, where M is Al, Ga, In, (Al,Ga), or a lanthanide; X is F, Cl, or I; and Pn is P, As, Sb, or (P,As). The precursors are mixed together in a dry box and ignited by light grinding with a mortar and pestle, or by brief, local heating from a hot filament. These reactions are very exothermic (calculated [Delta]H[sub rxn] (GaAs) = 138 kcal/mol) and typically reach ...

Energy Technology Data Exchange (ETDEWEB)

The electronic structure and properties of the cubic Laves phase (C15) compounds ZrZn/sub 2/ and ZrV/sub 2/ have been determined using our all-electron full-potential linearized-augmented-plane-wave (FLAPW) method for bulk solids. The computations were performed in two stages: (i) self-consistent warped muffin tin and (ii) self-consistent full potential. Spin-orbit coupling was included after either stage. The effects of the inclusion of the nonspherical terms inside the muffin tins on the eigenvalues is found to be small (of order 1 mRy). However, due to the fact that some of the bands near the Fermi level are flat, this effect leads to a much higher value of the density of states at E/sub F/ in ZnZr/sub 2/. The most important difference between the materials ZrZn/sub 2/ and ZrV/sub 2/ is the position of the d bands derived from the Zr and V atoms. Consequently, these materials have completely different Fermi surfaces. We ...

International Nuclear Information System (INIS)

The magnetic ordering temperature of some rare-earth-based heavy-fermion compounds is strongly pressure dependent and can be completely suppressed at a critical pressure, p_c, making way for novel correlated electron states close to this quantum critical point. We have studied the clean heavy-fermion antiferromagnets CePd_2Si_2 and CeIn_3 in a series of resistivity measurements at high pressures up to 3.2 GPa and down to temperatures in the mK region. In both materials, superconductivity appears in a small window of a few tenths of a GPa on either side of p_c. We present detailed measurements of the superconducting and magnetic temperature-pressure phase diagram, which indicate that superconductivity in these materials is enhanced, rather than suppressed, by the closeness to magnetic order. (author)

International Nuclear Information System (INIS)

EXAFS measurements are useful in determining the local atomic environment of a particular element in a solid. Since there has been some controversy about the nature of the defects produced in A-15 materials by radiation damage, such studies were carried out on some A-15 compounds, V_3Ga which was damaged by neutrons, as well as Nb_3Ge damaged by 2.5 MeV a particles. In the V_3Ga sample, site exchange disorder seems to be the most important result of the neutron damage with less than 20% of the vanadium atoms on wrong sites. However, in the Nb_3Ge samples in addition to site exchange disorder, an unusual splitting of the first near-neighbor distance between the Ge and Nb is found. This splitting, approximately 0.2 A, may explain the large Debye Waller factors observed by Burbank et al.

Energy Technology Data Exchange (ETDEWEB)

The national energy research programme LVIS-2000: Future Building Services is concerned with the control of energy use and indoor climate in buildings of the future. The projects were presented at a one day seminar arranged by the Laboratory of Heating and Ventilation of the Technical Research Centre in Finland which is coordinating the programme. The presentations at the seminar were: Impurity emission from materials, Building materials and indoor air quality, analysis of organic compounds in indoor air, effect of the return air, effect of the return air on health and comfort, electric heating as an indoor climate factor, calculations of air flows in ventilated rooms, effect of energy saving measures on hospital hygiene, application of modern aerosol measurement technique on indoor climate research.

Energy Technology Data Exchange (ETDEWEB)

Flywheels containing fiber-reinforced composite materials have attributes suitable for vehicular propulsion, indicating the need for rotor designs which are easily manufactured and low in cost. This development goal was pursued in a cooperative effort between Owens-Corning Fiberglas and Lawrence Livermore Laboratory which investigated flywheels made from compression-molded sheet molding compound (SMC). The design resulted from a Lawrence Livermore analysis, with successful fabrication achieved using a procedure developed by Owens-Corning. Details concerning materials selection, rotor fabrication, and testing are discussed. Owens-Corning subsequently initiated a technical/marketing survey to determine current industrial interests in a low-cost flywheel design; precursory information, pertaining to composite flywheels in particular, is described.

British Library Electronic Table of Contents (United Kingdom)

Ruthenium(II) and Iridium(III) polypyridyl complexes have been intensively investigated due to their use in energy conversion and light-emitting devices and materials for non-linear optics. Quantum mechanical computer simulations of molecules and materials have become increasingly popular in the scientific community. Along with experimental investigations, such computational analyses can provide complementary information on the electronic and optical properties of transition metal compounds of interest for optoelectronic applications. Here, we provide a unified review of recent work carried out on computational investigations of a large series of Ruthenium(II) and Iridium(III) polypyridyl complexes, discussing the relations between their electronic structure and optical properties and thei...

Energy Technology Data Exchange (ETDEWEB)

Lithium ion batteries use an oxide as a positive electrode and a carbon material as a negative electrode. The performances of carbon electrodes have rapidly evolved during the last years thanks to the substitution of soft carbons of Conoco or MCMB-2510 type by graphites (F-399, MCMB-2528) and then by hard carbons. These high capacity carbons (700 mAh/g) have higher service life and volume capacity than graphites but their irreversible losses are greater (>20%). In this work, materials with similar electrochemical performances are prepared by mechanical crushing. Mechanical crushing allows to obtain a wide range of carbon materials with various morphologies, specific surfaces and levels of disorder. The formation of the passivation film is directly linked with the surface of materials. A reaction scheme of the reversible and irreversible capacities has been defined and has permitted to obtain ...

Energy Technology Data Exchange (ETDEWEB)

Clay-based materials can be cold-stabilized using binder and formed by extrusion. This paper deals with the properties of such materials under the influence of silico-aluminous flying ashes addition. Flying ashes are solid industrial wastes produced by coal combustion. Characteristics of ashes bearing clay-based products, such as dimensional stability, water and mechanical resistance, accelerated aging, are considerably improved with respect to simple clay-binder mixtures. This is principally due to a better hydration of the binder in ashes-bearing mixtures because of: a higher free-water availability as a consequence of the smaller specific surface of ash grains, the filler effect of ash grains which do not participate to the reactions, the specific property of silico-aluminous ashes that can fix the lime in presence of water to produce hydrated compounds. These ashes-bearing clay based materials can ...

International Nuclear Information System (INIS)

Bangladesh possesses many industrial sites, whereby wastes and effluents are directly discharged into the environment without any treatment. Agricultural areas are contaminated thereby and the food quality is impaired. Therefore, the aim of the present work was to develop simple and cost effective strategies to reduce soil-plant transfer of harmful substances. Three sites were selected in the vicinity of Dhaka city (Tongi pharmaceutical, Tejgaon industrial and Hazaribagh tannery area). Field and pot experiments were carried out with different varieties of field crops (rice, wheat and tomato) and different soil amendments (cowdung, city waste compost, oil cake, waterhyacinth, poultry litter, lime and red mud). At the site Tongi, pollutants mainly consists of organic compounds. The soil of Tejgaon is acidic (pH=5.7), contains high organic matter and elevated concentrations of Zn (685 mg/kg), Pb (136 mg/kg), and Cd (2.6 mg/kg). The Hazaribagh ...

International Nuclear Information System (INIS)

Aim: Compounds such "9"9"mTc-MDP and "9"9"mTc-HEDP are used regularly in bone scintigraphy for metastasis detection. The therapeutics properties of beta emitter radionuclides like "1"5"3Sm, "1"6"6Ho and "1"7"7Lu has been widely reported in literature being "1"7"7Lu the less developed for medical applications. With the purpose of study different radiopharmaceuticals alternatives, for metastasis bone palliation, we have evaluated, on a comparative basis, the labeling of "1"5"3Sm-MDP, "1"5"3Sm-HEDP, "1"6"6Ho-MDP, "1"6"6Ho-HEDP, "1"7"7Lu-MDP and "1"7"7Lu-HEDP from the exhibited radionuclidic purity and biological distribution point of view. Material and Methods: The radionuclides were produced at La Reina Research Reactor, Chilean Nuclear Energy Commission. The radionuclidic purity was determined by gamma-Ray spectrometry. The labeling was accomplished with MDP (Plenum) and HEDP synthesized in-house. The in-vitro affinity of labeled ...

Energy Technology Data Exchange (ETDEWEB)

Formaldehyde, a well-identified indoor pollutant, was recently classified as carcinogenic. New regulations for the air quality are expected and therefore there is a need for low-cost sensors, sensitive and selective with a fast response time for the detection of formaldehyde at ppb level. In the present work, we had developed a chemical sensor based on nano-porous matrices doped with Fluoral-P and optical methods of detection. The nano-porous matrices, elaborated via the Sol-Gel process, display nano-pores whose cavity is tailored for the trapping of the targeted pollutant. They provide a first selectivity with the discrimination of the pollutants by their size. A second selectivity is obtained with a molecular probe, Fluoral-P, which reacts specifically with formaldehyde leading to the 3,5- di-acetyl-1,4-dihydro-lutidine (DDL). The kinetics of formation of DDL was studied as function of many parameters such as the concentration of Fluoral-P in the matrix, the pollutant content in gas ...

Energy Technology Data Exchange (ETDEWEB)

Time-of-flight secondary ion mass spectrometry (ToF-SIMS) and laser post-ionization secondary neutral mass spectrometry (laser-SNMS) have been used to image and quantify targeted compounds, intrinsic elements and molecules with subcellular resolution in single cells of both cell cultures and tissues. Special preparation procedures for analyzing cell cultures and tissue materials were developed. Cancer cells type MeWo, incubated with boronated compounds, were sandwiched between two substrates, cryofixed, freeze-fractured and freeze-dried. Also, after injection with boronated compounds, different types of mouse tissues were extracted, prepared on a special specimen carrier and plunged with high velocity into LN{sub 2}-cooled propane for cryofixation. After trimming, these tissue blocks were freeze-dried. The measurements of the K/Na ratio demonstrated that for both cell cultures and tissue ...

Energy Technology Data Exchange (ETDEWEB)

Organic materials released from energy-related activities could affect human health and the environment. To better assess possible impacts, we developed a model to predict the fate of spills or discharges of pollutants into flowing or static bodies of fresh water. A computer code, Aquatic Pathways Model (APM), was written to implement the model. The computer programs use compartmental analysis to simulate aquatic ecosystems. The APM estimates the concentrations of chemicals in fish tissue, water and sediment, and is therefore useful for assessing exposure to humans through aquatic pathways. The APM will consider any aquatic pathway for which the user has transport data. Additionally, APM will estimate transport rates from physical and chemical properties of chemicals between several key compartments. The major pathways considered are biodegradation, fish and sediment uptake, photolysis, and evaporation. The model has been implemented with parameters for ...

Wastenet

1 ?3?4.1 ? ?4.2 ...4.3 ? ?5.1?5.2 ? ?6.1 ?? ?6.2 ? ...8?10 ?? ?11 ? ?? ?12 ??13

Energy Technology Data Exchange (ETDEWEB)

Activated charcoal has so far taken a shape of particle or powder, but as the third activated charcoal, fibrous activated charcoal (ACF) has begun to be produced industrially. In comparison with the conventional activated charcoal, ACF has such characteristics as follows (1) its rate of absorption and desorption is very fast, (2) its specific area is large and it has high absorption performance, (3) it has wide absorption characteristics, and (4) its reactivation and reutilization are possible. In addition, because of its fibrous condition, it can be processed into compound materials of various shapes by utilizing the fiber processing technology. Furthermore, it can be combined with other functional fibrous material and used as multifunctional material. In this article, the production process, performance, characteristics and usage of ACF, which is an excellent absorbent as stated above, are outlined ...

Energy Technology Data Exchange (ETDEWEB)

Lithium, with its strong reducing property and very low potential (-3.045 V/ENH), is one of the best material for electrodes. By combining lithium with an oxidizer, one can obtain an energy and electromotive force higher than with any other electrochemical couple. The density of lithium is low (0.534 g/cm{sup 3}) and thus, its specific capacity is higher than other classical anode materials. This article presents the technology of lithium batteries: 1 - presentation; 2 - negative electrodes: metallic lithium based, lithiated carbon based, transition metal compounds based negative electrodes; 3 - positive electrodes: 'low' voltage and 'high' voltage cathode materials; 4 - electrolytes: introduction, organic solvents and lithium salts-based electrolytes (case of the lithium anode battery, case of the lithium-ion battery), polymer electrolytes; 5 - metallic lithium anode ...

Science.gov (United States)

Not Available

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared

Science.gov (United States)

Not Available

Energy Technology Data Exchange (ETDEWEB)

Short communication. 6 refs., 2 figs.

Energy Technology Data Exchange (ETDEWEB)

The objectives of this project are to develop feasible synthetic routes to produce (1) 4(4{prime}-hydroxy-5{prime},6{prime},7{prime},8{prime}-tetrahydro-1{prime}-naphthylmethyl)-6-methyldibenzothiophene, and (2) a 1-hydroxynaphthalene-dibenzothiophene polymer. These compounds are thought to be representative of sulfur containing molecules in coal. The program is divided into three tasks, the first of which is a project work plan that has already been submitted. There are several possible synthetic routes to the target molecule (1). The authors are now investigating two general synthetic approaches: coupling of a dialkylated dibenzothiophene fragment with the phenol, and coupling of a monoalkylated dibenzothiophene fragment with a monoalkylated phenol fragment. This quarter they developed syntheses for the reaction fragments and conducted some preliminary coupling experiments. They found that polymerization of the fragments is a problem; however, using an acidic ...

Energy Technology Data Exchange (ETDEWEB)

This report describes the cost, performance, and other key characteristics of an innovative technology for determining the presence or absence, and measuring the concentration, of volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs) in groundwater and soil, and in gaseous remediation process streams at hazardous waste sites. This new technology is Direct Sampling Ion Trap Mass Spectrometry (DSITMS). DSITMS introduces sample materials directly into an ion trap mass spectrometer by means of a very simple interface, such as a capillary restrictor or a polymer membrane. There is typically very little, if any, sample preparation and no chromatographic separation of the sample constituents. This means that the response of the instrument to the analytes or contaminants in a sample is nearly instantaneous, and that analytical methods based on DSITMS are fast. Analyses are typically completed in less than ...

Energy Technology Data Exchange (ETDEWEB)

This semiannual report for the period October 1983-March 1984 summarizes activities in Sandia National Laboratories' continuing program of coal liquefaction research. The primary goals are to: explore novel catalytic concepts and materials for conversion of coal to liquid fuels; determine the effects of process variables on catalyst deactivation; determine the effects of coal structure and solvent properties on low temperature dissolution; study the kinetics and catalysis of hydrogen transfer reactions; develop an understanding of slurry gelling phenomena; and provide a technical assessment of coal liquefaction processes. During this period, work was performed on: the use of pyrene as a chemical probe of catalyst activity; analysis of catalysts from Wilsonville run 242 using ESCA; atmospheric pressure model compound activity testing of regenerated catalysts from Wilsonville run 242; base displacement experiments with a coal-indole ...

Science.gov (United States)

This study examined the effect of sulfur-containing compounds on the storage stability of Jet A

Science.gov (United States)

Hydrothermal oxidation (HTO) is a promising technology for the treatment of aqueous-fluid hazardous and mixed waste streams. Waste streams identified as likely candidates for treatment by this technology are primarily aqueous fluids containing hazardous organic compounds, and often containing inorganic compounds including radioisotopes (mixed wastes). These wastes are difficult and expensive to treat by conventional technologies (e.g. incineration) due to their high water content; in addition, incineration can lead to concerns related to stack releases. An especially attractive potential advantage of HTO over conventional treatment methods is the total containment of all reaction products within the overall system. The potential application of hydrothermal oxidation (HTO) technology for the treatment of DOE hazardous or mixed wastes has been uncertain due to concerns about safe and efficient operation of the technology. In principle, aqueous ...

Energy Technology Data Exchange (ETDEWEB)

The development of rechargeable lithium batteries with a high mass capacity, made with non-toxic and low cost materials is an important industrial challenge. Morphological and structural modifications occurring in the electrode materials during charge-output cycles should not lower the electrochemical characteristics and the cycling properties of the battery. Thus the structure of electrode materials must be sufficiently deformable and stable to support the constraints linked with lithium intercalation and de-intercalation (ions and electrons absorption/extraction). The aim of this work is to explain some characteristics (mass capacity, ions and electrons mobility, cycling) using the relation between some mechanisms of lithium insertion (sites occupation, lattice reduction mods) and the nature of atoms and chemical bonds (covalence, ionicity). This approach is developed on 2-D models of crystallized and vitreous sulfur ...

Energy Technology Data Exchange (ETDEWEB)

Thermoplastic encapsulation has been extensively studied at Brookhaven National Laboratory`s (BNL) Environmental and Waste Technology Center (EWTC) as a waste encapsulation technology applicable to a wide range of waste types including radioactive, hazardous and mixed wastes. Encapsulation involves processing thermoplastic and waste materials into a waste form product by heating and mixing both materials into a homogeneous molten mixture. Cooling of the melt results in a solid monolithic waste form in which contaminants have been completely surrounded by a polymer matrix. Heating and mixing requirements for successful waste encapsulation can be met using proven technologies available in various types of commercial equipment. Processing techniques for thermoplastic materials, such as low density polyethylene (LDPE), are well established within the plastics industry. The majority of commercial polymer processing is ...

International Nuclear Information System (INIS)

The ternary compound CuInS2 is attractive for solar cells due to its band gap of 1.54 eV which borders the optimum value necessary for conversion of a solar spectrum. Recently, works on thin film cells based on this material (ZnO/CuInS2) has been reported to show efficiency as high as 11.4%. In this paper, the orientation and the morphology of CuInS2 sprayed films are determined by the means of X-ray diffraction and scanning electron microscopy. Sprayed CuInS2 films deposited onto a transparent Pyrex substrate with standard fabrication parameters show a chalcopyrite structure with a preferential orientation (1 1 2). A model based on the calculation of the relative dielectric function ? has been performed in order to obtain the profile of variation of this parameter and to understand the optical behavior of this material via its transmittance and reflectance in visible and near-infrared regions (0.35-2.5 ?m). In the same ...

Energy Technology Data Exchange (ETDEWEB)

With the advance of science, rise of public interest in environmental matters, and continuing erosion of air quality, Federal and state regulators are demanding an increasing complex array of data concerning emissions produced by burning and detonating energetic materials. The US Department of Defense, one of the world`s largest consumers of energetic materials, now must characterize combustion products resulting from open burning/open detonation disposal operations. The catch-all phrase ``below detection limits`` no longer satisfies the regulators who now want testing to delve into the ppt level for volatile organic compounds and ppt level for semivolatile organic compounds. Regulators are also expanding their scope of interest and may soon be asking for emissions data on training operations such as artillery firing. Providing this type of information is no longer an impossibility. The Army, as the ...

International Nuclear Information System (INIS)

Molar extinction coefficients for the solid solutes in aqueous solutions of some alkaline earth chlorides such as MgCl_2.6H_2O, CaCl_2, SrCl_2.6H_2O and BaCl_2.2H_2O have been determined at 81, 356, 511, 662, 1173 and 1332 keV energies in different concentration using the narrow beam transmission methods. (author)

Energy Technology Data Exchange (ETDEWEB)

A meeting was held on October 15, 16, 17, 1990 to discuss the state of tritium safety and environmental effects. The meeting was organized with the help of the International Energy Agency planning committee consisting of K. Steinmetz, Y. Seki, G. Nardella, and G. Vivian. Representative of tritium production facilities and heavy water reactor power production were also involved. The meeting was organized to address seven topics in tritium safety that were thought to require further work. The topics were: (1) materials science, (2) environmental models, (3) environmental model validation, (4) tritiated organic compounds, (5) human dosimetry, (6) tritium sampling and measurement, and (7) long-term environmental databases.

International Nuclear Information System (INIS)

As part of the general QC/QA management of the k_0-standardization, three types of 'SMELS' (synthetic multi-element standards) are being developed to check the performance of k_0-NAA when implemented in a laboratory. Phenol-formaldehyde resin is proposed in this paper as the matrix of choice. Based on previous work, this material could be prepared with sufficient purity so as to make interferences with the spiking elements negligible. The matrix was found to be adequately resistant towards high neutron flux irradiation. A selection was made of compounds, soluble in ethyl alcohol, for spiking the prepolymer ethanolic solution with the elements of interest. Finally, some prototypes were prepared and a satisfactory homogeneity of the spiked elements was found for 50 mg sample intake.

British Library Electronic Table of Contents (United Kingdom)

Mechanistic studies on a charged ultrafiltration (UF) membrane fouled with natural organic matter (NOM) and colloidal particles are systematically investigated to understand the relative role of each NOM fraction and the presence of colloidal particulate to membrane fouling. Humic acid (HA), dextran, and kaolin were employed as surrogate model foulants representing the organic hydrophobic acid NOM, hydrophilic neutral NOM, and inorganic colloidal materials, respectively. The results obtained showed that the organic NOM of hydrophilic surrogate (dextran) plays a primary role in promoting membrane fouling, followed by hydrophobic acids and inorganic kaolin, but to a lesser extent than organic NOM compounds. Significant differences in the extent of fouling between dextran and HA have been obs...

Science.gov (United States)

A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

Science.gov (United States)

Summaries are included of research contracts which expired prior to Dec. 31, 1960. The contracts were concerned with investigations of: electrophysiological responses of biological systems in nerve cells to irradiation with small doses of ionizing radiations; the mode of the protective action of certain sulfhydryl compounds against radiation effects on the synthesis of deoxyribonucleic acid, using tritium-labeled thymidine; development of a bubble chamber method of monitoring and dosimetry for Low fast neutron fluxes; effects of incorporated radioisotopes on the stability of genetic materials; interrelation of root and leaf absorption of radioisotopes in herbaceous plants; uptake of radioactive wastes by lowland rice from soils contaminated by irrigation water, and decontamination of the rice; and comparison between mutation rates induced by acute and chronic gamma irradiations. (B.O.G.)

International Nuclear Information System (INIS)

Electron charge distributions are presented for Nb_3Ge, Nb_3Al, and two other hypothetical A-15 structures. Results indicate that the bonding in these materials is mainly metallic in character with some covalentlike bonding between Nb-chain atoms. We find significant coupling between neighboring chains and also between chain atoms and atoms at the cubic site. Comparison is made with various theoretical models. Investigation of the charge character of states near E/sub F/ suggests further developments in current theories on the structural transformation of A-15 compounds. The effect of chain dimerization on electronic states and charge distribution of Nb_3Ge is also investigated.

Science.gov (United States)

Electron charge distributions are presented for Nb3Ge, Nb3Al, and two hypothetical A-15 structures. Results indicate that the bonding in these materials is mainly metallic in character with some covalentlike bonding between Nb-chain atoms. We find significant coupling between neighboring chains and also between chain atoms and atoms at the cubic site. Comparison is made with various theoretical models. Investigation of the charge character of states near EF suggests further developments in current theories on the structural transformation of A-15 compounds. The effect of chain dimerization on electronic states and charge distribution of Nb3Ge is also investigated.

Energy Technology Data Exchange (ETDEWEB)

Recent developments in rechargeable Li-ion battery technology include the use of lithium-carbon compounds instead of metallic anodes. Non-graphitizable carbons offer high capacity as the anode material but it's large irreversible capacity must be solved. The ultimate goals of the present work are to understand the origin of the high capacity and large irreversible capacity in conjunction with the structural change due to Li intercalation and thus to establish a scientific basis for optimizing their performance in real batteries. 'House of cards' model is considered and emphasis is given to find out the size of the pores present in the carbon fibers prepared from an isotropic petroleum pitch and heat treated at 1200degC. Small angle neutron scattering and wide angle neutron scattering results provide enlargement of pores and d-spacing of grapheme layers after Li intercalation. (author)

British Library Electronic Table of Contents (United Kingdom)

Purpose To study the chemical modifications induced upon irradiation of solid human insulin at radiosterilization doses and investigate the influence of the absorbed dose on radiolysis. Materials and Methods Volatile radiolytic products were monitored by gas chromatography coupled with mass spectrometry (GC-MS) and non-volatile products by two different high performance liquid chromatography (HPLC) methods: the formation of higher molecular weight proteins was assessed by size exclusion liquid chromatography whereas assays for related compounds and chemical potency tests were carried out using reverse-phase HPLC-UV. Conformational changes were investigated by measurements of circular dichroism. Results After gamma irradiation at 10?kGy, the recovery of insulin was 96.8%; higher molecular w...

International Nuclear Information System (INIS)

Accurate full-potential self-consistent linearized augmented-plane-wave (FLAPW) calculations have been carried out for hexagonal boron nitride. The resulting energy-band structure indicates that this material is an indirect-gap insulator and shows the existence of two unoccupied interlayer bands, similar to those found in graphite and graphite intercalation compounds. Chemical bonding is mainly covalent, with a small charge transfer towards the nitrogen atoms. Moreover, model-potential calculations, based on first-principles FLAPW wave functions and potentials, have been used to study slabs of thickness up to 35 layers. Contrary to the case of graphite, our results do not provide evidence of surface states associated with the interlayer bands.

International Nuclear Information System (INIS)

A rapid combustion unit (Baird and Tatlock) incorporating a combustion chamber provided with baffle plates for complete combustion of the sample without the use of a catalyst has been assembled in a glove box for the determination of carbon and hydrogen in actinide complexes. The unit has been modified employing a movable electric furnace and a proportional temperature controller, for decomposition of the sample at desired heating rates. The set-up was standardised employing various reference materials such as benzoic acid, acetanilide, sulphanilamide and 1-chloro 2:4 dinitrobenzene and the standard deviation in the measurements evaluated. It has also been used successfully for the determination of carbon in uranium carbide and carbon and hydrogen in some uranyl-#beta#-diketone-amine N-oxide complexes and in plutonium(IV) oxalate. (auth.).

International Nuclear Information System (INIS)

Thienyl oxazoles and thienyl isoxazoles, are composite molecules having two subsystems thiophene and oxazole molecules connected together by a single bond that they have 13 isomers. They are potential candidates for many kinds of applications such as OLED and nonlinear optical materials. Initially equilibrium geometries of title compounds have been obtained without any restriction using density functional theory with 6-311++g(2d,p) basis set. We obtained structural parameters, dipole moment and electronic energy. At the second stage, we have calculated some electronic and nonlinear optical properties such as HOMO and LUMO energies, polarizability, anisotropic polarizability and hyper polarizability using same level of theory.

Energy Technology Data Exchange (ETDEWEB)

Plasma nitriding is usually used for ferrous materials to improve their surface properties. Knowledge of the properties of thin surface layers is essential for designing engineering components with optimal wear performance. In our study, we investigated the microstructural, mechanical and tribological properties of plasma- and pulse plasma-nitrided AISI 4140 steel in comparison to hardened steel. The influence of nitriding case depth as well as the presence of a compound layer on its tribological behaviour was also examined. Plasma and pulse plasma nitriding were carried out using commercial nitriding processes. Nitrided samples were fully characterised, using metallographic, SEM microscopic, microhardness and profilometric techniques, before and after wear testing. Wear tests were performed on a pin-on-disc wear testing machine in which nitrided pins were mated to hardened ball bearing steel discs. The wear tests were carried out under dry ...

International Nuclear Information System (INIS)

Intermetallic compounds based on the Al-Co system were synthesized by solid state method - mechanical alloying and their properties were investigated using XRD, SEM, and DSC. The powder was used to make new targets of irradiation for gamma sources in order to enhance the specific activity and to reduce the consumption of material. The intermetallic compound AlCo was formed in the first 4 hours of milling. After 8 hours of milling the medium size of crystallites were of 5.58 nm. This value decreases with the increase of milling time up to 3 nm, corresponding to the 28 hours of grinding. There was calculated and plotted the Gibbs function, #DELTA#_f"0, for the reaction of formation AlCo and Al_3Co from the Al-Co system. It had negative values over the entire range of temperatures for both investigated compounds. After 28 hours milling a phase composition was obtained as follows: 0.2% Al; 21%Co ; ...

Science.gov (United States)

A way to synthesize the transient zwitterionic silylene L'Si: 8 {L'=CH[(C=CH(2))CMe(N(tBu))(2)]} and achieve its facile dimerization to the remarkable N-heterobicyclic disilane 8(2) is described. At first, employing the beta-diketiminate ligand L [L=CH(CMeN(tBu))(2)], both starting materials LH (2) and its N-lithium salt LLi (3) can react with SiBr(4) to yield the silylene precursor L'SiBr(2) (4) by silicon-induced C-H activation at an exocyclic methyl group on the backbone of the ligand. Compound 4 reacts with SiBr(4) above room temperature to afford the unexpected terminal CH(SiBr(3))-substituted dibromosilane 6 along with the unique tricyclic trisilane 7. Reduction of 4 with KC(8) at 0 degrees C furnishes the novel N-heterobicyclic disilane 8(2), which is a formal dimer of the desired zwitterionic silylene L'Si: (8). It has been reasoned that compound 8(2) may results from [4+1] cycloaddition of two molecules of 8 to ...

International Nuclear Information System (INIS)

Thermoplastic polymer materials and the compounds made with them are being used more frequently for industrial components and for general use. However, the application of these materials for the production of complex shaped or relatively large pieces is limited, because of the difficulty and cost of making the necessary tool kit for the job. One solution is the use of the welding process. But the safe and reliable union of different thermoplastic material parts is not a simple process, even less so in the case of unions of large components. Welding by microwaves using polymer conductors can help, since the large scale equipment is available, and methods for continuous processes by microwave have been developed, that can be used to weld large and small components. Many thermoplastics (ex. polyethylene) do not absorb, or absorb very little, energy from microwaves. Polymer conductors, however, heavily ...

International Nuclear Information System (INIS)

Alloying elements such as Fe and Cr are generally considered to be effective even in small quantities for corrosion resistance of Zircaloy-4. The maximum total solubility of Fe + Cr in a Zr-Sn matrix has been reported to be very low. Therefore, most of these elements are observed in the form of ternary Zr-Fe-Cr-type precipitates. To clarify the effects of precipitates on corrosion property, Zr-1.3 Sn-(Fe,Cr) alloys containing Fe + Cr from 45 up to 180 ppm (the Fe to Cr ratio is about 2) were melted from pure zirconium (X-bar Zr and EB-Zr) and pure alloying elements. They were subjected to corrosion testing in 633 K water and microstructural analysis. It was found that precipitate-free materials showed much larger weight gains than precipitate-containing materials even at the same alloy compositions. Subsequently, a corrosion test on the precipitate-free material galvanically coupled with a noble intermetallic ...

Energy Technology Data Exchange (ETDEWEB)

Net heats of reaction were measured in an isothermal calorimeter for both single phase (organic) and two phase (organic and aqueous) TBP/HNO{sub 3} reacting solutions at temperatures above 100 C. The oxidation rate constant was determined to be 5.4E-4 min{sup {minus}1} at 110 C for an open ``vented`` system as compared to 1.33 E-3 min{sup {minus}1} in the closed system. The heat released per unit material oxidized was also reduced. The oxidation in both phases was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water. The hydrolysis (esterification) rate constant determined by Nichols` (1.33E-3 min{sup {minus}1}) fit the experimental data from this work well. Forced evaporation of the volatile components by the product gases from oxidation resulted in a cooling mechanism which more than balanced the heat from the oxidation reaction in the two-phased systems. Rate expressions were derived and rate constants determined for both the ...

Energy Technology Data Exchange (ETDEWEB)

A considerable fraction of radioactivity entering the environment from different nuclear events is associated with particles. The impact of these events can only be fully assessed where there is some knowledge about the mobility of particle bound radionuclides entering the environment. The behavior of particulate radionuclides is dependent on several factors, including the physical, chemical and redox state of the environment, the characteristics of the particles (e.g., the chemical composition, crystallinity and particle size) and on the oxidative state of radionuclides contained in the particles. Six plutonium-containing particles stemming from Runit Island soil (Marshall Islands) were characterized using non-destructive analytical and microanalytical methods. By determining the activity of {sup 239,240}Pu and {sup 241}Am isotopes from their gamma peaks structural information related to Pu matrix was obtained, and the source term was revealed. Composition and elemental distribution ...

Energy Technology Data Exchange (ETDEWEB)

Perylene bisimides (PBIs) represent an important class of organic n-type semiconductors exhibiting a relatively high electron affinity among large-band-gap materials. Herein synthesis and characterization of several unsymmetrical N-substituted PBI dyes is presented and the thermotropic behavior, which is strongly affected by the respective N-substituents was investigated. Two different series of highly soluble and fluorescent derivatives have been synthesized: (1) PBIs bearing swallow-tailed alkyl chains, different in size or (2) one swallow-tailed alkyl chain and one branched oligoethylenglycolether. Synthesis of these PBIs is generally feasible by two distinct divergent synthesis approaches. Thermotropic behavior was studied by DSC, POM and XRD measurements. Inherent {pi}-{pi} interactions between cofacially orientated perylene molecules and the elliptic shape of the molecule favor the ordering in columns and self-organized architectures. Among them hexagonal ...

Energy Technology Data Exchange (ETDEWEB)

The optoelectronic compounds of GaAs and ZnSe are difficult to analyze by PIXE (particle-induced X-ray emission) due to the strong absorption of the As and Se K{sub {alpha}} X-rays. As part of a program to investigate optoelectronic materials using ion beam techniques, we have explored the possibility of using the high sensitivity of PIXE to check these materials for stoichiometry and dopant concentrations. The K{sub {alpha}} X-ray intensity ratios of Ga to As and Zn to Se have been investigated using H beams of 0.5 to 2.5 MeV and He beams of 1.0 to 2.5 MeV. The variation in the X-ray intensity ratio with beam energy and target thickness is modelled in terms of the cross section for X-ray production and the absorption coefficients of the X-rays in the target. The results of this model show the experimental conditions that must be satisfied in order that the X-ray intensity ratios are not strongly affected by X-ray ...

Energy Technology Data Exchange (ETDEWEB)

Neutron scattering experiments on the mixed-valence (MV) compounds SmB{sub 6} are reported. The inelastic magnetic response of SmB{sub 6} at T = 2 K, measured on a double-isotope single crystal,displays a strongly damped peak at 35 meV corresponding to the inter multiplet transition of Sm{sup 2+}. At lower energies ( h.{omega} {approx_equal} 14 meV), a narrow magnetic excitation is observed, with remarkable scattering-vector and temperature dependences of its intensity. This novel feature is discussed in terms of recent theoretical works describing the formation of an anisotropic local bound state in semiconducting MV materials. If the average samarium valence is decreased by substituting La for Sm, a peak is found to appear at high energies. The elastic magnetic form factor of SmB{sub 6} was determined using polarised neutrons and no significant difference is observed in its Q-dependence with respect to that of pure divalent samarium. This ...

Energy Technology Data Exchange (ETDEWEB)

ABO{sub 3} perovskite-type oxides having vacancies in the A-sites of their structure are interesting candidates for solid electrolytes when their A-sites are occupied by Li{sup +} ions having a high mobility. This is the case with the [Li{sub 3x}La{sub 2/3-x}]TiO{sub 3} solid solution compound which has a 10{sup -3} S cm{sup -1} ionic conductivity at ambient temperature. Electrochemical intercalation in this material is possible thanks to the presence of Ti{sup 4+} but the small amount of vacancies (0.33 maximum) leads to a low intercalation rate. In order to solve this problem, the LiLaNb{sub 2}O{sub 7} material which has a greater amount of vacancies has been studied and the results relative to the electrochemical intercalation of lithium in this perovskite are presented. The thermodynamical and kinetics properties of the lithium intercalation reaction have been studied by intermittent galvano-static discharges and ...

International Nuclear Information System (INIS)

Hydrogen cyanide is a key molecule for chemical evolution studies because, when it is exposed to different sources of energy, it forms various compounds of biological importance. To understand the role of minerals in chemical evolution, a series of experiments was performed. First, the adsorption capacity of HCN on different surface minerals was studied; the results show that HCN is readily adsorbed onto the solids proposed (zeolite, serpentine, dolomite, and sodium montmorillonite), in particular zeolite and montmorillonite. Second, the radiolysis of HCN adsorbed on olivine (as an example of a mineral surface) was also followed; it was found that the rate of HCN decomposition by gamma irradiation is enhanced in the presence of the solid. The third series of studies show that organic material was produced in high abundance from HCN at high radiation doses. The radiolytic products included gases (CO_2, NH_4, and CO) and oligomeric ...

International Nuclear Information System (INIS)

Kaolinite intercalated with potassium acetate is of great interest in the areas of environmental remediation and industrial application; however, its exact atomic structure and the changes which occur when heated have remained largely elusive. Here, neutron pair distribution function analysis is used to investigate the local structural characteristics of this complex material, revealing that hydrated potassium acetate exists as a single layer in the interlamellar spacing of kaolinite. Furthermore, the potassium ions within the intercalated complex are most likely associated with the resonance structure of the acetate molecules, and upon heating (and decomposition of the carbon containing molecules), these ions become strongly associated with the negative charge located on the oxygen atoms in the alumina layers of dehydroxylated kaolinite. Several possible orientations of hydrated potassium acetate within the interlamellar spacing of kaolinite have been proposed and ...

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The activated charcoal treatment in the field of the water treatment is applied to water supply, sewage, industrial water supply and industrial sewage, etc.. Its main treatment effects are (1) decolorization, (2) removal of odorous substance, (3) removal of organic material which is detected as COD or BOD, (4) removal of harmful substance, (5) removal of substance which could generate muddness and tarnish and (6) removal of organic material which affects the succeeding high degree treatment badly, etc.. Many actual application examples in the above fields have been reported. As the most recent topic, a big amount of the demand of activated charcoal is expected in the treatment of water supply. Chlorine which is used as disinfectant during the water purification process generates organic halogen compounds such as trihalomethane through the reaction with precursor such as humic acid. The countermeasure therefore is being ...

International Nuclear Information System (INIS)

A systematic study for the materials design of III-V and II-VI compound-based ferromagnetic diluted magnetic semiconductors is given based on ab initio calculations within the local spin density approximation. The electronic structures of 3d-transition-metal-atom-doped GaN and Mn-doped InN, InP, InAs, InSb, GaN, GaP, GaAs, GaSb, AlN, AlP, AlAs and AlSb were calculated by the Korringa-Kohn-Rostoker method combined with the coherent potential approximation. It is found that the ferromagnetic ground states are readily achievable in V-, Cr- or Mn-doped GaN without any additional carrier doping treatments, and that InN is the most promising candidate for high-T_C ferromagnet. A simple explanation of the systematic behavior of the magnetic states in III-V and II-VI compound-based diluted magnetic semiconductors is also given. It is also shown that V or Cr-doped ZnS, ZnSe, and ZnTe are ferromagnetic without p- or n-type doping ...

International Nuclear Information System (INIS)

At the Savannah River Site (SRS), nuclear production reactors used de-ionizers to control the chemistry of the reactor moderator during their operation to produce nuclear materials primarily for the weapons program. These de-ionizers were removed from the reactors and stored as a legacy waste with no path to disposal due to the relatively high 14C contamination (i.e., on the order of 20 curies per de-ionizer for 48-50 de-ionizers) and the low disposal limit of 4.2 Ci previously established for the Intermediate Level Vault (ILV). The ILV is considered most appropriate facility within which to dispose these items due to the method of solidifying waste items with cementitious material inside concrete vaults. In previous analyses the 14C ILV disposal limit was established at 4.2 Ci resulting from the use of a very conservative method to analyze the dose received from atmospheric releases of gaseous 14C. This investigation implemented a more ...

Energy Technology Data Exchange (ETDEWEB)

A large part of mechanical and durability characteristics of cement-based materials comes from the performances of the hydrated cement, cohesive matrix surrounding the granular skeleton. Experimental studies, in situ or in laboratory, associated to models, have notably enhanced knowledge on the cement material and led to adapted formulations to specific applications or particularly aggressive environments. Nevertheless, these models, developed for precise cases, do not permit to specifically conclude for other experimental conclusions. To extend its applicability domain, we propose a new evolutive approach, based on reactive transport expressed at the microstructure scale of the cement. In a general point of view, the evolution of the solid compounds of the cement matrix, by dissolutions or precipitations, during chemical aggressions can be related to the pore solution evolution, and this one relied to the ionic exchanges ...

Science.gov (United States)

and streambed sediment samples 2-6. Graphs showing: 2. Cesium-137 profile in HOE core 3. PAH trends in Lake Houston cores 4. DDE trends in Lake Houston cores 5. Trends in six trace...

UK PubMed Central (United Kingdom)

The high-yield, stereoselective conversion of geraniol (3,7-dimethyl-trans-2,6-octadien-1-ol) to the insect juvenile hormone, methyl 12,14-dihomojuvenate (methyl cis-10-epoxy-3,11-dimethyl-7-ethyl-trans,...Full Text Available

International Nuclear Information System (INIS)

Japanese (Jul 1976). Japan Kametani, Katsuaki Tomura, Kayoko . National

UK PubMed Central (United Kingdom)

Some biological effects of hypoglycin-A, a compound isolated from the fruit of Blighia sapida, have been investigated. Administration of this compound to animals caused drowsiness...Full Text Available

UK PubMed Central (United Kingdom)

Woolfolk, C. A. (University of Washington, Seattle). Reduction of inorganic compounds with molecular hydrogen by Micrococcus lactilyticus. II. Stoichiometry with inorganic...Full Text Available

Science.gov (United States)

The report contains general information on aluminium and aluminium compounds concerning the existing standards, emissions, exposure levels and effect levels. The document is to be considered as a first evaluation to be used for the national discussion dur...

International Nuclear Information System (INIS)

... organic compounds other organic compounds separation processes

International Nuclear Information System (INIS)

"9Be-induced inelastic scattering of "6"2","6"4","6"6Fe and "6"0","6"2","6"4Cr was performed at intermediate beam energies. Excited states in "6"4Cr were measured for the first time. Energies and population patterns of excited states in these neutron-rich Fe and Cr nuclei are compared and interpreted in the framework of large-scale shell-model calculations in different model spaces. Evidence for increased collectivity and for distinct structural changes between the neighboring Fe and Cr isotopic chains near N=40 is presented.

Energy Technology Data Exchange (ETDEWEB)

In the framework of the search for a ceramic material usable in the radioactive waste storage, uranium and thorium phosphates have been investigated. Their experimental synthesis conditions have been entirely reviewed, they lead to the preparation of four new compounds: U(UO{sub 2})(PO{sub 4}){sub 2}, U{sub 2}O(PO{sub 4}){sub 2}, UCIPO{sub 4}, 4H{sub 2}O, and Th{sub 4}(PO{sub 4}){sub 4}P{sub 2}O{sub 7}. Experimental evidenced are advanced for non existent compounds such as: U{sub 3}(PO{sub 4}){sub 4}, U{sub 2}O{sub 3}P{sub 2}O{sub 7} and Th{sub 3} (PO{sub 4}){sub 4}. Characterization by several techniques (X-rays and neutron powder diffractions, UV-Visible and Infra-red spectroscopies, XPS,...) were performed. The ab initio structure determination of U(UO{sub 2})(PO{sub 4}){sub 2} has been achieved by X-rays and refined by neutron diffractions. Through its physico-chemical analysis, we found that this ...

International Nuclear Information System (INIS)

TlGaSe_2 compound belongs to group of layered semiconductors of A"3B"3C_2"6-type. Photoelectric and optical properties of TlGaSe_2 single crystals were investigated in detail. Influence of gamma-, electron and neutron radiation on photoelectric properties of TlGaSe_2 single crystals is investigated too. The present work deals with experimental results relative to X-ray dosimetric characteristics of TlGaSe_2 crystals at 300 K. X-ray conductivity and X-ray dosimetric characteristic measurements are carried out in low load resistance regime. The source of X-ray radiation is the installation of X-ray diffraction analysis (URS-55a) with the BCV-2(Cu). Intensity of X-ray radiation (E) is regulated by measurement with current variation in tube at each given value of X-ray radiation dose E (R/min) are measured by crystal dosimeter DRGZ-02. X-ray conductivity coefficients K_#sigma# characterising X-ray sensitivity of investigated crystals are determined ...

International Nuclear Information System (INIS)

Radiation sterilization has several merits that it is a positively effective sterilization method, it can be used to sterilize low heat-resistant containers and high gas barrier films, and there is no possibility of residual chemicals being left in the packages. It has been commercially used in 'Bag in a Box' and some food containers. The #gamma# ray and an electron beam are commonly used in radiation sterilization. The #gamma# ray can sterilize large size containers and containers with complex shapes or sealed containers due to its strong transmission capability. However, since the equipment tends to be large and expensive, it is generally used in off production lines. On the other hand, it is possible to install and electron beam system on food production lines since the food can be processed in a short time due to its high beam coefficient and its ease of maintenance, even though an electron beam has limited usage such as sterilizing relatively thin materials ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared

International Nuclear Information System (INIS)

... halogenation ionizing radiations kinetics radiations reaction kinetics

International Nuclear Information System (INIS)

... ammonium compounds benzilic acid chemical preparation lanthanum oxides

International Nuclear Information System (INIS)

Short note.

J-STORE (Japan)

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Science.gov (United States)

Not Available

KoreaScience (Korea)

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KoreaScience (Korea)

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Science.gov (United States)

Breath Tests; Human Volunteers; Pilot Study

J-STORE (Japan)

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Energy Technology Data Exchange (ETDEWEB)

Powder mold type solid state battery was fabricated, and positive electrode compounding ratio and the battery characteristics were studied. The current density depended greatly on the TiS2 content of positive electrode material, and the current density showed maximum value of 800 {mu}A/cm{sup 2} at a TiS2 content of 40 wt%. This composition is expected to be the best to provide better charge-discharge characteristics. The rate capability of TiS2 is dominated by Li{sup +} ion in positive electrode. Further, the diffusion of lithium ion is greatly dominated by TiS2 in positive electrode, compounding ratio of solid state electrolyte and its particle size. Results of charge-discharge characteristics studied for various charge-discharge current densities revealed that the rate capability of TiS2 was more than 50% for a current density of less than 254 {mu}A/cm{sup 2}, and this battery system proved the possibility of high rate ...

Energy Technology Data Exchange (ETDEWEB)

This Guideline provides a set of procedures for the measurement of organic contaminants and particles in producer gases from biomass gasifiers. The procedures are designed to cover different gasifier types (updraft or downdraft fixed bed or fluidised bed gasifiers), operating conditions (0 - 900C and 0.6-60 bars) and concentration ranges (1 mg/m{sub n}{sup 3} to 300 g/m{sub n}{sup 3}). The Guideline describes a modular sampling train, and a set of procedures, which include: planning and preparation of the sampling, sampling and post-sampling, analysis, calculations, error analysis and reporting. The modular sampling train consists of 4 modules. Module 1 is a preconditioning module for isokinetic sampling and gas cooling. Module 2 is a particle collection module including a heated filter. Module 3 is a tar collection module with a gas quench (optionally by circulating a liquid), impinger bottles and a backup adsorber. Module 4 is a volume-sampling module consisting of a pump, a ...

Energy Technology Data Exchange (ETDEWEB)

The pharmacological properties of medicinal plants have been related to the presence of organic compounds, however elements are also known to have an important participation in the active compounds constitution process. In this study, instrumental neutron activation analysis (INAA) was applied to determine elements in leaves of Casearia obliqua medicinal plant collected at two different locations in the Atlantic Forest, Brazil, SP. Soil samples collected from where this plant was grown were also analyzed in order to verify if there is a correlation between the elements present in soils and plant leaves. Br, Ca, Cl, Co, Cr, Cs, Fe, K, La, Mn, Na, Rb, Sb, Sc and Zn were determined in C. obliqua leaves and the elements As, Ca, Ce, Eu, Fe, Hf, La, Lu, Nd, Rb, Sc, Sm, Tb, Th, U and Zn in soils. Soil samples collected from two different locations presented similar concentrations for most elements. Likewise, C. obliqua leaves collected from the two ...

International Nuclear Information System (INIS)

Aim: Rheumatoid arthritis is a limiting disease having, among its pathological features, the inflammation of synovial tissue with progressive and later destruction of the articulation. This leads to joint deformation and loss of its function, generating pain and reducing the mobility of the affected articulation. The aim was to evaluate "1"6"6Ho-Hydroxyapatite ("1"6"6 Ho-HA) as potential radiopharmaceutical for the symptomatic treatment of chronic and acute arthritis. Materials and Methods: Holmiun-166 was produced by irradiation of Ho_2O_3 at La Reina Research Reactor, Nuclear Chilean Energy Commission. Hydroxyapatite was in-house synthesized. Its labelling and quality controls follows the internationally accepted procedures. An antigen's arthritis was induced to eight New Zealand rabbits with the "1"6"6 Ho-HA radiochemical being administered thereafter in two dosage modalities (single and double). The compound therapeutic efficiency was ...

International Nuclear Information System (INIS)

The structural parameters of various Haegg phases (H or M_n_+_1AX_n phases) are studied experimentally by x-ray and electron spectroscopies, x-ray diffraction, and ab initio full potential as well as full mutiple scattering theoretical calculations. Experimentally it was found that the structure of all ternary compounds analyzed herein are relaxed. The values of the lattice parameters and relaxations obtained from ab initio calculations are in excellent agreement with those deduced from the analysis of the experimental data. The bonding scheme has been analyzed and the charge transfer between constituting atoms determined. It is demonstrated that the strength and electrical transport properties in these materials are principally governed by the metallic planes. For the solid solution (Ti_0_._5Nb_0_._5)_2AlC, the most salient result is that the basal planes are corrugated, which could explain the solid solution scattering observed in this H ...

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence analysis is a method, which has many advantages for analysing various historic artefacts, as it is relatively cheap, sensitive and non-destructive, and it allows measurements in-situ. However, this analysis has also certain limitations especially concerning sensitivity to chemical elements only, irrespective of the compounds or chemical forms in which these elements have been bonded. In addition, light elements emitting very soft X-rays cannot be measured, and in order to detect a wide range of elements, it is necessary to carry out repeated measurements with different radiation sources. Despite these limitations, valuable information can be obtained about the composition of historic materials and data about the origin and age of these artefacts can be derived. Analyses of wall paintings, ancient metal sculptures or other objects of art provide the basis for historic considerations documented in our results for ...

International Nuclear Information System (INIS)

We have performed X-ray magnetic diffraction (XMD) experiment of ferromagnets at the Photon Factory (PF) of the High Energy Accelerator Research Organization (KEK) in Tsukuba. In this study, we have upgraded the XMD experimental system in order to apply this method to as many samples as possible. Upgrade was made for (1) the X-ray counting system and related measurement program, (2) the electromagnet, and (3) the refrigerator. The performance of the system was enhanced so that (1) the counting rate capability was improved from 104cps to 105cps, (2) the maximum magnetic field was increased from 0.85T to 2.15T, and (3) the lowest sample temperature was reduced from 15K to 5K. The new system was applied to an orbital ordering compound of YTiO3, and we obtained spin magnetic form factor for the reflection plane (010) perpendicular to the b axis. The magnetic field of 2T was needed to saturate the magnetization of YTiO3 along the b axis. These are the first data with ...

British Library Electronic Table of Contents (United Kingdom)

The pentenary compound semiconductor Cu(In,Ga)(Se,S)2 is one of the most attractive materials for high-efficiency solar cells due to its tunable band gap to match well the solar spectrum. In this study, semiconducting Cu(In,Ga)(Se,S)2 thin films were prepared by a classical two-step growth process, which involves the selenization and/or sulfurization of In/Cu?Ga precursor. During the precursor formation step metallic In/Cu?Ga alloys were deposited onto the Mo-coated soda-lime glass substrates by DC magnetron sputter process. The respective precursors were subsequently reacted with H2Se and/or H2S gasses, at elevated temperatures. By optimizing the selenization parameters, such as the gas concentrations, reaction time, reaction temperature, and the flow of H2Se and H2S, high quality, single...

Energy Technology Data Exchange (ETDEWEB)

One of our research objectives is to develop chemistry of transition metal chalcogenides which are relevant to new inorganic materials, environmental catalysts, metalloenzymes. In this context, this research project has been aimed at rational syntheses of chalcogenide complexes of electron-deficient transition metals, construction of hetero metallic clusters with high nuclearity, and elucidation of chemical properties characteristic of these metal chalcogenide compounds. We were successful in synthesizing a series of sulfide (selenide)/thiolate complexes of group 4,5 and 6 transition metal elements by making use of C-S bond cleaving reactions and anhydrous chalcogenide reagents. We also achieved construction of unprecedented large chalcogenide clusters of mixed metal systems such as [Cu{sub 4}(dppm){sub 4}MS{sub 4}] [PF{sub 6}]{sub 2} (M=Mo, W), [(Cp*WS{sub 3}Ag{sub 2}){sub 2}({mu}-Br){sub 2}]{sub {infinity}}, and [Cp*{sub 2}Mo{sub 2}Fe{sub ...

International Nuclear Information System (INIS)

The profile imaging technique is used to study the oxidation of ZnTe and InP surfaces induced by in situ reaction due to the electron beam of the microscope and by ex situ heating in air. For both materials, in situ reaction with the electron beam resulted in desorption of the anion species and the formation of the metal oxide. The observation of In metal particles, and the fact that the rate of formation of In_2O_3 was substantially reduced by an improvement of the vacuum near the specimen region, suggested that the presence of oxygen is not involved in the desorption process. The ex situ heating of ZnTe up to 260 degrees C in air resulted in crystals of ZnO and Te metal, generally in a layered surface region with the sequence of ZnTe/Te/ZnO. The large Te crystals usually had an epitaxial relationship with the bulk ZnTe but the small ZnO crystals had random orientations. The ex situ heating of InP to 380 degrees C in air only gave rise to small crystals of In_2O_3 ...

International Nuclear Information System (INIS)

Superconducting Cu-rich composites containing the A-15 compounds V_3Si or V_3Ga were made by the ''Tsuei'' process (melting into ingots followed by cold working and heat treatment). Superconducting transition temperatures of the composites were measured. X-ray diffraction analyses were performed. Microstructures were studied using both the optical metallograph and the scanning electron microscope. For some composites containing V_3Ga, the critical current densities as functions of transverse magnetic field up to 60 kG, and as functions of temperature from 4.2 to 12"0K were measured. It was found that the Tsuei process does not work for the composites containing V_3Si, but works satisfactorily for V_3Ga; reasons are discussed. Relations between measured properties and various metallurgical factors such as alloy compositions, cross-section reduction ratios, and heat treatment are discussed. The mechanism for the observed superconductivity in the ...

International Nuclear Information System (INIS)

The production of radiopharmaceuticals used in positron emission tomography (PET) can require large amounts of activity at the start of synthesis in order to yield sufficient labeled material for clinical studies. Several investigators have developed remote and automated systems for the routine production of PET radiopharmaceuticals in order to reduce radiation exposure to personnel. Such devices, however, suffer from limited flexibility and can be relatively complicated in design. These systems are also limited to the production of a single or a few closely related compounds. Furthermore, changes in chemistry would require considerable modifications in hardware and/or software in order to bring the device back into operation. To circumvent the above limitations associated with the remote production of PET radiopharmaceuticals, the authors have investigated the use of laboratory robotics as a flexible alternative to the synthesis of several ...

British Library Electronic Table of Contents (United Kingdom)

Purpose Radiation-induced heart disease (RIHD) is a severe side effect of thoracic radiotherapy. This study examined the effects of pentoxifylline (PTX) and a-tocopherol on cardiac injury in a rat model of RIHD. Methods and Materials Male Sprague-Dawley rats received fractionated local heart irradiation with a daily dose of 9 Gy for 5 days and were observed for 6 months after irradiation. Rats were treated with a combination of PTX, 100 mg/kg/day, and a-tocopherol (20 IU/kg/day) and received these compounds either from 1 week before until 6 months after irradiation or starting 3 months after irradiation, a time point at which histopathologic changes become apparent in our model of RIHD. Results Radiation-induced increases in left ventricular diastolic pressure (in mm Hg: 35 +- 6 after sham...

Science.gov (United States)

Certain materials, especially Sn, passivate the rare earth-exchanged Y zeolite (REY) used in petrochemical fluid-cracking catalysts against vanadium degradation caused by V impurities in the feed oil. The mechanism of passivation was investigated here from the standpoint of high-temperature oxide acid-base reaction; i.e., where the controlling factors were considered to be Lewis acid-base reactions between V{sub 2}O{sub 5}, the RE oxides, SnO{sub 2}, etc. Molten salt tests at 680{degree}C showed SnO{sub 2}, presumably because of its acidic nature, to be essentially nonreactive with V{sub 2}O{sub 5} or Na{sub 2}O-V{sub 2}O{sub 5} compounds. A hypothesis was developed to explain how the passivation effect by Sn might result from the unique resistivity of SnO{sub 2} to reaction with V{sub 2}O{sub 5}.

Science.gov (United States)

The specification describes a semiconductor solar cell and fabrication process therefor wherein a thin N-type gallium arsenide layer is deposited on a larger P-type substrate layer which is selected from the group of III-V ternary compounds consisting of aluminum phosphide antimonide, AlPSb, and aluminum indium phosphide, AlInP. P-type impurities are diffused from the substrate layer into a portion of the thin N-type gallium arsenide layer to form P-type region wherein which defines a PN junction in the thin gallium arsenide layer. Thus, the quantity of gallium arsenide required to provide this PN photovoltaic junction layer in the cell is minimized, and th P-type substrate serves as a high bandgap window layer for the cell. Such high bandgap of this window material is especially well suited for efficiently transmitting the blue spectrum of sunlight to the PN junction, thus enhancing the power conversion efficiency of the solar cell.

Energy Technology Data Exchange (ETDEWEB)

Useful bipolar transistor action over the full temperature range from 78 to 823K has been demonstrated for mesa-isolated, liquid-phase epitaxial n/sup +/npn, GaP/Al/sub 0/ /sub 35/Ga/sub 0/ /sub 65/P/GaP/GaP structures. This represents both the highest temperature and the widest temperature range (745K) over which useful solid-state transistor action has ever been demonstrated in any III-V compound semiconductor system. These results imply that the GaP/Al/sub x/Ga/sub 1-x/P chemical system is an excellent materials candidate in which to base a technology for high-temperature electronics and the results also imply the very real possibility of functional solid-state devices and circuits at temperatures in excess of 500/sup 0/C.

International Nuclear Information System (INIS)

For ages, herbs have been used as medicine and food. Nowadays, the interest in phytotherapeutics is increasing as well as the consumer attention. Some biochemical compounds synthesized by plants as alkaloids, phenolics, flavonoids, essential oils, tannins and vitamins, influence the composition of these plant pharmacologicals, which may produce various reactions in the human body. The microbial contamination in these raw plant materials is common, and the radiation processing is one appropriate technique for the reduction of microorganism. In herbs used as food products, the changes in total #beta#-carotene and flavonoids upon the radiation treatment were tested. The powdered and dehydrated herbs were irradiated with "6"0Co gamma rays applying doses of 0, 10, 20 and 30 kGy. The botanical species investigated were rosemary (Rosmarinus officinalis Linne), watercress (Nasturtium officinale R. Br), artichoke (Cynara scolymus Linne) and sweet basil ...

Energy Technology Data Exchange (ETDEWEB)

This report describes the combustion experiments performed using the SP Industry Calorimeter. In addition to measuring parameters such as heat release rate (HRR), mass loss rate, effective heat of combustion and smoke obscuration, considerable effort was put into the characterisation of the smoke gases in order to obtain a basis for evaluations of the toxic potency of the smoke. The materials studied were Nylon 66, polypropene, polystyrene (with and without fire retardant, respectively), PVC and chlorobenzene. A total of 19 large-scale, well ventilated combustions were carried out. The mass of sample burned ranged from 20 kg to 125 kg in an experiment. A procedure was designed for cleaning the smoke gas duct between experiments and was found to be effective. Measurements were carried out for the amounts of O{sub 2}, CO{sub 2}, CO, NO{sub x}, THC (unburned hydrocarbons), HCN, HCl, NH{sub 3} and individual organic compounds in the smoke. ...

Energy Technology Data Exchange (ETDEWEB)

Components of various forest and agricultural residue biomass-including the polyphenolic compounds-were converted into aqueous solution and/or suspension by extraction and digestion. Some biomass components reacted vigorously under alkaline catalysis with formaldehyde and initially showed a high degree of exothermic reaction; however, other components did not react as vigorously under these conditions, indicating that different biomass materials require different methods to obtain optimum reactivity for the copolymerization with phenol. Our primary goal is to develop adhesives capable of producing acceptable bond quality, as determined by the wood products industries` standards, under a reasonable range of gluing conditions. Copolymer resins of phenol, formaldehyde, and biomass components were synthesized and evaluated for gluability of bonding exterior grade structural replaced with chemicals derived from peanut hulls, pecan shell flour, pecan ...

International Nuclear Information System (INIS)

A reaction of aqueous-methanol solutions of thiocarbazide and salycilic aldehyde, taken in a molal ratio of 1:2 on the matrix of oxovanadium(VO) in the presence of aqueous ammonium results in a coordination compound of the VC_1_5H_1_2N_4O_3S composition. Similar compounds are obtained with salts of nickel(2) and copper(2). Complexes of oxovanadium(4) and copper(2) have effective magnetic moments normal for systems with a spin of 1/2. The compound with nickel is diamagnetic. These data agree with the configuration of the coordination compounds obtained.

Science.gov (United States)

... Materials (PREM) Synopsis of Program: The objective of PREM is to enhance diversity in materials ... careers in materials research.The Partnerships for Research and Education in Materials (PREM ...

Science.gov (United States)

... Materials Research - Major Instrumentation Project (IMR-MIP) program in the Division of Materials ... for materials preparation and characterization essential for researchers studying materials in a ...

Science.gov (United States)

... Materials Development Program TECHNOLOGY EDUCATION INSTRUCTIONAL MATERIALS Elementary - High School ... of technology education materials through its Instructional Materials Development (IMD) program. The ...

International Nuclear Information System (INIS)

Both soil and plant samples of nine different plant species grown in soils from southeastern China contaminated with uranium mine tailings were analyzed for the plant uptake and translocation of "2"3"8U, "2"2"6Ra and "2"3"2Th. Substantial differences were observed in the soil-plant transfer factor (TF) among these radionuclides and plant species. Lupine (Lupinus albus) exhibited the highest uptake of "2"3"8U (TF value of 3.7x10"-"2), while Chinese mustard (Brassica chinensis) had the least (0.5x10"-"2). However, in the case of "2"2"6Ra and "2"3"2Th, the highest TFs were observed for white clover (Trifolium pratense) (3.4x10"-"2) and ryegrass (Lolium perenne) (2.1x10"-"3), respectively. "2"3"2Th in the tailings/soil mixture was less available for plant uptake than "2"2"6Ra or "2"3"8U, and this was especially evident for Chinese mustard and corn (Zea mays). The root/shoot (R/S) ratios obtained for different plants and ...

International Nuclear Information System (INIS)

A procedure is described for the isolation and determination of "9"0Sr, "2"2"6Ra, "2"2"8Ra and "2"1"0Pb in food. These nuclides are highly radiotoxic, above all for babies and children. Samples are dry ashed, alkali metals are removed as carbonates. Separation from other matrix ions and separation of Ra, Sr and Pb can be achieved with a column of Sr-Spec, an immobilized crown ether. For activity measurements membrane filters with SrSO_4, Ba(Ra)SO_4 and PbS are prepared. Ra is determined by gamma-spectrometry, "9"0Sr and "2"1"0Pb are determined by low-level-betacounting. The determination limits are 10 mBq/kg for "9"0Sr and "2"1"0Pb and 50 mBq/kg for "2"2"6Ra and "2"2"8Ra. The procedure is useful for all kinds of foodstuff. (orig.).

Energy Technology Data Exchange (ETDEWEB)

Our institute has been investigating laser-produced tin, lithium and xenon plasma for extreme ultraviolet (EUV) light source of EUV lithography system, and found the highest conversion efficiency of 3% at 13.5 nm in 2% bandwidth. In the present paper, we introduce fabrication methods of density-controlled tin targets to generate relatively monochromatic EUV, and higher conversion efficiency than bulk tin. The first method is the nano-template method, where liquid tin solution was immersed into a polymer film with monodispersed size nano-particle. The density can be controlled by tin concentration of the solution. The target can be classified into mass-limited target. We have shown a tendency of monochromatic EUV emission around 13.5 nm with decreasing of tin density. The intensity was higher than tin foil with bulk density. The tendency has a merit to mitigate heat effect of the first EUV mirror. The fabrication method has another merit to control not only density but also the pore ...

Energy Technology Data Exchange (ETDEWEB)

This thesis deals with the special electronic properties of the transition-metal aluminides. Following quasicrystals and their approximants it is shown that even materials with small elementary cells exhibit the same surprising effects. So among the transition-metal aluminides also semi-metallic and semiconducting compounds exist, although if they consist of classic-metallic components like Fe, Al, or Cr. These properties are furthermore coupled with a deep pseusogap respectively gap in the density of states and strongly covalent bonds. Bonds are described in this thesis by two eseential properties. First by the bond charge and second by the energetic effect of the bond. It results that in the caes of semiconducting transition-metal aluminides both a saturation of certain bonds and a bond-antibond alteration in the Fermi level is present. By the analysis of the near-order in form of the so-calles coordination polyeders it has been succeeded to ...

International Nuclear Information System (INIS)

Ti and its alloys (Ti-6Al-4V) have been used in different engineering applications due to their several outstanding properties. Nevertheless, their use in practical applications is limited in many cases due to their poor tribological property. Researches are ongoing on surface modification of Ti based materials by different plasma and ion based techniques to overcome this problem. However, the conventional plasma nitriding techniques have several problems such as formation of an arc, increased possibility of surface contamination due to a comparatively higher operating pressure, production of a very thin nitrided layer after a long processing time, etc. In this present work, the possibility of a new low-pressure plasma nitriding process using a Plasma Enhanced Chemical Vapor Deposition (PECVD) based saddle field fast atom beam source on a Ti-6Al-4V alloy sample is investigated. Plasma nitriding was carried out at 900 deg. C and at a pressure 0.1 Pa for 8 h by using ...

Energy Technology Data Exchange (ETDEWEB)

In order to understand the chemistry of altermetal dopants in antimony oxide, the detailed structural characterization of two ..beta..-Sb/sub 2/O/sub 4/ compounds is reported, Mo-doped ..beta..-Sb/sub 2/O/sub 4/ (1.5 metal%) and V-doped ..beta..-Sb/sub 2/O/sub 4/ (5 metal%). The methods used to characterize these materials are X-ray and neutron diffraction, scanning electron microscopy, Mo K-edge extended X-ray absorption fine structure spectroscopy, and elemental analysis. The atomic position of each of these dopants in Sb/sub 2/O/sub 4/ is radically different as is the overall effect on the host structure. Molybdenum does not substitute for Sb atoms, rather the Mo atoms are found in channels of electron density formed by Sb/sup 3 +/ lone pairs. The two nearest Sb/sup 3 +/ are absent and the oxygen stoichiometry is preserved. The formula is Sb/sub 1.97/Mo/sub 0.015/O/sub 4/. Vanadium incorporates substitutionally for the Sb/sup 3 +/ atoms and ...

Energy Technology Data Exchange (ETDEWEB)

Irradiation-assisted stress corrosion cracking (IASCC) of several types of BWR field components fabricated from solution-annealed austenitic stainless steels (SSs), including a core internal weld, were investigated by means of slow-strain-rate test (SSRT), scanning electron microscopy (SEM), Auger electron spectroscopy (AES), and field-emission-gun advanced analytical electron microscopy (FEG-AAEM). Based on the results of the tests and analyses, separate effects of neutron fluence, tensile properties, alloying elements and major impurities identified in the American Society for Testing and Materials (ASTM) specifications, minor impurities, water chemistry, and fabrication-related variables were determined. The results indicate strongly that minor impurities not specified by the ASTM-specifications play important roles, probably through a complex synergism with grain-boundary Cr depletion. These impurities, typically associated with steelmaking and component ...

International Nuclear Information System (INIS)

The paper describes the production of highly enriched isotopes of uranium, plutonium, americium and curium by electromagnetic separation for scientific and applied researches in physics, chemistry, geology, medicine, biology and other fields. Using the equipment described, the isotopes are produced in quantities sufficient to set up nuclear physical experiments, to produce nuclear reference materials and standard sources for calibration of radiometrical and mass spectrometrical equipment, in radionuclide metrology, etc. For the following isotopes the indicated degrees of isotopic enrichment were achieved: "2"3"3U-99.97%; "2"3"5U-99.97%; "2"3"6U-98.0%; "2"3"8U-99.997%; "2"3"8Pu-99.6%; "2"3"9Pu-99.9977%; "2"4"0Pu-99.9-100%; "2"4"1Pu-96.998%; "2"4"2Pu-97.8-99.96%; "2"4"4Pu-96.7%; "2"4"1Am-99.6%; "2"4"2"mAm-73.6%; "2"4"3Am-99.2-99.94%; "2"4"3Cm-99.99%; "2"4"5Cm-99.998%; "2"4"6Cm-99.8%; "2"4"7Cm-90%, "2"4"8Cm-97%. Methods for preparing layers of highly enriched isotopes ...

British Library Electronic Table of Contents (United Kingdom)

This review focusses on spin crossover complexes with octahedral metal ions which are bound to a tetraazamacrocyclic ligand and additionally either to two monodentate ligands or to one bidentate ligand. Macrocyclic ligands with a sufficiently large ring size prefer to coordinate to metal ions in an equatorial fashion yielding trans-octahedral coordination environments. In contrast, twelve-membered tetraazamacrocycles with high steric rigidity, such as 2,11-diaza[3.3](2,6)pyridinophanes or 2,11-dithia[3.3](2,6)pyridinophane, are prone to form cis-octahedral complexes. While the electronic and the steric properties of the coordinated tetraazamacrocycle in trans-octahedral complexes are very likely responsible for the paucity of observed spin transitions, the cis-octahedral coordination mode ...

Energy Technology Data Exchange (ETDEWEB)

The dd{yields}{sup 4}He{eta} reaction has been investigated near threshold using the ANKE facility at COSY-Juelich. Both total and differential cross-sections have been measured at two excess energies, Q=2.6 MeV and 7.7 MeV, with a subthreshold measurement being undertaken at Q=-2.6 MeV to study the physical background. While consistent with isotropy at the lower energy, the angular distribution reveals a pronounced anisotropy at the higher one, indicating the presence of higher partial waves. Options for the decomposition into partial amplitudes and their consequences for the determination of the s-wave {eta}{alpha} scattering length are discussed. (orig.)

Science.gov (United States)

Materials World Network: Cooperative Activity in Materials Research between US Investigators and ... Program Title: Materials World Network: Cooperative Activity in Materials Research between US ...

Environmental Research Database

ObjectivesObjectives Not AvailableDescriptionA collaborative study of the anaerobic treatment of wastes containing recalcitrant and inhibitory compounds using the SERC Anaerobic facility, in particular biomass structure, monitoring and control, catabolism and toxicity, pre-acidification and microbial growth and mesophilic and thermophilic lignocellulose degradation.~%~

Energy Technology Data Exchange (ETDEWEB)

The present invention relates to a method of acidizing a subterranean formation or well bore employing an acidic solution containing a corrosion inhibitor composition comprising an inhibiting effective amount of an acetylenic alcohol, a quaternary ammonium compound, an aromatic hydrocarbon and an antimony compound.

UK PubMed Central (United Kingdom)

Iron is a central element in the metabolism of normal and malignant cells. Abnormalities in iron and ferritin expression have been observed in many types of cancer. Interest in characterizing iron compounds...Full Text Available

International Nuclear Information System (INIS)

A brief review is given of the nature of lattice instabilities in high-T/sub c/ superconductors. The Frohlich instability in A-15 compounds is indicated to be a microdomain which acts as an embryo for the Martensitic transformations in these compounds.

Energy Technology Data Exchange (ETDEWEB)

The inhibiting effects of two mineral compounds on corrosion of nickel in phosphoric acid (H[sub 3]PO[sub 4]) polluted by sulfide ions (S[sup 2[minus