Energy Technology Data Exchange (ETDEWEB)
Oil shale resource data are provided for a 1300-square mile area around Farson, Wyoming. The data were derived from analyses of samples from 14 core holes drilled by the US Bureau of Mines and the Department of Energy, plus 4 core holes drilled by private companies. Fischer assay oil yield data for nine stratigraphic resource units are tabulated, correlated, and contoured to provide an assessment of shale oil potential in the area. Oil shale resources in the northeastern part of the Green River Basin occur in the Laney Member and the upper part of the Wilkins Peak Member of the Eocene Green River Formation. A total in-place shale oil resource of 137 billion barrels was calculated for the area. Four stratigraphic resource units have average oil yields of 12 to 20+ gallons per ton within the area of investigation, and in some parts a section up to 275 feet thick averages as much as 15.9 gallons per ton. ...
1988-03-01
Energy Technology Data Exchange (ETDEWEB)
Research highlights: {yields} The use of resonant photoemission in its 'core-hole clock' expression for the study of the dynamical charge transfer across hybrid organic-inorganic interfaces and for the intermolecular charge transfer in the bulk of organic thin films is reviewed. {yields} The electronic coupling to the substrate and the efficiency of charge transport across hybrid interfaces is different for individual electronic subsystems of the molecular adsorbate. {yields} The intermolecular charge transfer in the bulk of discotic liquid crystals occurs on the order of a few femtoseconds and is faster than expected from the macroscopic charge transport characteristics of the material. -- Abstract: The focus of this brief review is the use of resonant photoemission in its 'core-hole clock' expression for the study of two important problems relevant for the field of organic electronics: the dynamical charge ...
2011-01-15
Lifetime of steam turbine parts
International Nuclear Information System (INIS)
The lifetime of technical constructions is determined by many factors. Technical, operational and technological aspects all help to define the term 'lifetime'. Examples from practical operation of steam turbines are considered for a discussion of 'lifetime', and methods of analysis are described. (TK/AK).
1975-02-21
Intercombination transitions in beryllium-like and boron-like iron
Energy Technology Data Exchange (ETDEWEB)
Beam-foil spectroscopy techniques have been used to study intercombination transitions in Be-like Fe{sup 22+} and B-like Fe{sup 21+}. The method of time delayed spectroscopy was used to identify the Be-like 2s{sup 2} {sup 1}S{sub 0}-2s2p {sup 3}P{sub 1} and B-like 2s{sup 2}2p {sup 2}P{sub 3/2}-2s2p{sup 2} {sup 4}P{sub 5/2} transitions. Intensity decay curves for these transitions were recorded and level lifetimes were obtained. The latter were found to be 17.5 {+-} 1.5 ns for the Be-like 2s2p {sup 3}P{sub 1} level and 14.8 {+-} 1.0 ns for the B-like 2s2p{sup 2} {sup 4}P{sub 5/2} level. (orig.).
1997-04-01
Near-edge structures from first principles all-electron Bethe-Salpeter equation calculations
International Nuclear Information System (INIS)
We obtain x-ray absorption near-edge structures (XANES) by solving the equation of motion for the two-particle Green's function for the electron-hole pair, the Bethe-Salpeter equation (BSE), within the all-electron full-potential linearized augmented plane wave method (FPLAPW). The excited states are calculated for the Li K-edge in the insulating solids LiF, Li_2O and Li_2S, and absorption spectra are compared with independent particle results using the random phase approximation (RPA), as well as supercell calculations using the core-hole approximation within density functional theory (DFT). The binding energies of strongly bound excitations are determined in the materials, and core-exciton wavefunctions are demonstrated for LiF.
2009-03-11
Tunable Gas Lasers Utilizing Ground State Dissociation
... the effective lifetime of the excited states against spontaneous radiation is only a fe- times the natural lifetime and collisional destruction by ...
1972-09-15
Physical interpretation of recent isomer investigations
International Nuclear Information System (INIS)
... lifetime lutetium isotopes lutetium 171 lutetium 173 lutetium 175 lutetium 177
1975-08-01
Energy Technology Data Exchange (ETDEWEB)
A continuous, subsurface Cretaceous-Tertiary boundary section, including the boundary clay within an 87 cm thick lignite, has been recovered from a core hole near Wood Mountain, Saskatchewan, Canada. The lignite-encompassed clay layer with geochemical anomaly indicates that peat deposition was continuous across the boundary. Core data indicate that, locally, a pre-boundary, conifer-dominated swamp was abruptly replaced by an angiosperm-dominated, herbaceous wetland. Sudden extermination of the dominant forest elements indicates mass kill at the level of the boundary and supports the theory of extraterrestrial impact accompanied by catastrophic destruction. Devastation of the standing vegetation may have been caused by one or more of the killing agents predicted to have accompanied impact, including freezing temperatures caused by atmospheric dust, acid rain, thermal pulse, and shock waves. There is no evidence supporting wildfires as a killing ...
1999-05-01
Measurement of the cosmic-ray antiproton flux and a search for an antihelium
Energy Technology Data Exchange (ETDEWEB)
A balloon-borne instrument has measured the cosmic-ray antiproton flux between 130 and 320 MeV and searched for antihelium between 130 and 370 MeV per nuclear. These particles were selected from the background of normal-matter cosmic rays by combining a selective trigger with a detailed spark chamber visualization of each recorded event. Antiprotons are identified by their characteristic annihilatin radiation. Residue from background processes meeting the selection criteria is small. The observed 14 antiprotons yield a measured differential flux of 1.7 +- 0.5 x 10/sup -4/ antiprotons m/sup -2/ sr/sup -1/ s/sup -1/ MeV/sup -1/ at the top of the atmosphere. The corresponding antiproton/proton ratio is 2.2 +- 0.6 x 10/sup -4/,, only slightly smaller than the ratio observed by other experiments at higher energies. Thus the antiprotons have a spectral shape similar to the protons, at least down to about 100 MeV. The expected flux of these particles ...
1981-09-15
Energy Technology Data Exchange (ETDEWEB)
Stargardt`s disease is inherited as an autosomal recessive condition characterized by a juvenile macular dystrophy. Genetic linkage analysis recently assigned the disease locus to chromosome 1p21-p13 with the best estimate for location of the gene near the locus D1S435. We performed linkage analysis in 34 North American families and 2 inbred families from the Kingdom of Saudi Arabia with 12 highly polymorphic markers on chromosome 1p flanking D1S435 between D1S207 and D1S223 and report significant linkage for all 12 markers with no evidence for genetic heterogeneity. Two-point linkage analysis demonstrated the Stargardt`s disease locus and D1S435 are linked with a maximum lod score of 17.17 at a recombination fraction of 1%. The markers UT851, ...
1994-09-01
Reliability and Validity of an Internet-based Questionnaire Measuring Lifetime Physical Activity
UK PubMed Central (United Kingdom)
Lifetime exposure to physical activity is an important construct for evaluating associations between physical activity and disease outcomes, given the long induction periods in many chronic diseases....Full Text Available
2010-11-15
The Effect of Compressive Loading on the Fatigue Lifetime of ...
... Coupon 119 * 52 Probability of Survival Versus Ultimate Compressive Strength for Un-notched Laminate 1 Coupon ipn ...
1979-10-01
Lifetime of 2.734 mev Sr"8"8 level
International Nuclear Information System (INIS)
... range 01-10 nuclei photons radiation sources recoils resonance scattering
Heavy-ion accelerators and predicted lifetimes of highly stripped ions
International Nuclear Information System (INIS)
(Sep 1973). United Kingdom Sinanoglu, O. Luken, W. Yale Univ., New Haven,
1973-01-01
Full potential all electron positron lifetime calculations: assessment of local enhancement factors
International Nuclear Information System (INIS)
We report the implementation of positron wave function and lifetime calculations in the all-electron full-potential linearized augmented plane wave method. Calculations of lifetimes for more than 30 materials with two different forms of the enhancement factor were done and compared to prior calculations and experiment. We find that reasonable agreement with experiment can be obtained within the local density approximation when all-electron full-potential calculations are done.
2008-04-01
Line shapes for some specific transitions in Hydrogenic, Lithium-like, and Helium-like ions
Energy Technology Data Exchange (ETDEWEB)
A set of computer codes have been developed to produce spectral line shapes of highly stripped ions for a number of transitions in Hydrogenic, Helium-like and Lithium-like species. The choice of the transitions has been dictated largely by the laser compression experiments. The transitions of Hydrogenic species are: Lyman ..cap alpha..; Lyman ..beta..; Lyman ..gamma..; Lyman delta; Balmer ..cap alpha..; and Balmer ..beta... The transitions of Helium-like species are: 1s/sup 2/(/sup 1/S/sub 0/)-1s2p(/sup 1/P); 1s/sup 2/(/sup 1/S/sub 0/)-1s3p(/sup 1/P); 1s/sup 2/(/sup 1/S/sub 0/)-1s4p(/sup 1/P) and the associated ...
1980-12-29
Influence of the X-ray radiation on the lifetime of carriers in the p-n junctions of Si and Ge
International Nuclear Information System (INIS)
Lifetime of minority charae carriers in the Si and Ge p-n unctions has been measured by pulse method of conductivity modulation of base. Its dependence on the X-ray radiation dose has been investigated. Dependence of current transmission coefficients on the dose has been measured and their sharp decrease at low doses and the following saturation at high doses have been observed. Linear dependence of lifetime on X-ray radiation dose has been obtained. Resulting from the comparison of regularities of the change of lifetime due to current characteristics, it has been shown that X-ray radiation leads to the formation of the surface defects, influencing the change of current characteristics as well as to stationary structural defects, causing the decrease of lifetime of the charge carriers with the increase of X-ray radiation dose.
Frequency evaluation of the doubly forbidden $^1S_0\\to ^3P_0$ transition in bosonic $^{174}$Yb
We report an uncertainty evaluation of an optical lattice clock based on the $^1S_0\\leftrightarrow^3P_0$ transition in the bosonic isotope $^{174}$Yb by use of magnetically induced spectroscopy. The absolute frequency of the $^1S_0\\leftrightarrow^3P_0$ transition has been determined through comparisons with optical and microwave standards at NIST. The weighted mean of the evaluations is $\
2008-01-01
Energy Technology Data Exchange (ETDEWEB)
Due to changed operational conditions and because of the increasing age of several hydro power plant components, there is an increasing risk of damages and the control of degradation mechanisms is of increasing significance. Therefore lifetime considerations for safety relevant components in pumped-storage plants become more and more important. The development of a lifetime management system, in conjunction with monitoring systems and specific surveillance for a group of pumped-storage power plants of different ages and in a wide range of power output is presented. The special focus is on the impact of fatigue strength considerations within this framework. The applied procedure will be described for typical mechanical components in pumped-storage plants exemplarily. (orig.)
2010-07-01
We demonstrated that the intensity levels and lifetimes of two-photon autofluorescences (2PAF) in human liver tissues can be exploited to diagnose hepatocellular carcinoma (HCC). Excited by an infrared femtosecond laser, we suppressed the two-photon autofluorescences of most endogenous fluorophores and made red autofluorescences more specific to particular molecules in the cryo-sectioned human livers. Using such fluorescence contrast, we found HCC tissues have reduced levels of 2PAF and longer fluorescence lifetime.
2011-02-01
Systems MEMS sensors C11-20 Lifetime Distributions of Aluminum Electrolytic Capacitors C11-22 Adhesion Strength of Advanced Polymer Films for Flexible and Rigid...
2011-03-15
Statistical estimation of the lifetimes of charmed particles
Energy Technology Data Exchange (ETDEWEB)
Various statistical methods for the estimation of the mean lifetimes of charmed particles have been considered. It is shown that the usual estimates of the maximum likelihood in some cases do not exist or may have rather great positive bias, if the statistics are low. Alternative estimates of the mean lifetime tau are discussed. Among them the 'jackknife' estimate of tau is considered. The minimum variance unbiased estimates of the average rate of decay 1/tau have been derived for some particular cases. It is also shown that the usual estimate of the ratio of the mean lifetimes of different kinds of particles may also have a bias when the statistics are poor. Two methods of reducing this bias have been proposed.
1984-12-15
On the statistical estimation of the lifetimes of charmed particles
Energy Technology Data Exchange (ETDEWEB)
Various statistical methods for the estimation of the mean lifetimes of charmed particles have been considered. It is shown that the usual estimates of the maximum likelihood in some cases do not exist or may have rather great positive bias, if the statistics are low. Alternative estimates of the mean lifetime tau are discussed. Among them the 'jackknife' estimate of tau is considered. The minimum variance unbiased estimates of the average rate of decay 1/tau have been derived for some particular cases. It is also shown that the usual estimate of the ratio of the mean lifetimes of different kinds of particles may alos have a bias when the statistics are poor. Two methods of reducing this bias have been proposed. (orig.).
1984-12-15
Influence of absorbed hydrogen on the positron lifetime spectra in Pd, Pd-Ag, Pd-Cu
International Nuclear Information System (INIS)
(1 Oct 1979). German Democratic Republic Alekseeva, OK Onishchuk, VA
1979-10-01
GAMMA SPECTRA AND PERIODS OF FOUR ODD-A ISOTOPES OF TUNGSTEN AND TANTALUM
The gamma spectra and lifetimes of the Ta and W isotopes havimg mass numbers 173, 175, 177, and 179 are determined. (T.F.H.)
1963-06-01
Electric and magnetic dipole transitions in odd-proton rare-earth nuclei
International Nuclear Information System (INIS)
... gamma cascades kev range 10-100 lifetime lutetium 171 lutetium 173 lutetium
1972-05-01
Theoretical transition energies, lifetimes and fluorescence yields of multiply ionized silicon
Energy Technology Data Exchange (ETDEWEB)
Theoretical x-ray transition energies, lifetimes and partial multiplet fluorescence yields are presented for all spectroscopic terms of electron configurations with a single K-shell vacancy and varying number of electrons in the L-shell and M/sub 1/-subshell for multiply-ionized silicon. 9 tables.
1982-01-01
Investigation of lifetimes in the dipole band of {sup 139}Sm
Energy Technology Data Exchange (ETDEWEB)
Lifetimes have been measured for a dipole band in {sup 139}Sm using DSAM. The deduced B(M1) and B(E2) values as well as B(M1)/B(E2) ratios are compared with calculations in the framework of the TAC (Tilted Axis Cranking) and SPAC (Shears mechanism with Principal Axis Cranking) models. The dipole band in {sup 139}Sm can be considered as a magnetic rotational band with a prolate or triaxial nuclear deformation. (orig.)
2008-09-15
Investigation of lifetimes in dipole bands of {sup 142}Gd
Energy Technology Data Exchange (ETDEWEB)
Lifetimes have been measured for dipole bands in {sup 142}Gd using DSAM. The deduced B(M1) and B(E2) values as well as B(M1)/B(E2) ratios are compared with calculations in the framework of the TAC (Tilted Axis Cranking) and SPAC (shears mechanism with Principal Axis Cranking) models. The dipole bands DB1 to DB4 can be interpreted as magnetic rotational bands. (orig.)
2005-02-01
Defect influence on the T/sub c/ of A-15 compounds
The defect-induced electron lifetime and energy-gap anisotropy effects on the T/sub c/ of the A-15 compounds are examined. A self-consistent model calculation demonstrates that the various defect dependences of T/sub c/ can be qualitatively understood in terms of the electron-lifetime effect.
1979-10-01
Defect influence on the T/sub c/ of A-15 compounds
International Nuclear Information System (INIS)
The defect-induced electron lifetime and energy-gap anisotropy effects on the T/sub c/ of the A-15 compounds are examined. A self-consistent model calculation demonstrates that the various defect dependences of T/sub c/ can be qualitatively understood in terms of the electron-lifetime effect.
Advances in Old-Fashioned Heterotic String Model Building
I review findings of various research groups regarding perturbative heterotic string model building in the last 12 months. Attention is given to recent studies of extra U(1)'s and local discrete symmetries (LDS's) in generic string models. Issues covered include the role of U(1)'s and LDS's in limiting proton decay, developments in classification of models containing anomalous U(1), and possible complications resulting from kinetic mixing between observable and hidden sector U(1)'s. Additionally, recent string-derived and string-inspired models are briefly reviewed. Talk Presented at SUSY '97.
1998-01-01
The Canonical Seyfert Spectrum: The Implications of OSSE ...
... In a HEAO 1 study of active galaxies, principally Seyfert 1s, in the 2, 165 keV energy range, Rothschild et al. ... As discussed by Rothschild et al. ...
2011-05-14
Infantry Behind the Lines-Still a Viable Concept?
Page 1. S~Infantry Behind the Lines- Still A Viable Concept? A Monograph by Major Mike McMahon Infantry 4T-' School ...
1993-12-17
International Nuclear Information System (INIS)
Absolute total cross sections for electron-impact excitation of the 3s"2"1S#->#3s3p"3P and 3s"2"1S#->#3s3p"1P transitions in Si"2"+ were measured using the merged electron-ion beams energy-loss technique. The results are compared to R-matrix close-coupling theory, which predicts a strong resonance enhancement of the cross section near the threshold for excitation of the "3P state and this is confirmed by the experiments. The observed disagreement between theory and experiment for the dipole excitation is suggested to be due to resonance interference. copyright 1997 The American Physical Society.
g factors and lifetimes for 2_1"+ states of sup(84,86,88)Sr
International Nuclear Information System (INIS)
The g factors of the 2_1"+ states in sup(84,86,88)Sr have been deduced using the thin-foil transient field technique with the field calibration of the Rutgers group. The values are g("8"4Sr)= + 0.419(47), g("8"6Sr)= + 0.273(50) and g("8"8Sr)= + 1.15(17). The mean lifetimes of the 2_1"+ states in sup(86,88)Sr were determined by the Doppler-shift attenuation method to be 2.10(22) ps and 0.219(23) ps respectively. The g factor and lifetime results are compared with shell model and interacting boson model predictions. (author).
The estimation of lifetime distribution of Alloy 800 steam generator tubing
Energy Technology Data Exchange (ETDEWEB)
Alloy 800 has been used for steam generator (SG) tubing for more than 30 years, primarily in CANDU reactors worldwide and in reactors in Germany. Extensive laboratory testing and in-service experience suggest that the Alloy 800 tubing has excellent resistance to corrosion-related degradation under appropriate operating conditions. In planning refurbishment of nuclear plants stations, a key concern is the longevity of existing SGs up to the 60-year lifetime of the refurbished plant. The paper reviews an existing methodology based on the concept of the improvement factor, and refines its estimation based on data specific to CANDU operating conditions. The paper presents a more advanced Bayesian probabilistic approach to estimate the degradation free lifetime distribution of Alloy 800 tubing, which is used to quantify the probability of degradation during the service life and to evaluate the impact of potential occurrences of degradation on ...
2009-10-15
The estimation of lifetime distribution of Alloy 800 steam generator tubing
International Nuclear Information System (INIS)
Alloy 800 has been used for steam generator (SG) tubing for more than 30 years, primarily in CANDU reactors worldwide and in reactors in Germany. Extensive laboratory testing and in-service experience suggest that the Alloy 800 tubing has excellent resistance to corrosion-related degradation under appropriate operating conditions. In planning refurbishment of nuclear plants stations, a key concern is the longevity of existing SGs up to the 60-year lifetime of the refurbished plant. The paper reviews an existing methodology based on the concept of the improvement factor, and refines its estimation based on data specific to CANDU operating conditions. The paper presents a more advanced Bayesian probabilistic approach to estimate the degradation free lifetime distribution of Alloy 800 tubing, which is used to quantify the probability of degradation during the service life and to evaluate the impact of potential occurrences of degradation on ...
2009-10-01
System, economy and ecology viewpoints of the Krsko NPP lifetime extension
International Nuclear Information System (INIS)
Krsko NPP plant life extension was analysed and evaluated with respect to system, economy and ecology viewpoints. From the system perspective it was established that also in the extended lifetime the plant will remain in operation as a base load electricity supplier. The systematic review was performed to determine its overall competitiveness against advanced coal, gas and new nuclear units. The analysis considered also hydro and renewable sources. Analysis and evaluations resulted in the conclusion that the Krsko NPP lifetime extension is the most effective alternative for base load production due to small additional capital investments, low fuel costs, no new siting requirements, lowest climate and environmental impact, and reliable and safe operation. (author)
2007-09-10
G factors and lifetimes for 2/sub 1//sup +/ states of sup(84,86,88)Sr
Energy Technology Data Exchange (ETDEWEB)
The g factors of the 2/sub 1//sup +/ states in sup(84,86,88)Sr have been deduced using the thin-foil transient field technique with the field calibration of the Rutgers group. The values are g(/sup 84/Sr)= + 0.419(47), g(/sup 86/Sr)= + 0.273(50) and g(/sup 88/Sr)= + 1.15(17). The mean lifetimes of the 2/sub 1//sup +/ states in sup(86,88)Sr were determined by the Doppler-shift attenuation method to be 2.10(22) ps and 0.219(23) ps respectively. The g factor and lifetime results are compared with shell model and interacting boson model predictions.
1988-01-01
Dissociative electron attachment to CCl_4: Lifetime of the CCl_4"- intermediate
International Nuclear Information System (INIS)
Dissociative electron capture to CCl_4 is studied by measuring the angular and velocity distribution of Cl"- ions produced in collisions with velocity selected K(np) Rydberg atoms. Analysis of the data using a Monte Carlo collision code that models the detailed kinematics of the reaction indicates that the lifetime of the CCl_4"- intermediate formed by Rydberg electron capture is 7.5 #+-# 2.5 ps and that, upon dissociation, only a small fraction of the excess energy of reaction appears as translational energy of the Cl"- and CCl_3 fragments. The present approach is one of the few experimental techniques yet devised that can probe the lifetimes of collisionally-produced excited states on a picosecond timescale, and demonstrates that Rydberg atoms provide a unique tool with which to investigate the dynamics of dissociative electron attachment. Measurements are being extended to additional species, including CFCl_3.
1996-05-15
Energy Technology Data Exchange (ETDEWEB)
Knowledge, assessment and understanding of phenomena caused by ageing, together with systematic utilization and extension of the technical life-time of components and systems, are of critical importance to the safety and economy of electricity generation in nuclear power stations. Economic use can be optimized by integrated ageing and life-time management; it can also be used to improve performance characteristics. (orig.) [Deutsch] Fuer die Sicherheit und Wirtschaftlichkeit der Stromerzeugung in Kernkraftwerken sind die Kenntnis, Bewertung und Beherrschung alterungsbedingter Phaenomene und systematische Ausnutzung bzw. Verlaengerung der technischen Lebensdauer der Komponenten und Systeme von zentraler Bedeutung. Durch ganzheitliches Alterungs- und Lebensdauermanagement, das auch auf die Verbesserung von Leistungsmerkmalen abzielt, kann der wirtschaftliche Nutzen optimiert werden. (orig.)
1999-07-01
A probabilistic approach to the estimation of lifetime distribution of Alloy 800 SG tubing
Energy Technology Data Exchange (ETDEWEB)
Alloy 800 has been used for steam generator (SG) tubing for more than 30 years, primarily in CANDU reactors and in reactors in Germany. Extensive laboratory testing and in-service experience suggest that the Alloy 800 tubing has excellent resistance to corrosion-related degradation under specified and appropriate operating conditions. In planning refurbishment of CANDU stations, a key concern is the longevity of existing SGs up to the 60 year lifetime of the refurbished plant. The paper reviews an existing methodology based on the concept of the improvement factor, and estimates it based on experimental data specific to CANDU operating conditions. The paper presents a more advanced probabilistic approach to estimate the degradation free lifetime distribution of Alloy 800 tubing, which is used to quantify the probability of degradation during the service life and to evaluate the impact of potential occurrences of degradation on reliability of SG ...
2008-07-01
A probabilistic approach to the estimation of lifetime distribution of Alloy 800 SG tubing
International Nuclear Information System (INIS)
Alloy 800 has been used for steam generator (SG) tubing for more than 30 years, primarily in CANDU reactors and in reactors in Germany. Extensive laboratory testing and in-service experience suggest that the Alloy 800 tubing has excellent resistance to corrosion-related degradation under specified and appropriate operating conditions. In planning refurbishment of CANDU stations, a key concern is the longevity of existing SGs up to the 60 year lifetime of the refurbished plant. The paper reviews an existing methodology based on the concept of the improvement factor, and estimates it based on experimental data specific to CANDU operating conditions. The paper presents a more advanced probabilistic approach to estimate the degradation free lifetime distribution of Alloy 800 tubing, which is used to quantify the probability of degradation during the service life and to evaluate the impact of potential occurrences of degradation on reliability of SG ...
2008-06-01
Charmonium with three flavors of synamical quarks
Energy Technology Data Exchange (ETDEWEB)
We present a calculation of the charmonium spectrum with three flavors of dynamical staggered quarks from gauge configurations that were generated by the MILC collaboration. We use the Fermilab action for the valence charm quarks. Our calculation of the spin-averaged 1P-1S and 2S-1S splittings yields a determination of the strong coupling, with {alpha}{sub {ovr MS}}(M{sub Z}) = 0.119(4).
2003-12-23
A YAC contig encompassing the recessive Stargardt disease gene (STGD) on chromosome 1p
Energy Technology Data Exchange (ETDEWEB)
Stargardt disease (STGD) and fundus flavimaculatus are infrequent autosomal recessive conditions characterized by a juvenile macular dystrophy and variable degrees of peripheral retinal changes. Linkage analysis performed in 47 STGD/fundus flavimaculatus families demonstrated significant linkage to 13 polymorphic DNA markers on chromosome 1p. The maximum combined two-point lod score was 32.7 (maximum recombination fraction [{theta}{sub max}] = .006) with the polymorphic marker D1S188. Our data demonstrate that STGD and fundus flavimaculatus are the same disorder clinically and genetically and provide further evidence for genetic homogeneity of this phenotype. Analysis of recombination on disease chromosomes placed the STGD gene within a 4-cM interval between markers D1S435 and D1S236. A physical map was constructed of a YAC contig flanking STGD, from markers ...
1995-12-01
UK PubMed Central (United Kingdom)
Objective:This article examines relationships between reproductive onset and lifetime history of smoking, regular smoking, and nicotine dependence, and cannabis and other illicit...Full Text Available
2009-09-01
SN1987A: The supernova of a lifetime
Energy Technology Data Exchange (ETDEWEB)
The current status of cosmological observations is presented; and the light curves and radiation spectra from supernova SN1987A are used in comparison between expected and observed universal nucleosynthesis and star evolution data./aip/.
1988-09-20
UK PubMed Central (United Kingdom)
The classic evolutionary theory of aging explains why mortality rises with age: as individuals grow older, less lifetime fertility remains, so continued survival contributes less to reproductive fitness....Full Text Available
2003-08-05
Quantifiable Biomarkers of Normal Aging in the Japanese Medaka Fish (Oryzias latipes)
UK PubMed Central (United Kingdom)
BackgroundSmall laboratory fish share many anatomical and histological characteristics with other vertebrates, yet can be maintained in large numbers at low cost for lifetime studies....Full Text Available
UK PubMed Central (United Kingdom)
ObjectiveLimited data is available to understand the prevalence and correlates of suicidal behavior among U.S. Latino subgroups. This paper compares the prevalence...Full Text Available
2007-04-01
UK PubMed Central (United Kingdom)
Polyandrous mating is common, but the benefits for females of polyandry remain controversial. To test whether mating with multiple males affects female fitness, we compared lifetime components of fitness...Full Text Available
2010-08-03
Energy Technology Data Exchange (ETDEWEB)
GaN and Al{sub 1{minus}x}Ga{sub x}N films were grown by the method of ECR-MBE. Absorption constants as a function of wavelength were determined from transmission measurements. Photoconducting detectors were fabricated from these films and characterized in terms of their spectral response and photoconductive gain. Mobility-lifetime products were determined from the measurement of photoconductive gain. The resistivity and mobility-lifetime products of the films were varied from 10--10{sup 9} ohm-cm and 10{sup {minus}3}--10{sup {minus}8} cm{sup 2}/V respectively by changing the microwave power in the ECR discharge from 20--60 watts. The change in the mobility-lifetime product is attributed to change in the lifetimes of the photogenerated carriers. This assumption is supported by direct measurement of detector response times. Finally, the authors report for the first time, the detection of alpha particles ...
1997-12-31
International Nuclear Information System (INIS)
GaN and Al_1_-_xGa_xN films were grown by the method of ECR-MBE. Absorption constants as a function of wavelength were determined from transmission measurements. Photoconducting detectors were fabricated from these films and characterized in terms of their spectral response and photoconductive gain. Mobility-lifetime products were determined from the measurement of photoconductive gain. The resistivity and mobility-lifetime products of the films were varied from 10--10"9 ohm-cm and 10"-"3--10"-"8 cm"2/V respectively by changing the microwave power in the ECR discharge from 20--60 watts. The change in the mobility-lifetime product is attributed to change in the lifetimes of the photogenerated carriers. This assumption is supported by direct measurement of detector response times. Finally, the authors report for the first time, the detection of alpha particles using GaN detectors.
1996-12-02
UK PubMed Central (United Kingdom)
The polarity of biological mediums controls a host of physiological processes such as digestion, signaling, transportation, metabolism, and excretion. With the recent widespread use of near-infrared...Full Text Available
2007-10-15
Minority-carrier lifetime damage coefficient of irradiated InP
Energy Technology Data Exchange (ETDEWEB)
Minority-carrier lifetime damage coefficients for 1 MeV electron, 3 MeV proton, and 6 MeV alpha particle irradiation of n-type (4.5{times}10{sup 15} and 1.3{times}10{sup 17}cm{sup {minus}3}) and p-type (2.5{times}10{sup 17}cm{sup {minus}3}) InP have been measured using time-resolved photoluminescence. These values are relatively insensitive to carrier type and show a slight increase with increasing carrier concentration. Evidence of comparable electron and hole capture lifetimes is found for the dominant recombination defect. The effect of 3 MeV proton and 6 MeV alpha particles relative to 1 MeV electrons is an increase in the lifetime damage coefficient by factors of about 10{sup 4} and 10{sup 5}, respectively. {copyright} {ital 1997 American Institute of Physics.}
1997-09-01
International Nuclear Information System (INIS)
The nuclear structure of A #propor to# 100 nuclei has been studied in the frame of this thesis with a recently developed #beta# - #gamma# - #gamma# triple coincidence fast timing technique and different models such as shell model, hydrodynamic model, Nilsson and particle-rotor models. This technique which allows the measurement of the level lifetimes in the ps range has been applied at JOSEF at the research reactor DIDO of KFA Juelich in studes of the short-lived neutron-rich nuclei in the A #approx =# 100 region. Lifetimes of level in "9"6,"9"8,"1"0"0 ZR, "9"9,"1"0"1-"1"0"4 Nb, "1"0"0-"1"0"5 Mo have been measured, which are in many cases completely new, and otherwise more precise than previously published data. From the lifetimes of the members of rotational bands, the size of the nuclear deformations has been deduced. (orig./HSI).
International Nuclear Information System (INIS)
Radiation defects produced by helium implantation were used to shape profiles of palladium (Pd) and platinum (Pt) atoms in-diffusing (for 20 min at temperatures 600-800 deg. C) either from surface silicide (Pd_2Si, PtSi) or implanted layers. Results show that this procedure allows a strong localization of substitutional Pd and Pt at the depth where the damage produced by helium peaks. This results in local reduction of carrier lifetime by an almost ideal recombination centers - the acceptor level of substitutional Pd (E _c - 0.22 eV) or Pt (E _c - 0.23 eV). While optimum conditions for Pt in-diffusion are about 700 deg. C, Pd gives the best results already at lower temperatures (600 deg. C) where it also exhibits higher peak solubility. Both methods were used for optimization of turn-off properties of high power PiN diodes. The devices, where the lifetime was killed locally by Pd and Pt, exhibited similar trade-off between the static and ...
2006-12-01
International Nuclear Information System (INIS)
Radiation-and-thermal-combined degradation of some kinds of cable insulating and jacketing materials was evaluated by accelerated aging tests. Plasticized polyvinyl chloride (PVC), silicone rubber, crosslinked and non-crosslinked halogen-free flame-retardant polyolefins (NH-XLPO and NH-PO) and ethylene-propylene rubber (EP rubber) of experimental formulation were degraded at accelerated rates, that are 50-1000 times the degradation rate under standard conditions (e.g.; 1Gy/h, 50degC), and a method to assess the lifetime of these materials under standard conditions was studied. The degradation was investigated by measuring tensile properties. In the accelerated aging tests, rates of elongation decrease owing to degradation for these materials were in proportion to the increase in accelerated rate. The PVC lifetime estimated from sequential aging tests had a tendency to extend beyond that from simultaneous aging tests, while the ...
1994-01-01
Inhibited spontaneous emission by a Rydberg atom
Spontaneous radiation by an atom in a Rydberg state is inhibited by use of parallel conducting planes to eliminate the vacuum modes at the transition frequency. Spontaneous radiation emission is observed to turn off abruptly at the cutoff frequency of the waveguidelike structure, and the natural lifetime is measured to increase by a factor of at least 20.
1985-11-11
How Children Move: Activity Pattern Characteristics in Lean and Obese Chinese Children
UK PubMed Central (United Kingdom)
Physical activity and sedentary behavior are central components of lifetime weight control; however, our understanding of dimensions of these behaviors in childhood is limited. This study investigated...Full Text Available
2011-01-01
Evidence for Diversity in Transcriptional Profiles of Single Hematopoietic Stem Cells
UK PubMed Central (United Kingdom)
Hematopoietic stem cells replenish all the cells of the blood throughout the lifetime of an animal. Although thousands of stem cells reside in the bone marrow, only a few contribute to blood production...Full Text Available
2006-09-01
Waste management considerations for fusion power reactors
International Nuclear Information System (INIS)
To estimate the waste management needs of a fusion power reactor, a scheme for handling radioactive waste from a fusion plant has been devised. The handling scheme proceeds with radioactive waste, primarily from blanket replacement, being stored on-site; waste in cooled and shielded casks is then isolated off-site; finally, the materials are recycled. Using activities and component lifetimes supplied by designers, several conceptual fusion power reactors have been analyzed and their waste streams compared to fission reactors with regard to total activity, specific activity, and lifetimes of activity.
Waste management considerations for fusion power reactors
To estimate the waste management needs of a fusion power reactor, a scheme for handling radioactive waste from a fusion plant has been devised. The handling scheme proceeds with radioactive waste, primarily from blanket replacement, being stored on-site; waste in cooled and shielded casks is then isolated off-site; finally, the materials are recycled. Using activities and component lifetimes supplied by designers, several conceptual fusion power reactors have been analyzed and their waste streams compared to fission reactors with regard to total activity, specific activity, and lifetimes of activity.
1978-02-01
Positronium formation in liquid nitrogen as a function of electric field
International Nuclear Information System (INIS)
The intensity of the orthopositronium component and its lifetime have been measured in liquid nitrogen as a function of electric field. While the lifetime remains constant at about 12.5 ns, the fraction of positronium formed is about 20% at zero field and decreases monotonically to an asymptotic value near 6% as the field is raised to 3.2 MV m"-"1. The decrease is roughly exponential with a drop off rate of 2.0 MV m"-"1. The results are a further indication of the importance of Mogensen's spur mechanism in the positronium formation process. (author).
1993-07-01
Energy Technology Data Exchange (ETDEWEB)
Lifetimes have been measured in the {pi}h{sub 9/2} (yrast) and {pi}i{sub 13/2} (excited) bands in the nuclei {sup 181}Ir and {sup 187}Au using the Recoil Distance Method (RDM). The results clearly indicate that the {pi}i{sub 13/2} band exhibits an increased deformation over the {pi}h{sub 9/2} band, in keeping with the premise that the delayed crossing in this band is due to enhanced quadrupole deformation. (author). 3 refs, 1 fig, 2 tab.
1995-02-01
Lifetime in "1"8"1Ir and "1"8"7Au: enhanced deformation of the #pi#i _1_3_/_2 intruder orbital
International Nuclear Information System (INIS)
Lifetimes have been measured in the #pi#h_9_/_2 (yrast) and #pi#i_1_3_/_2 (excited) bands in the nuclei "1"8"1Ir and "1"8"7Au using the Recoil Distance Method (RDM). The results clearly indicate that the #pi#i_1_3_/_2 band exhibits an increased deformation over the #pi#h_9_/_2 band, in keeping with the premise that the delayed crossing in this band is due to enhanced quadrupole deformation. (author). 3 refs, 1 fig, 2 tab.
1994-09-05
Energy Technology Data Exchange (ETDEWEB)
Smooth and notched specimens of the bearing steel 100Cr6 (SAE 52100) in a bainitic condition were used to determine the S-N-curves under tensile, torsional and combined in- and out-of-phase loading. In the area of high-cycle-fatigue, crack initiation was most likely caused by inclusions like Titanium Carbonitrides or Aluminium Oxides. A model was developed to describe the influence of the magnitude of these inclusions on the lifetime. A weakest link model, using the statistical distribution of inclusions and surface flaws, was used to describe the fatigue limit. (orig.)
2000-07-01
Determination of the b_s lifetime using hadronic decays
Energy Technology Data Exchange (ETDEWEB)
The authors present a measurement of the B{sub s}{sup 0} meson lifetime using fully and partially reconstructed hadronic decays B{sub s}{sup 0} {yields} D{sub s}{sup -} {pi}{sup +}(X) followed by D{sub s}{sup -} {yields} {phi}{pi}{sup -}. The data sample was recorded with the CDF II detector at the Fermilab Tevatron and corresponds to an integrated luminosity of 1.3 fb{sup -1} from p{bar p} collisions at {radical}s = 1.96 TeV.
2008-07-01
Behavior of the cooling towers as a function of the time
International Nuclear Information System (INIS)
In the scope of the nuclear plants lifetime study, the behavior of the cooling towers is discussed. The main geometrical characteristics of the cooling towers in the French nuclear power plants, are presented. The surveyance program, the risks of accident, the research and development actions are considered. The results of the investigations of the cooling tower structure show that it is a multidiciplinary problem and needs the development of experimental and theoretical methods. Concerning the regenerators, the surveyance actions under operating conditions, the accelerated aging tests, and some aspects of the mechanical resistance, are underlined. It is shown that mainly the creep tests will allow the lifetime estimation of the materials developed for the regenerators.
1988-12-01
International Nuclear Information System (INIS)
The inelastic scattering of the beam and the residual gas molecules in RHIC could represent one of the limitations on the beam life time and emittance growth. This report covers the dominant central nuclear collisions influence on the beam lifetime and transverse emittance growth. The cross sections for the beam-gas electron radiative captures are an order of magnitude smaller. The capture cross sections include the radiative and non-radiative capture, and the capture from the electron-positron pair creation from the 'vacuum capture'.
2010-09-01
A Cautionary Tale: Small Sample Size Concerns for Grouped Lifetime Data
British Library Electronic Table of Contents (United Kingdom)
Often, lifetime data come from experiments where failure times are grouped. The Weibull distribution is a popular distribution for modeling failure times. Maximum likelihood estimation (MLE) has outstanding large sample properties for the Weibull distribution. This article evaluates small sample properties of MLEs for grouped data. We evaluate sample size requirements for MLE asymptotic properties to take effect. We compare type I and type II censoring for pooled experiments and conclude that bias for the shape parameter estimate can be alarmingly high especially for type II censored data. Finally, we investigate the benefits of the pooled analysis.
2011-01-01
Phenomenological analysis of heavy hadron lifetimes
International Nuclear Information System (INIS)
A phenomenological analysis of lifetimes of bottom and charmed hadrons within the framework of the heavy quark expansion is performed. The baryon matrix element is evaluated using the bag model and the nonrelativistic quark model. We find that bottom-baryon lifetimes follow the pattern #tau#(#OMEGA#_b)#approx =##tau#(#XI#_b"-)>#tau#(#LAMBDA#_b)#approx =##tau#(#XI#_b"0). However, neither the lifetime ratio #tau#(#LAMBDA#_b)/#tau#(B_d) nor the absolute decay rates of the #LAMBDA#_b baryon and B mesons can be explained. One way of solving both difficulties is to allow the presence of linear 1/m_Q corrections by scaling the inclusive nonleptonic width with the fifth power of the hadron mass m_H__Q rather than the heavy quark mass m_Q. The hierarchy of bottom baryon lifetimes is dramatically modified to #tau#(#LAMBDA#_b)>#tau#(#XI#_b"-)>#tau#(#XI#_b"0)>#tau#(#OMEGA#_b): The longest-lived ...
$\\eta(2225)$ observed by BES Collaboration
In the framework of the $^3P_0$ meson decay model, the strong decays of the $3 ^1S_0$ and $4 ^1S_0$ $s\\bar{s}$ states are investigated. It is found that in the presence of the initial state mass being 2.24 GeV, the total widths of the $3 ^1S_0$ and $4 ^1S_0$ $s\\bar{s}$ states are about 438 MeV and 125 MeV, respectively. Also, when the initial state mass varies from 2220 to 2400 MeV, the total width of the $4 ^1S_0$ $s\\bar{s}$ state changes from about 100 MeV to 132 MeV, while the total width of the $3 ^1S_0$ $s\\bar{s}$ changes from about 400 MeV to 594 MeV. A comparison of the predicted widths and the experimental result of $(0.19\\pm 0.03^{+0.04}_{-0.06})$ GeV, the width of the $\\eta(2225)$ with a mass of ...
2008-01-01
Characterization of acid sites in pentasil zeolites by x-ray photolectron spectroscopy
Energy Technology Data Exchange (ETDEWEB)
The N{sub 1s} XPS band of pyridine chemisorbed on Al-ZSM-5 zeolite was found to be properly deconvoluted into three component peaks. In a previous contribution these three components were assigned to pyridine chemisorbed on two kinds of Bronsted acid sites and one Lewis acid site. This analysis is extended here to Fe-ZSM-5 and B-ZSM-5. Isomorphous substitution of Fe for Si or Al in the zeolite framework leads to a slight decrease in the binding energy of the N{sub 1s} Lewis component. In the case of B substitution a decrease in the binding energy of all three N{sub 1s} components is observed.
1990-11-01
Identifying related L1 retrotransposons by analyzing 3' transduced sequences
UK PubMed Central (United Kingdom)
BackgroundA large fraction of the human genome is attributable to L1 retrotransposon sequences. Not only do L1s themselves make up a significant portion of the genome, but L1-encoded...Full Text Available
2003-01-01
Lifetime measurements of singlet ungerade states in isotopic molecular nitrogen
International Nuclear Information System (INIS)
Full text: In the upper layers of the Earth's atmosphere, molecular nitrogen absorbs the extreme ultraviolet (XUV) solar radiation. The absorption is associated with dipole-allowed excitation of states of singlet ungerade symmetry ("1#SIGMA#"+_u and "1#PI#_u), which are known to undergo predissociation due to coupling with a mainfold of "1#PI#_u states. We determined new N_2 isotopic lifetimes of many "1#SIGMA#"+_u and "1#PI#_u states via line broadening measurements in the frequency domain. Ultrahigh resolution XUV + UV ionization spectra were recorded (bandwidth #approx# 250 MHz, resolving power 10"7), from which the natural linewidth, i.e. lifetime, was determined. These lifetimes provide new information about the predissociation of the singlet ungerade states in N_2. Tunable narrowband XUV radiation was produced by successively pulsed amplification of cw dye laser radiation, frequency doubling the pulsed visible laser ...
2004-07-19
Application of continuous casting steel 100Cr6 (SAE 52100) for bearing balls
Energy Technology Data Exchange (ETDEWEB)
The objective of the investigation was to study the feasibility of applying continuous casting steel 100Cr6 (SAE 52100) for bearing balls. It was found that two of three continuous casted steel batches have longer or at least similar rolling contact fatigue lifetimes compared to one ingot casted batch. For one of the continuous casted batches, the rolling contact fatigue lifetime was 30% less. The micro- and macrostructure and the residual stresses below the surface of the balls were comparable. There is also no obvious difference between the four batches in the metallurgical parameters like contents of oxygen, titanium and sulfur as well as in the distribution of carbides and their network. The reason for the shorter lifetime of one batch finally was found to be due not to the continuous casting process itself. There was a difference in the cross section of the different casting moulds, and by this in the speed of ...
1998-12-31
Late-onset Stargardt-like macular dystrophy maps to chromosome 1p13
Energy Technology Data Exchange (ETDEWEB)
Stargardt`s disease (MIM 248200), originally described in 1909, is an autosomal recessive condition of childhood, characterized by a sudden and bilateral loss of central vision. Typically, it has an early onset (7 to 12 years), a rapidly progressive course and a poor final outcome. The central area of the retina (macula) displays pigmentary changes in a ring form with depigmentation and atrophy of the retinal pigmentary epithelium (RPE). Perimacular yellowish spots, termed fundus flavimaculatus, are observed in a high percentage of patients. We have recently reported the genetic mapping of Stargardt`s disease to chromosome 1p13. On the other hand, considering that fundus flavimaculatus (MIM 230100) is another form of fleck fundus disease, with a Stargardt-like retinal aspect but with a late-onset and a more progressive course, we decided to test the hypothesis of allelism between typical Stargardt`s disease and late-onset autosomal recessive fundus flavimaculatus. Significant pairwise ...
1994-09-01
The ITER divertor cassette project
International Nuclear Information System (INIS)
The divertor 'Large Project' was conceived with the aim of demonstrating the feasibility of meeting the lifetime requirements by employing the candidate armor materials of beryllium, tungsten (W) and carbon-fiber-composite (CFC). At the start, there existed only limited experience with constructing water-cooled high heat flux armored components for tokamaks. To this was added the complication posed by the need to use a silver-free joining technique that avoids the transmutation of n-irradiated silver to cadmium. The research project involving the four Home Teams (HTs) has focused on the design, development, manufacture and testing of full-scale Plasma Facing Components (PFCs) suitable for ITER. The task addressed all the issues facing ITER divertor design, such as providing adequate armor erosion lifetime, meeting the required armor-heat sink joint lifetime and heat sink fatigue life, sustaining thermal-hydraulic and ...
1999-12-01
International Nuclear Information System (INIS)
New five complexes of the type of [RuL sub(3-x)(dmby) sub(x)]X sub(2)(x = 1,2,3, L = 2,2'-bipyridyl or 1,10-phenanthroline, dmby = 3,3'-dimethy1-2,2'-bipyridyl, X = halide ion) have been synthesized in order to investigate the effects of two methyl groups of dmby on the absorption and emission spectra, luminescence quantum yields, and lifetimes. Values of the radiative and nonradiative rate constants have been calculated from these data at 77K. Although the absorption and emission maxima and the lifetimes are not much affected by the dmby ligand substitution, the molar extinction coefficients and emission quantum yields are decreased compared with trischelated complexes of the parent bipyridyl or phenanthroline ligands. At 25"0C the emission yields of the complexes containing dmby decrease by 3 - 4 orders of magnitude than at 77K. Possible causes of the decrease in the quantum yields are discussed. (author).
1982-01-01
Strain effect and characteristics of GaInP/AlGaInP strain-compensated multiple quantum wells
Energy Technology Data Exchange (ETDEWEB)
Ga{sub 0.6}In{sub 0.4}P/(Al{sub 0.8}Ga{sub 0.2}){sub 0.4}In{sub 0.6}P strain-compensated multiple quantum wells (SCMQW) and Ga{sub 0.5}In{sub 0.5}P/(Al{sub 0.4}Ga{sub 0.6}){sub 0.5}In{sub 0.5}P unstrained MQW were grown by MOVPE to investigate the shift of photoluminescence (PL) peak wavelength and the carrier lifetime caused by strain effect in SCMQW. The PL peaks of SCMQW and unstrained MQW were 608 and 628 nm, respectively. From the rocking curve of SCMQW, it indicated that the active layers of SCMQW were not zero net strain. The residual strain caused the emission intensity of SCMQW to be about four times weaker than that of unstrained MQW. The carrier lifetimes of SCMQW and unstrained MQW were measured to be 3 and 6.02 ns, respectively. It was conjectured that the residual strain in SCMQW induced a decrease in the carrier lifetime by a factor of two with respect to that of unstrained MQW.
2003-02-15
Strain effect and characteristics of GaInP/AlGaInP strain-compensated multiple quantum wells
International Nuclear Information System (INIS)
Ga_0_._6In_0_._4P/(Al_0_._8Ga_0_._2)_0_._4In_0_._6P strain-compensated multiple quantum wells (SCMQW) and Ga_0_._5In_0_._5P/(Al_0_._4Ga_0_._6)_0_._5In_0_._5P unstrained MQW were grown by MOVPE to investigate the shift of photoluminescence (PL) peak wavelength and the carrier lifetime caused by strain effect in SCMQW. The PL peaks of SCMQW and unstrained MQW were 608 and 628 nm, respectively. From the rocking curve of SCMQW, it indicated that the active layers of SCMQW were not zero net strain. The residual strain caused the emission intensity of SCMQW to be about four times weaker than that of unstrained MQW. The carrier lifetimes of SCMQW and unstrained MQW were measured to be 3 and 6.02 ns, respectively. It was conjectured that the residual strain in SCMQW induced a decrease in the carrier lifetime by a factor of two with respect to that of unstrained MQW.
2003-02-15
Lifetime modelling of lead acid batteries
Energy Technology Data Exchange (ETDEWEB)
The performance and lifetime of energy storage in batteries are an important part of many renewable based energy systems. Not only do batteries impact on the system performance but they are also a significant expenditure when considering the whole life cycle costs. Poor prediction of lifetime can, therefore, lead to uncertainty in the viability of the system in the long term. This report details the work undertaken to investigate and develop two different battery life prediction methodologies with specific reference to their use in hybrid renewable energy systems. Alongside this, results from battery tests designed to exercise batteries in similar modes to those that they experience in hybrid systems have also been analysed. These have yielded battery specific parameters for use in the prediction software and the first results in the validation process of the software are also given. This work has been part of the European Union Benchmarking ...
2005-04-01
Energy Technology Data Exchange (ETDEWEB)
Radiation-and-thermal-combined degradation of ethylene-propylene rubber (EP rubber) and chlorosulfonated polyethylene (CSM) as cable insulating and jacketing materials were evaluated by accelerated aging tests and a method to assess the lifetime of these materials under practical application was studied. EP rubber and CSM of experimental formulation were degraded at accelerated rates, that are 50 [approx] 1000 times the degradation rate under a standard condition (1Gy/h, 50degC). The degradation was investigated by measuring the tensile properties. In the accelerated aging tests, rates of elongation decrease owing to degradation for both EP rubber and CSM were in proportion to increase in accelerated rate. Behaviors of elongation changes showed little difference with accelerated rate. EP rubber lifetime estimated from sequential aging test had a tendency to extend beyond that from simultaneous aging test, while CSM lifetime ...
1992-10-01
International Nuclear Information System (INIS)
Radiation-and-thermal-combined degradation of ethylene-propylene rubber (EP rubber) and chlorosulfonated polyethylene (CSM) as cable insulating and jacketing materials were evaluated by accelerated aging tests and a method to assess the lifetime of these materials under practical application was studied. EP rubber and CSM of experimental formulation were degraded at accelerated rates, that are 50 #approx# 1000 times the degradation rate under a standard condition (1Gy/h, 50degC). The degradation was investigated by measuring the tensile properties. In the accelerated aging tests, rates of elongation decrease owing to degradation for both EP rubber and CSM were in proportion to increase in accelerated rate. Behaviors of elongation changes showed little difference with accelerated rate. EP rubber lifetime estimated from sequential aging test had a tendency to extend beyond that from simultaneous aging test, while CSM lifetime ...
1992-01-01
International Nuclear Information System (INIS)
The details and principles of an apparatus built for measurements of fluorescence quantum yields and cascade-free lifetimes of open-shell cations are reported. These rely on the detection of coincidences between energy selected photo-electrons and undispersed photons. The results of such measurements for CO"+_2,COS"+,CS"+_2 and N_2O"+ in selected vibrational levels of their excited states are presented. Non-unity fluorescence quantum yields are found for some vibronic levels of CO"+_2(B), COS"+(A), N_2O"+(A) and a non-exponential decay is observed for CS"+_2(B). The data yield the following values for the radiative lifetimes: CO"+_2(A) 124 +- 6 ns,CO"+_2(B) 140 +- 7 ns, COS"+(A) 550 +- 50 ns and N_2O"+(A) 240 +- 12 ns. (orig.).
1980-10-01
Energy Technology Data Exchange (ETDEWEB)
The rate coefficients for the reactions of OH radical with CH3Br and CH2Br2 were measured as functions of temperature using the laser photolysis - laser induced fluorescence method. This data was incorporated into a semiempirical model (Solomon et al., 1992) and a 2D model to calculate the steady-state ozone depletion potentials (ODP) and atmospheri lifetimes, tau, with greatly improved accuracy as compared to earlier studies. The calculated ODPs and tau are 0.65 and 1.7 years and 0.17 and 0.41 years for CH3Br and CH2Br2, respectively, using the semiempirical model. These lifetimes agree well with those calculated using a 2D model. This study better quantifies the ODPs and tau of these species which are needed inputs for discussion of possible regulation of human emissions currently under international considerations. 29 refs.
1992-10-01
An Optimized Lifetime Enhancement Scheme for Data Gathering in Wireless Sensor Networks
Design of energy efficient schemes for data gathering is an important concern for lifetime enhancement of wireless sensor networks. Variation in the distances of nodes from the Base Station and differences in inter-nodal distances are primary factors causing unequal energy dissipation among the nodes. Thus energy difference between the various nodes increases with time resulting in degraded network performance. The LEACH and PEGASIS schemes which provided elegant solutions to the problem suffer basic drawbacks due to randomization of cluster heads and greedy chain formation respectively. In this paper, we propose an Optimized Lifetime Enhancement (OLE) Scheme which shows enhanced performance over these schemes. OLE increases the network performance by ensuring a sub-optimal energy dissipation of the individual nodes despite their random deployment. It employs modern heuristics like particle swarm optimization instead of the greedy algorithm as ...
2010-01-01
The temporal evolution of coronal loops observed by GOES-SXI
We study the temporal evolution of coronal loops using data from the Solar X-ray Imager (SXI) on board of GOES-12. This instrument allows us to follow in detail the full lifetime of coronal loops. The observed light curves suggest three somewhat distinct evolutionary phases: rise, main, and decay. The durations and characteristic timescales of these phases are much longer than a cooling time and indicate that the loop-averaged heating rate increases slowly, reaches a maintenance level, and then decreases slowly. This suggests that a single heating mechanism operates for the entire lifetime of the loop. For monolithic loops, the loop-averaged heating rate is the intrinsic energy release rate of the heating mechanism. For loops that are bundles of impulsively heated strands, it is an indication of the frequency of occurrence of individual heating events, or nanoflares. We show that the timescale of the loop-averaged heating rate is proportional ...
2006-01-01
Energy Technology Data Exchange (ETDEWEB)
We study some aspects of the experimental behaviour of tachyons, in particular by finding out their <
1982-10-21
Materials selection for the US INTOR divertor collector plate
Energy Technology Data Exchange (ETDEWEB)
The divertor collector plate in the INTOR reactor will be subjected to high heat, particle, and neutron fluxes, making it the most severely damaged torus component. The collector plate is composed of a protection plate, which is directly exposed to the particle flux, and a heat sink which provides support for the protection plate and carries the water coolant. The high-Z refractory metals have been considered for use as the protection plate material, and austenitic stainless steels and copper alloys have been considered as the heat sink material. Tungsten and Type 316 stainless steels have been selected for the protection plate and heat sink, respectively. The protection plate has a sputtering lifetime of 1.75 y at a 50% duty factor, while the heat sink is expected to last the lifetime of the reactor.
1981-01-01
Isomeric states and spin polarization in A approx. 90 nuclei
Energy Technology Data Exchange (ETDEWEB)
The observed inhibition of M4 transitions in A approx. 90 nuclei has represented a long standing theoretical problem. In particular by calculating first- and second-order configuration mixing contributions to the inhibited M4 lifetimes of /sup 89/Y and /sup 87/Sr, it is found that the first-order perturbative treatment of the residual interaction usually used in shell-model calculations is unjustified in this case. Using random-phase approximation techniques, the renormalization effects of collective (''giant'') M4 resonances in /sup 88/Sr on the low energy M4 transitions in /sup 89/Y and /sup 87/Sr are investigated. It is concluded that the observed retardation of M4 lifetimes in these nuclei is consistent with the manifestation of nuclear spin polarization.
1980-04-01
Energy Technology Data Exchange (ETDEWEB)
Smooth and notched specimens of the bearing steel 100Cr6 (SAE 52100) in a bainitic condition were used to determine the S-N curves under tensile, torsional and combined in- and out-of-phase loading. In the area of high-cycle fatigue, crack initiation was most likely caused by inclusions like Titanium Carbon nitrides or Aluminium Oxides. A micro mechanical model for the crack initiation by inclusions was developed. Another model was developed to describe the influence of these inclusions on the lifetime. A weakest-link model, using the statistical distribution of inclusions and surface flaws, was used to describe the endurance limit. (orig.)
2002-07-01
Energy Technology Data Exchange (ETDEWEB)
Five arylethylenes with 1-naphthyl, 2-naphthyl, and phenyl groups in 1,2-positions have been studied for singlet-mediated charge-transfer interactions with several amines and paraquat dication. 1-Phenyl-2-(2-naphthyl)ethylene and 1,2-di(2-naphthyl)ethylene exhibit distinct dependence of exciplex emission maxima and lifetimes, and fluorescence quenching constants, on excitation and/or monitoring wavelengths; this is in conformity with the existence of ground-state rotamers for these systems, wtih distinguishable absorption-emission spectra and fluorescence lifetimes. The fluorescence quenching by aromatic amines and paraquat dication occurs with rate constants in the limit of diffusion control and is accompanied by the formation of radical ions in polar solvents (acetonitrile). The transient spectra and kinetics associated with the radical ions, observed by 337.1- and 355-nm laser flash photolysis, are also reported. 10 figures, 4 tables.
1983-05-12
Estimating a parameter of Burr type XII distribution using hybrid censored observations
British Library Electronic Table of Contents (United Kingdom)
Purpose - Burr distribution has been proved to be a useful failure model. It can assume different shapes which allow it to be a good fit for various lifetimes data. Hybrid censoring is an important way of generating lifetimes data. The purpose of this paper is to estimate an unknown parameter of the Burr type XII distribution when data are hybrid censored. Design/methodology/approach - The problem is dealt with through both the classical and Bayesian point of view. Specifically, the methods of estimation used to tackle the problem are maximum likelihood estimation method and Bayesian method. Empirical Bayesian approach is also considered. The performance of all estimates is compared through their mean square error values. The paper employs Monte Carlo simulation to evaluate the mean square...
2011-01-01
Autofluorescence spectroscopy has been a widely explored technique for in vivo and noninvasive diagnosis of pre-cancer lesions in epithelium where 90% cancers originate. For extracting more accurate fluorescence information for cancer diagnosis, depth-resolved fluorescence measurements are crucial to assess NADH and FAD in non-keratinized epithelial layer and collagen in stromal layer, respectively. In this study, we achieved the depth-resolved fluorescence spectral measurements of squamous epithelial tissue based on confocal technique. We found that in non-keratinized epithelial layer the fluorescence signals excited at 405 nm were the combination of NADH and FAD fluorescence and could be used for evaluating the redox ratio. Moreover, we found that confocal time-resolved autofluorescence measurements of epithelial tissue with 405 nm excitations could provide the information on the layered tissue structure. All depth-resolved autofluorescence decays were accurately fitted with a ...
2007-03-01
The triaxial motion in Mo isotopes
Energy Technology Data Exchange (ETDEWEB)
The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of [sup 87]Mo are studied in detail and explained by the evolution of the [gamma]-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N [>=] 47 for the spherical shape of the Mo isotopes. (orig.)
1993-11-22
The triaxial motion in Mo isotopes
International Nuclear Information System (INIS)
The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of "8"7Mo are studied in detail and explained by the evolution of the #gamma#-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N #>=# 47 for the spherical shape of the Mo isotopes. (orig.).
Test and simulation of dynamic phase compensation from Mita-Teknik A/S
Energy Technology Data Exchange (ETDEWEB)
This report describes the test of a dynamic phase compensation unit for a wind turbine with directly connected induction generators. The compensation unit is based on thyristor switched capacitors, where conventional wind turbine compensations use mechanical contactors to switch the capacitors. The influence on power quality analysed, and influence on component lifetime is discussed. Besides, simulation models in Matlab/Simulink are presented, including a flicker meter model. (au)
2004-03-01
Tailored airfoils for vertical axis wind turbines
Energy Technology Data Exchange (ETDEWEB)
The evolution of a family of airfoil sections designed to be used as blade elements of a vertical axis wind turbine (VAWT) is described. This evolution consists of extensive computer simulation, wind tunnel testing and field testing. The process reveals that significant reductions in system costs-of-energy and increases in fatigue lifetime may be expected for VAWT systems using these blade elements.
1984-11-01
Sustainable managment of the weaner pig through nutrition
Environmental Research Database
DescriptionIn young pigs the post-weaning period is generally characterised by a marked reduction in voluntary feed intake, poor growth and development, and diarrhoea. The associated reduction in digestive and absorptive capacity of the gastrointestinal tract decreases the overall efficiency of nutrient capture and utilisation, thereby causing an increase in nutrient loading to the environment. The reduction in digestive and absorptive efficiency after weaning has implications for lifetime performance be [continued...
2006-01-31
Spin evolution in wind-fed X-ray binaries
International Nuclear Information System (INIS)
Global angular momentum balance suggests that the neutron stars in Be/X-ray binaries are not spinning in equilibrium. This requires an X-ray lifetime ''approx <'' 10"5 yr, and suggests that there are many 'dead' Be/X-ray binaries in the Galaxy. Some of these may be turned up as millisecond radio pulsars with Be star companions. (author).
International Nuclear Information System (INIS)
The intensity of luminescence from the "2E state of Cr(bpy)_3"3"+ (bpy = 2, 2'-bipyridine) is lower in D_2O, although the "2E lifetime is unchanged, indicating that the "4T_2 (precursor to "2E) is sensitive to the isotopic nature of the solvent. A photophysical mechanism is proposed for Cr(NN)_3"3"+ complexes.
Simulation aided hardening of N-channel power MOSFETs to prevent single event burnout
International Nuclear Information System (INIS)
2D MEDICI simulator is used to investigate hardening solutions to single-event burnout (SEB). SEB parametric dependencies such as carrier lifetime reduction, base enlargement, and emitter doping decrease have been verified and a p"+ plug modification approach for SEB hardening of power MOSFETs is validated with simulations on actual device structures.
1995-07-17
Photoexcitation and optical pumping in a barium atomic beam
International Nuclear Information System (INIS)
An apparatus allowing the photoexcitation of barium atomic beam over its whole surface is described. This photoexcitation is achieved by another barium spectrum emitted up steam of the beam by a cathodic out-flow produced at the exit oven. The fluorescence spectrum is studied in detail as well as the influence of different parameters, such as oven temperature, current intensity of the outflow, and excitation depth. A calculation shows how to determine Einstein coefficient, oscillator strengths and atomic lifetimes from our experimental measurements.
Photochemistry and photooxidation of tetraphenyl-p-dioxin
International Nuclear Information System (INIS)
Laser flash photolysis studies of tetraphenyl-p-dioxin have led to the characterization of its triplet state. The T-T absorption spectra shows maxima at 350 and 545 nm; the triplet has a lifetime of 535 ns in methanol and can be quenched by di-tert-butyl nitroxide, paraquat dications, oxygen, and di-tert-butyl selenoketone. The interaction of the triplet with oxygen leads to the formation of singlet oxygen which in turn reacts with the title compound to yield benzil.
Partial discharge in liquid nitrogen
Results are presented of experiments on partial discharge in liquid nitrogen, including insulation breakdown characteristics of liquid nitrogen, partial discharge characteristics of composite insulation systems, lifetime of polymer films, impulse breakdown of polymer films in liquid nitrogen, etc. The partial discharge characteristics of liquid nitrogen are examined with increasing liquid-nitrogen pressure. It is concluded that a composite insulation structure of polymer film and liquid nitrogen can be used as effective electrical insulators at cryogenic temperatures.
1976-01-01
Neutron scattering studies in the actinide region. Progress report, August 1, 1992--July 31, 1993
Energy Technology Data Exchange (ETDEWEB)
This report discusses the following topics: Prompt fission neutron energy spectra for {sup 235}U and {sup 239}Pu; Two-parameter measurement of nuclear lifetimes; ``Black`` neutron detector; Data reduction techniques for neutron scattering experiments; Inelastic neutron scattering studies in {sup 197}Au; Elastic and inelastic scattering studies in {sup 239}Pu; and neutron induced defects in silicon dioxide MOS structures.
1993-09-01
Energy Technology Data Exchange (ETDEWEB)
Frequency response measurements are used to determine the carrier lifetime of 1.3-..mu..m InGaAsP buried heterostructure lasers between 1 mA and threshold. The data confirm previous results on the radiative and Auger recombination coefficients and reveal the presence of a nonradiative current which dominates at low currents and contributes 4 mA at threshold.
1987-02-09
Energy Technology Data Exchange (ETDEWEB)
Often measures of protection and restoration of reinforced concrete structures are not taken until damage occurs which affects power plant operation. These failures can be avoided by predictive civil engineering maintenance and repair. The consequent application and implementation of a life-time management system for power plant buildings is being suggested. (orig.)
2008-07-01
Energy Technology Data Exchange (ETDEWEB)
A research report presents the basic data required when designing a building with minimal environmental impacts. Topics covered include the energy consumption of building elements during their lifetime, the environmental implications linked to the extraction and processing of building material and the energy consumed in buildings by the occupants. (UK)
1993-12-31
Energy Technology Data Exchange (ETDEWEB)
The properties of capacitors are reviewed in general, including dielectrics, induced polarization, and permanent polarization. Then capacitance characteristics are discussed and modelled. These include temperature range, voltage, equivalent series resistance, capacitive reactance, impedance, dissipation factor, humidity and frequency effects, storage temperature and time, and lifetime. Applications of energy storage capacitors are then discussed. (LEW)
1984-01-01
Erosion is the main contributing factor to the decrease in lifetime of gun barrels. The precision, muzzle velocity and fire range deteriorate when the surface inside the gun tube is eroded. This study deals with gun barrel material, what happens in the ba...
2002-01-01
Effects of ions and electrons on atmospheric lifetimes of fully fluorinated compounds
International Nuclear Information System (INIS)
Fully fluorinated compounds (perfluoro compounds) represent a class of chemicals which include many extremely inert species-inert to both chemical reaction and photodissociation. Well known examples include SF6 and the perfluorocarbons (PFCs) CF_4 and Teflon. SF_6 is used industrially in electrical switch gear and as an atmospheric tracer. CF_4 and C_2F_6 are released into the atmosphere as a by-product of aluminum manufacture. Several perfluoro compounds have been proposed as substitutes for the ozone-destroying Freons and halons; proposed substitutes include SF_6, c-C_4F_8, C_5F_1_2, and C_6F_1_4. These chemicals were chosen in part because they do not harm the stratospheric ozone layer and were therefore considered environmentally friendly. Recently, Ravishankara et al. reported that perfluoro compounds have significant global warming potential (GWP), contributing to the greenhouse effect due to strong infrared absorption. The perfluoro compounds have particularly high GWPs because ...
1994-04-05
Effect of lifetime nutrition on ruminant carcass and meat quality
Environmental Research Database
DescriptionThis application is a request for Bridge Link funds to support studies in order to develop a full proposal under the Link Sustainable Livestock Scheme in collaboration with Dr Nigel Scollan of IGER. The hypothesis being examined is that the poor performance of some ruminants is due to poor nutrition at strategic time points during the animal's development. The initial hypothesis will be tested in sheep and the results from this will be used to develop the full proposal. Excessive fat in ruminan [continued...
2006-01-31
Charge and fluence lifetime measurements of a dc high voltage GaAs photogun at high average current
Energy Technology Data Exchange (ETDEWEB)
GaAs-based dc high voltage photoguns used at accelerators with extensive user programs must exhibit long photocathode operating lifetime. Achieving this goal represents a significant challenge for proposed high average current facilities that must operate at tens of milliamperes or more. This paper describes techniques to maintain good vacuum while delivering beam, and techniques that minimize the ill effects of ion bombardment, the dominant mechanism that reduces photocathode yield of a GaAs-based dc high voltage photogun. Experimental results presented here demonstrate enhanced lifetime at high beam currents by: (a) operating with the drive laser beam positioned away from the electrostatic center of the photocathode, (b) limiting the photocathode active area to eliminate photoemission from regions of the photocathode that do not support efficient beam delivery, (c) using a large drive laser beam to distribute ion damage over a larger area, ...
2011-04-01
Annihilation of a positron in a vacancy in aluminum
International Nuclear Information System (INIS)
Results of an augmented-plane-wave calculation of the positron lifetime and the angular-correlation curves for aluminum, both in the vacancy-free crystal and in the crystal with a vacancy, are presented. The environment of the vacancy was simulated by a face-centered-cubic supercell with a volume 27 times that of the standard primitive unit cell of the Al lattice. The calculated positron-vacancy binding energy is 3.36 eV at room temperature. The temperature dependences of the trapping potential, the positron-vacancy binding energy, and the positron lifetime both in the Bloch state and in the vacancy-trapped state, associated only with the static thermal expansion of the lattice, have been calculated. It is found that the fractional increase in positron lifetime in the Bloch state is only approx.80% of the fractional increase in the volume of the lattice. The lifetime in the vacancy-trapped state is also ...
A stochastic regime switching model for the failure process of a repairable system
Energy Technology Data Exchange (ETDEWEB)
This paper presents a stochastic model and estimation procedure for analyzing the failure process of a repairable system. We consider repairable systems whose successive interfailure times reveal a significant dependence while showing an insignificant trend. Neither the renewal process nor the non-homogeneous Poisson process are adequate for modeling such failure processes. Especially when the interfailure times show a cyclic pattern, we may consider a switching of the regimes (states) governing the lifetime distribution of the system. We propose a Markov switching model describing the failure process for such a case. The model postulates that a finite number of states governs the distinct lifetime distributions, and the state makes transitions according to a discrete-time Markov chain. Each of the distinct lifetime distributions represents a failure type that may change after successive repairs. Our model generalizes the ...
1998-02-01
A kinetic study of ozone and nitric oxides in dielectric barrier discharges for O_2/NO_x mixtures
International Nuclear Information System (INIS)
A simple model is described to simulate kinetic processes in dielectric barrier discharges for O_2/NO_x mixtures. A threshold of ozone production found experimentally is confirmed by the calculations of this modeling, and the underlying chemical reaction mechanisms are discussed. It is also found that the effects of diffusion processes in the period of the lifetime of O atoms are not important to micro-discharge channels with a large radius, i.e. larger than 150 #mu#m
2002-04-01
Design of High-speed Wear Lifetime Tester of the Instrument Ball Bearings
Energy Technology Data Exchange (ETDEWEB)
The instrument ball bearings are the key components of movable components for various kinds of measuring and control instruments; they often operate in the environmental condition of high-speed and light preload. In general, the non metal, disposable oilimpregnated retainer material has been used for these kinds of high precision miniature bearing. The engineering practice shows that the common failure mode of them is the wear which appears under the condition of insufficient lubrication condition. As the results, the vibration and noise will be enlarged, so does the frictional torque, which makes the ball bearings to lose its original working accuracy. It is the lifetime test of bearings that can enable the designers and manufacturers to chose the material of the bearing properly, optimize the product structure, mend the manufacturing technique process, and to enhance the technical level of the bearing products significantly. In this paper, the wear ...
2006-10-15
Energy Technology Data Exchange (ETDEWEB)
The isotope shifts of the levels 5p/sup 2/ /sup 1/D/sub 2/, /sup 1/S/sub 0/ and 5sns /sup 1/S/sub 0/(n = 7,8) of strontium have been measured between the isotopes 84, 86, 87 and 88 in two-photon transitions from the ground state, using two lasers with different wavelengths. These levels occur below the beginning of the Rydberg series, and are known to exhibit very strong configuration mixing. Mass and field isotope shifts are calculated ab initio by means of the MCHF method for these levels and 5s4d /sup 1/D2, 5s6s /sup 1/S/sub 0/. The qualitative agreement between theory and experiment confirms the necessity of taking into account the mixing (up to 50%) with both the 5p/sup 2/ and 4d/sup 2/ perturbers in the wavefunction expansions.
1984-05-14
Enhanced Star Formation in Narrow Line Seyfert 1 AGN revealed by Spitzer
We present new low resolution Spitzer mid-infrared spectroscopy of a sample of 20 ROSAT selected local Narrow Line Seyfert 1 galaxies (NLS1s). We detect strong AGN continuum in all and clear PAH emission in 70% of the sources. The 6.2 micron PAH luminosity spans three orders of magnitudes, from ~10^(39) erg/s to ~10^(42) erg/s providing strong evidence for intense ongoing star formation in the circumnuclear regions of these sources. Using the IRS/Spitzer archive we gather a large number of additional NLS1s and their broad line counterparts (BLS1s) and constructed NLS1 and BLS1 sub-samples to compare them in various ways. The comparison shows a clear separation according to FWHM(H_beta) such that objects with narrower broad H_beta lines are the strongest PAH emitters. We test this division in various ways trying to remove biases due to luminosity and aperture ...
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) have been conducted on a new fuel cell electrocatalytic material based on a highly porous carbonized polyacrylonitrile (PAN) microcellular foam with very low platinum loading ({approximately}13 to 23 {micro}g/cm{sup 2}). TEM images of this material clearly show the existence of nanometer size platinum particles which are homogeneously distributed in the highly porous carbonized PAN matrix. An XPS study of Pt-loaded PAN indicates that C 1s, O 1s, and N 1s peaks shift to lower binding energies, compared to virgin PAN. It was concluded that special metal-support interaction exists, through the formation of a charge-transfer complex between platinum and pyridine-type nitrogen atoms of PAN support. This interaction leads to the enhancement of the catalytic activity, and the improvement ...
1997-01-01
A New Measurement of Kaonic Hydrogen X rays
The $\\bar{K}N$ system at threshold is a sensitive testing ground for low energy QCD, especially for the explicit chiral symmetry breaking. Therefore, we have measured the $K$-series x rays of kaonic hydrogen atoms at the DA$\\Phi$NE electron-positron collider of Laboratori Nazionali di Frascati, and have determined the most precise values of the strong-interaction energy-level shift and width of the $1s$ atomic state. As x-ray detectors, we used large-area silicon drift detectors having excellent energy and timing resolution, which were developed especially for the SIDDHARTA experiment. The shift and width were determined to be $\\epsilon_{1s} = -283 \\pm 36 \\pm 6 {(syst)}$ eV and $\\Gamma_{1s} = 541 \\pm 89 {(stat)} \\pm 22 {(syst)}$ eV, respectively. The new values will provide vital constraints on the theoretical description of the low-energy $\\bar{K}N$ ...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
Mono- and disubstituted novel derivatives of the heptaene nystatin analog 28,29-didehydronystatin A1 (S44HP, 1) were obtained by chemical modification of the exocyclic C-16 carboxyl and/or an amino group of mycosamine moiety. The strategy of preparation of mono- and double-modified polyene macrolides was based on the use of intermediate hydrophobic N-Fmoc (9-fluorenylmethoxycarbonyl) derivatives that facilitated the procedures of isolation and purification of new compounds. The antifungal activity of the new derivatives was first tested in vitro against yeasts and filamentous fungi, allowing the selection of the most active compounds that were subsequently tested for acute toxicity in mice. 2-(N,N-dimethylamino)ethylamide of 1 (2) and 2-(N,N-dimethylamino)ethylamide of N-fructopyranosyl-28...
2010-01-01
Transition rates of electrons in superheavy elements
International Nuclear Information System (INIS)
Transition rates for electrons in the superheavy elements Z = 114, 126, 134, 145, 164 and 173 are calculated. K, L and M-shells are considerd as final states. The 2s - 1s stransition of multipolarity M1 is dominant for Z = 173 with a transition time of 10"-"1"8s. The radial expectation values and #sq root# are given. (orig.).
The origin and physical mechanism of the ensemble Baldwin effect
We have conducted a systematic investigation of the origin and underlying physics of the line--line and line--continuum correlations of AGNs, particularly the Baldwin effect. Based on the homogeneous sample of Seyfert 1s and QSOs in the SDSS DR4, we find the origin of all the emission-line regularities is Eddington ratio (L/Ledd). The essential physics is that L/Ledd regulates the distributions of the properties (particularly column density) of the clouds bound in the line-emitting region.
2009-01-01
International Nuclear Information System (INIS)
Phenomenological accountancy of quanta-electrodynamic corrections by means of introduction into multielectron theory of short-term potential, the parameters whereof are calibrated in such a way that provides for correct reproduction of the Lamb shift of the 1s-orbital energy for a correspondingly selected effective charge is developed by example of d-line of Na-like multicharged ions.
P2X1 receptor mobility and trafficking; regulation by receptor insertion and activation
UK PubMed Central (United Kingdom)
P2X1 receptors for ATP contribute to signalling in a variety of cell types and following stimulation undergo rapid desensitisation (within 1 s), and require ∼5 min to recover. In HEK293 cells...Full Text Available
2010-06-01
UK PubMed Central (United Kingdom)
sFlt-1 (soluble Flt-1) potently inhibits angiogenesis by binding extracellularly to VEGF (vascular endothelial growth factor). In the present paper, we report that hypoxia down-regulates sFlt-1 expression...Full Text Available
2011-06-01
Electron impact excitation of lithium-like iron
Energy Technology Data Exchange (ETDEWEB)
Calculations of total and angle-differential excitation cross sections for the electron impact excitation of lithium-like iron were performed with the R-matrix formulation. The alignments of the excited states 1s{sup 2}np {sup 2}P{sub 3/2} are also presented for n=3 and 4 along with the angular photon distribution from these states to the ground state. Relativistic effects were included in the present calculations by the Breit-Pauli Hamiltonian.
1996-05-01
Dissipativity for linear neutral distributed parameter systems: LOI approach
British Library Electronic Table of Contents (United Kingdom)
In this work dissipativity of linear neutral distributed parameter systems has been addressed. Delay-dependent sufficient conditions for the dissipativity with respect to the infinite-dimensional version of energy supply rate (Q"1,S"1,R"1) characterized exclusively by unbounded operator Q"1 are established in terms of linear operator inequalities (LOIs). Finally, the 3-dimensional heat equation illustrates our result.
2012-01-01
Yields of short-lived fission products produced following "2"3"5U(n_t_h,f)
International Nuclear Information System (INIS)
Measurements of gamma-ray spectra, following the thermal neutron fission of "2"3"5U have been made using a high purity germanium detector at the University of Massachusetts Lowell (UML) Van de Graaff facility. The gamma spectra were measured at delay times ranging from 0.2 s to nearly 10000 s following the rapid transfer of the fission fragments with a helium-jet system. On the basis of the known gamma transitions, forty isotopes have been identified and studied. By measuring the relative intensities of these transitions, the relative yields of the various precursor nuclides have been calculated. The results are compared with the recommended values listed in the ENDF/B-VI fission product data base (for the lifetimes and the relative yields) and those published in the Nuclear Data Sheets (for the beta branching ratios). This information is particularly useful for the cases of short-lived fission products with lifetimes of the order of fractions ...
1998-08-01
Ultrafast carrier dynamics of InGaAsN and InGaAs single quantum wells
International Nuclear Information System (INIS)
Striking differences in differential reflectance and carrier relaxation in In0.4Ga0.6As and In0.4Ga0.6As0.98N0.02 single quantum wells (SQWs) were studied using ultrafast time-resolved photoreflectance. Even with extremely thin SQW of only 60 A within 3000 A wide GaAs confining layers, negative and positive differential reflectance was observed for the excitation photon energy far above the bandgaps at 820 and 880 nm for both samples. Due to absorption by the GaAs confining layer, the peak differential reflectance pumped at 820 nm is an order of magnitude larger than that pumped at 880 nm; and it is larger for InGaAs SQWs than for InGaAsN SQWs. The shorter carrier lifetimes of these samples result from carrier-carrier scattering as pumped at both wavelengths. The longer carrier lifetime as pumped at 880 nm is due to hot phonon decay in InGaAs but may be due to stimulated emission in InGaAsN. The results reveal that the carrier dynamics is ...
2008-04-21
Stripping a debris disk by close stellar encounters in an open stellar cluster
A debris disk is a constituent of any planetary system surrounding a main sequence star. We study whether close stellar encounters can disrupt and strip a debris disk of its planetesimals in the expanding open cluster of its birth. Such stripping would affect the dust production and hence detectability of the disk. We tabulated the fractions of planetesimals stripped off during stellar flybys of miss distances between 100 and 1000 AU and for several mass ratios of the central to passing stars. We then estimated the numbers of close stellar encounters over the lifetime of several expanding open clusters characterized by their initial star densities. We found that a standard disk, with inner and outer radii of 40 and 100 AU, suffers no loss of planetesimals around a star born in a common embedded cluster with star density 20 000 pc^-3. In this environment, a disk loses >97% of its planetesimals around an M-dwarf, >63% around a solar-type star, and >42% ...
2011-01-01
Species abundance distributions in neutral models with immigration or mutation and general lifetimes
We consider a general, neutral, dynamical model of biodiversity. Individuals have i.i.d. lifetime durations, which are not necessarily exponentially distributed, and each individual gives birth independently at constant rate \\lambda. We assume that types are clonally inherited. We consider two classes of speciation models in this setting. In the immigration model, new individuals of an entirely new species singly enter the population at constant rate \\mu (e.g., from the mainland into the island). In the mutation model, each individual independently experiences point mutations in its germ line, at constant rate \\theta. We are interested in the species abundance distribution, i.e., in the numbers, denoted I_n(k) in the immigration model and A_n(k) in the mutation model, of species represented by k individuals, k=1,2,...,n, when there are n individuals in the total population. In the immigration model, we prove that the numbers (I_t(k);k\\ge 1) of species ...
2010-01-01
International Nuclear Information System (INIS)
Analyses of the roles of cement-based barriers in radioactive waste isolation show that models used to estimate their characteristics during the lifetime of the repository must consider the alteration of material properties with time due to degradation processes. Reinforced concrete barriers at repositories shall be designed in such manner that they fulfil besides isolative capabilities also the required functions of mechanical resistance and stability. Key elements of safety evaluation are mainly the correct selection of materials for mineral composites with cement binder (cements, aggregates, mineral additives and chemical admixtures) and their design, execution of construction works and production of precast concrete containers (continuous casting of concrete - no cold joints, limited number of construction joints, proper placing and consolidation, finishing and curing), strict control of used materials and inspection of works, as well as investigation after the ...
2007-09-10
Energy Technology Data Exchange (ETDEWEB)
Hard surface finishing represents the final manufacturing step for functional areas of machine elements in state-of-the-art production. Raceways of rolling bearing rings are ground and honed to the required low roughness. Plastic deformation is restricted to a narrow edge zone of the hardened steel. Reheating of the machined components below the martensite tempering or bainite transformation temperature results in a marked decrease of the XRD line width on the surface. The investigated samples are made of through-hardened standard bearing steel 100Cr6 (international denotation: SAE 52100). On the basis of a material model that explains the effect as a complex diffusion process of dislocational carbon segregation, i.e. static strain aging, the measured kinetics of the XRD line width reduction is simulated by an Arrhenius-type equation, which describes the rate-controlling reaction step of temper carbide dissolution. The formation of a small white-etching surface layer of around 1 um ...
2008-07-01
Photovoltaic performance and reliability workshop
Energy Technology Data Exchange (ETDEWEB)
This proceedings is the compilation of papers presented at the ninth PV Performance and Reliability Workshop held at the Sheraton Denver West Hotel on September 4--6, 1996. This years workshop included presentations from 25 speakers and had over 100 attendees. All of the presentations that were given are included in this proceedings. Topics of the papers included: defining service lifetime and developing models for PV module lifetime; examining and determining failure and degradation mechanisms in PV modules; combining IEEE/IEC/UL testing procedures; AC module performance and reliability testing; inverter reliability/qualification testing; standardization of utility interconnect requirements for PV systems; need activities to separate variables by testing individual components of PV systems (e.g. cells, modules, batteries, inverters,charge controllers) for individual reliability and then test them in actual system configurations; more results ...
1996-10-01
Energy Technology Data Exchange (ETDEWEB)
The low-cycle fatigue properties of the ferritic-martensitic steels MANET I and II and F82H-mod, have been investigated at a temperature of 200 C. The strain-controlled fatigue has been performed with strain ranges between 0,4% and 1,0% and at a strain rate of 8.10{sup -4} s{sup -1}. The steel F82H-mod, is characterised by a higher plastic strain amplitude compared to MANET I and II. Some of the specimens have beenirradiated with a 104 MeV {alpha}-particle beam. The homogeneous implantation of 400 appm He leads to a hardening of the material. At the beginning of the fatigue tests the stress response of the irradiatedspecimens is higher compared to the unirradiated specimens. In general, thematerial shows softening during fatigue. The softening of irradiated material, which is fatigue tested with a high total strain amplitude, is higher than that of the unirradiated material. The lifetime is reduced. For irradiated specimens fatigued at small total strain amplitudes ...
1997-09-01
DEFF Research Database (Denmark)
OBJECTIVES: The authors examine the rationale and efficacy of pre-travel hepatitis B immunization strategies based on itinerary and presumed on-travel risk behaviour. METHODS: A large survey among 26,640 Danes survey provided data on journey lengths and destinations, immunization coverage, risk behaviour and knowledge. RESULTS: The estimated cumulative lifetime stay in endemic areas outside Europe is 4.3 months. The majority of risk situations are involuntary and unforeseeable. The majority of risk situations occur on short-term journeys. 5% nonimmune and 5% short-term travellers experienced at least one risk situation such as injections/operations/tattoos on their journey. The level of knowledge of hepatitis A and B is low. CONCLUSIONS: The rationale and efficacy of current immunization strategies are challenged. Based on the results presented here and the availability of vaccines with long-lasting coverage, the authors find that recommendations of immunization ...
2009-01-01
International Nuclear Information System (INIS)
Tris(8-quinolinolato)aluminum(III) (Alq3) shows electronic absorption bands at 378, 360 (in a 1:1 mixed solvent of methanol and ethanol (ME) at 77 K), 334, 316, 300, 263, 255.8, and 233 nm in ethanol at room temperature. According to the polarized fluorescence excitation spectrum together with MO calculations, for instance, the 360 nm band is assigned to an LL CT transition (an intramolecular charge transfer transition between two ligands), and the 378 nm band to an LM/ML CT one (an intramolecular charge transfer transition between ligand and metal). Alq3 shows a broad fluorescence band peaking at around 478 nm in the ME matrix at 77 K. The emission spectrum measured with a phosphoroscope has two emission bands at 567 and 478 nm. The 567 nm band accompanies vibronic bands at 578 and 605 nm, being safely assigned to a phosphorescence of Alq3. The lifetimes of the 478 and 567 nm bands are both 5.4 ms. The lifetime of the 478 nm band together with ...
2008-08-01
Assessment of dose-time-effect surfaces for somatic late effects after low dose irradiation
International Nuclear Information System (INIS)
Awaiting new data from RERF, an attempt was made to estimate the somatic risks of low doses of radiation for members of the German public. The new estimate follows closely the approach used in deriving the values published in the NIH Radioepidemiological Tables. The lifetime risk factors thus calculated are significantly larger than the estimates presented in ICRP Report 26 and are consistent with estimates recently made in the ongoing reactor safety study of NUREG. The increase in lifetime risks is mainly due to the introduction of a new time projection model which appears to be more consistent with the epidemiological data for many late effect end points than the constant absolute risk model previously employed. Results from a study in which epidemiological data were stochastically simulated with a computer indicate that the shapes of actual dose effect curves might be significantly more influenced by pure chance than by the dose dependency ...
1988-04-01
A numerical simulation of the evolution and fate of a FRI jet. The case of 3C 31
The evolution of FRI jets has been long studied in the framework of the FRI-FRII dichotomy. In this paper, we test the present theoretical and observational models via a relativistic numerical simulation of the jets in the radio galaxy 3C 31. We use the parameters derived from the modelling presented by \\cite{lb02a,lb02b} as input parameters for the simulation of the evolution of the source, thus assuming that they have not varied over the lifetime of the source. We simulate about 10 % of the total lifetime of the jets in 3C 31. Realistic density and pressure gradients for the atmosphere are used. The simulation includes an equation of state for a two-component relativistic gas that allows a separate treatment of leptonic and baryonic matter. We compare our results with the modelling of the observational data of the source. Our results show that the bow shock evolves self-similarly at a quasi-constant speed, with slight deceleration by the end ...
2007-01-01
Trapping of neutral atoms with resonant microwave radiation
Energy Technology Data Exchange (ETDEWEB)
We duscuss a resonant microwave trap for neutral atoms. Because of the long spontaneous radiation time this trap is remarkably different from the optical trap. It also has advantages over static magnetic traps that trap the excited spin state of the lowest electronic level, in that atoms predominantly in the spin ground state can be trapped. We analyze the relaxation-ejection lifetime of atoms in such a trap using the formalism of dressed atomic states. Results are appliedi to atomic hydrogen and the possibility of Bose-Einstein condensation is considered.
1989-05-15
Energy Technology Data Exchange (ETDEWEB)
The platinum-silicide layer was investigated as the anode contact of a high-power P-i-N diode. The thermal stability at 700 deg. C was found sufficient for the purpose of Pt in-diffusion from the platinum-silicide layer into the volume. The diffusion, which was controlled using the radiation defects resulting from the 10 MeV alpha particle irradiation, represents a new local lifetime control in the float zone silicon with very low-leakage current, while keeping the benefits of traditional approaches.
2003-06-02
Solution of the orthopositronium lifetime puzzle
The intrinsic decay rate of orthopositronium formed in SiO/sub 2/ powder is measured using the direct 2 gamma correction method such that the time dependence of the pick-off annihilation rate is precisely determined. The decay rate of orthopositronium is found to be 7.0396+or-0.0012(stat.)+or-0.0011(sys.)/ mu s/sup -1/, which is consistent with our previous measurements with about twice the accuracy. Results agree well with the O( alpha /sup 2/) QED prediction, and also with a result reported very recently using nanoporous film.
2004-01-01
Radio frequency He/sup -/ source and a source of negative ions by cesium sputtering
Energy Technology Data Exchange (ETDEWEB)
Two sources of negative ions are described. An rf source produces up to 14 ..mu..A beams of He/sup -/ by charge exchange in Rb vapor. The other Source of Negative Ions by Cesium Sputtering (SNICS) produces a wide variety of negative ion beams in the ..mu..A range. Two important features of SNICS are its simple, compact construction and its very good beam emittance (2 to 4..pi..mm mrad MeV/sup 1/2/). Both sources have lifetimes >200 hours and they are used extensively on the Wisconsin EN tandem.
1981-04-01
Energy Technology Data Exchange (ETDEWEB)
One of the major scientific and technological challenges for the production of flexible organic electronic devices is the device protection against atmospheric molecule permeation, which causes corrosion reducing its operation and lifetime. In this work, Spectroscopic Ellipsometry has been implemented to investigate the influence of silicon dioxide nanoparticles on the optical properties of hybrid polymers. The spectra analysis revealed valuable information about the electronic and vibrational response as well as the cross-linking mechanisms of these materials. The correlation of the optical properties with the synthesis parameters and the barrier response will contribute towards their optimization in order to be used as high barrier coatings for flexible organic electronics applications.
2009-10-01
Nondestructive Technique Survey for Assessing Integrity of Composite Firing Vessel
Energy Technology Data Exchange (ETDEWEB)
The repeated use and limited lifetime of a composite tiring vessel compel a need to survey techniques for monitoring the structural integrity of the vessel in order to determine when it should be retired. Various nondestructive techniques were researched and evaluated based on their applicability to the vessel. The methods were visual inspection, liquid penetrant testing, magnetic particle testing, surface mounted strain gauges, thermal inspection, acoustic emission, ultrasonic testing, radiography, eddy current testing, and embedded fiber optic sensors. It was determined that embedded fiber optic sensor is the most promising technique due to their ability to be embedded within layers of composites and their immunity to electromagnetic interference.
2000-08-01
Negative charges in liquid hydrogen and deuterium
Energy Technology Data Exchange (ETDEWEB)
The temperature and pressure dependence of the mobilities of negative charges injected into liquid hydrogen and deuterium have been measured. The authors propose the existence of two types of charge carriers in liquid parahydrogen. One is a bubble with an electron inside while the other has higher mobility. Relaxation of the current through liquid hydrogen was observed. It is suggested that in liquid and solid hydrogen under {beta}-irradiation neutral complexes are created which can trap the negative charges and have a lifetime of about 10 hours. 6 refs., 5 figs.
1992-11-01
Energy Technology Data Exchange (ETDEWEB)
The nuclear structure of A {proportional_to} 100 nuclei has been studied in the frame of this thesis with a recently developed {beta} - {gamma} - {gamma} triple coincidence fast timing technique and different models such as shell model, hydrodynamic model, Nilsson and particle-rotor models. This technique which allows the measurement of the level lifetimes in the ps range has been applied at JOSEF at the research reactor DIDO of KFA Juelich in studes of the short-lived neutron-rich nuclei in the A {approx_equal} 100 region. Lifetimes of level in {sup 96},{sup 98},{sup 100} ZR, {sup 99},{sup 101}-{sup 104} Nb, {sup 100}-{sup 105} Mo have been measured, which are in many cases completely new, and otherwise more precise than previously published data. From the lifetimes of the members of rotational bands, the size of the nuclear deformations has been deduced. (orig./HSI). [Deutsch] Im Rahmen dieser Doktorarbeit wurde die ...
1992-08-01
Mastery of risks: we build the memory of radioactive waste disposal facilities
International Nuclear Information System (INIS)
The ANDRA, the French national agency of radioactive wastes, is organizing today the information needs of tomorrow. The aim is to allow the future generations to have access to the knowledge of the existence of subsurface radioactive waste facilities and to understand the context and technologies of such facilities. The storage of this information is made on 'permanent paper', a high resistant paper with a lifetime of 600 to 1000 years. An updating of these data is made every 5 years for each waste disposal center. Another project, still in progress, concerns the memory management of deep geologic waste disposal facilities for which the time scale to be considered is of the order of millennia. (J.S.)
Infrared stimulated luminescence in quartz
Energy Technology Data Exchange (ETDEWEB)
Infrared (IR, 880 nm) stimulated luminescence (IRSL) signal was observed from quartz at room temperature. The characteristics of the signal such as its response to {gamma}-ray irradiation, thermal stability and thermal assistance energy show that the signal originates from different traps than those responsible for the luminescence signal stimulated by green light (GL, 514 nm). The IRSL signal's short lifetime (18 days at 15 deg. C) may have been the reason why it was not detected in previous experiments. The decay of the IR signal after GL illumination was observed. The thermoluminescence at 76 deg. C was enhanced after IR illumination.
2005-02-01
Improved beam confinement in the modified betatron with strong focusing
International Nuclear Information System (INIS)
The lifetime of the circulating electron beam in the Naval Research Laboratory modified betatron has been increased by more than 2 orders of magnitude with the addition of strong focusing windings to the device. The injected beam consistently spirals from the injector to the minor axis and is trapped. The #approx#0.5-kA trapped electron ring has been accelerated above 10 MeV from the injection energy of 0.5 to 0.6 MeV. The beam acceleration has been confirmed not only by the x-ray attenuation technique but also with the detection of photoneutrons.
High temperature fatigue example of creep life time prediction for grade 2 alloy 800 at 550 C
Energy Technology Data Exchange (ETDEWEB)
Experimental data on the material characteristics of structures subjected to thermal and mechanical cycling are needed for designing structural parts for creep and creep-fatigue interaction. Moreover, high-temperature low-cycle fatigue data are not sufficient to predict the fatigue creep lifetime. In order to check the reliability of steam generators, tests on pipe materials are conducted under cyclic thermal loading. The tests have been performed on an iron-nickel chromium alloy (alloy 800). Isothermal low-cycle fatigue tests have been conducted at 550 C. 15 refs.
1994-04-01
HVDC cable design logic for digital computers
Energy Technology Data Exchange (ETDEWEB)
The design of High-Voltage, Direct-Current transmission cables insulated with oil-impregnated cellulose paper is constrained by the maximum temperature and the maximum steady-state and transient stresses (voltage gradients) that the cable insulation can reliably withstand over the desired operating lifetime. Because the electrical stresses in the insulation are related in a very complex fashion to temperature, applied voltage and cable geometry, iterative techniques are required to compute the values of these stresses. Digital computers are ideally suited for these iterative techniques. This paper presents the principal equations and logic needed to develop suitable computer programs.
1992-10-01
HTSC devices fabricated by selective epitaxial growth
International Nuclear Information System (INIS)
The use of a selective epitaxial growth technique for fabricating YBCO thin-film microstructures is described. No film post-deposition processing is required; hence damage to the structure is minimized. The technique is compatible with a passivation process to protect the structure without exposure to air. The microbridges, Josephson junctions and rf SQUIDs protected by an amorphous YBCO passivation have long lifetime even after severe accelerated aging tests. Rf SQUIDs fabricated by this technique show a significant reduction of low-frequency noise when operating in weak magnetic fields compared with SQUIDs fabricated by the conventional ion beam etching technique. (author)
1999-04-01
Fluorescence resonance energy transfer using lanthanide-ion doped oxide nanoparticles as donors
We have demonstrated fluorescence resonance energy transfer (FRET) between lanthanide-ion doped oxide nanoparticles acting as donors and organic acceptor molecules (Cy5). Due to the long nanoparticle lifetime and the large Stokes shift between nanoparticle absorption and emission, unambiguous and precise FRET measurements can be performed despite the presence of large free acceptor oncentrations. We determined FRET efficiencies as a function of Cy5 concentration which are in very good agreement with a multiple acceptor-multiple donor calculation.
2006-03-01
Evolution of the white dwarf mass and spin in cataclysmic variables
International Nuclear Information System (INIS)
We consider the spin-up of the white dwarf in non-magnetic cataclysmic variables (CVs) during secular evolution. If this is unresisted, CVs are quenched as boundary-layer emitters once the binary period has decreased by #approx# 1 hr. Angular momentum loss in nova explosions may, however, prevent the star reaching breakup. If the explosions remove (1 + #epsilon#) x the mass accreted between outbursts, values 0.5 < #approx# #epsilon# < #approx# 1 allow CVs to be modest boundary-layer emitters for most of their lifetimes. Spectral effects will limit their detection as soft X-ray sources. (author).
Electronic structure calculations of vacancies and their influence on materials properties
Energy Technology Data Exchange (ETDEWEB)
We provide two examples to illustrate how electronic structure calculations contribute to our understanding of vacancies and their role in determining material properties. Diffusion and elctromigration in aluminium are known to depend strongly on vacancies. Electronic structure calculations show that the vacancy-impurity interaction oscillates with distance, and this leads to an explanation for both the increased elctromigration resistance and the slow impurity diffusion for copper in aluminium. Calculations of vacancies in plutonium have been used in conjunction with positron annihilation lifetime measurements to identify the presence of helium-filled vacanies. Helium stabilization of vacancies can provide the precursors for subsequent vacancy-related changes in materials properties.
1997-08-01
Energy Technology Data Exchange (ETDEWEB)
An experimental verification for long-term performance of a Pd-Ag permeation in ITER tritium fusion cleanup units (FCU) is needed. In addition, information is required on the influence of tritium and {sup 3}He decay on the physical and chemical properties of Pd-Ag alloys (V-1). The results of the investigations of alloys (V-1) (mechanical properties and microstructure) after long-term usage exposition in tritium are given in this report. The experimental conditions (temperature, pressure, clearance, {sup 3}He concentrations) and the previous conclusions on the V-1 alloy performance are presented. (orig.).
1996-10-01
A study of aging effects in gas proportional detectors at the BAC calorimeter of the ZEUS experiment
Energy Technology Data Exchange (ETDEWEB)
The multicell proportional chambers at the backing calorimeter of the ZEUS experiment at the storage ring HERA are supplied with a gas mixture of Ar/CO[sub 2] by an open gas system. Flow proportional counters with the build-up [sup 55]Fe sources are used as gas system monitoring detectors. The ZEUS experiment is planned to collect data for about 10 years. Therefore, the lifetime of the Ar/CO[sub 2] mixture should be known. In this paper, the results of laboratory tests and preliminary measurements of the aging effects for monitoring counters are presented. ((orig.))
1994-09-01
International Nuclear Information System (INIS)
The model compounds, 8-methoxypsoralen-CH_2O(CH_2)_n-adenine (MOPCH_2OC_nAd, n=2,3,5,6,8, and 10) in which 5 position of 8-methoxypsoralen (8-MOP) is linked by various lengths of polymethylene bridge to N"9 of adenine. UV absorption spectra are identical with the sum of MOPCH_2OC3 and adenine absorption spectra. Solvent effect on the UV absorption and fluorescence emission spectra indicate that the lowest excited singlet state is the (#pi##->##pi#"*) state. The spectral characteristics of the fluorescence of MOPCH_2OC_nAd are strongly dependent upon the nature of the solvents. The fluorescence emission spectra in aprotic solvents are broad and structrueless due to the excimer formation through the folded conformation accelerated by hydrophobic #pi#-#pi# stacking interaction. Increasing polarity of the protic solvents leads to higher population of unfolded conformation stabilized through favorable solvation and H-bonding, and consequently to an increase in the fluorescence intensity, ...
2002-10-01
East-Asia nuclear/fossil power plant competitiveness
Energy Technology Data Exchange (ETDEWEB)
The competitiveness of a new nuclear plant vs. a new oil or gas fired combined cycle plant or a coal fired plant in East-Asia, is reviewed in the paper. Both the nuclear and the fossil fired plants are evaluated as either utility financed or independent power producer (IPP) financed. Two types of advanced light water reactors (ALWRs) are considered in this paper, namely evolutionary ALWRs (1200 MWe size) and passive ALWRs (600 MWe class). A range of capital and total generation costs for each plant type is reported here. The comparison centers on three elements of overall competitiveness: generation costs, hard currency requirements, and employment requirements. Each of these aspects is considered perspective. Year-by-Year generation cost history over the plant lifetime is shown in some cases. It is found here that a utility financed evolutionary and passive ALWRs are broadly competitive with an IPP financed gas fired combined cycle plant and are more economic than ...
1996-12-31
Energy Technology Data Exchange (ETDEWEB)
We report the results of ab initio calculations of cross sections and molecular-frame photoelectron angular distributions for C 1s ionization of CO2, and propose a mechanism for the recently observed asymmetry of those angular distributions with respect to the CO^+and O^+ions produced by subsequent Auger decay. The fixed-nuclei, photoionization amplitudes were constructed using variationally obtained electron-molecular ion scattering wave functions. We have also carried out electronic structure calculations which identify a dissociative state of the CO2^++ dication that is likely populated following Auger decay and which leads to O^+ + CO^+ fragment ions. We show that a proper accounting of vibrational motion in the computation of the photoelectron angular distributions, along with reasonable assumptions about the nuclear dissociation dynamics, gives results in good agreement with recent experimental observations. We also demonstrate that ...
2009-02-18
Solid oxide fuel cells (Part 2)
Energy Technology Data Exchange (ETDEWEB)
The project has been developing Yttria Stabilized Zirconia (YSZ)-Alumina Composites as an electrolyte of a self-support type planar Solid Oxide Fuel Cell (SOFC) from the following points of view: a path of alumina particles with high thermal conductivity can be designed as an electrolyte sheet; there are some possibilities that the electrolyte can be enhanced in mechanical strength. As previously reported, these composite materials have higher mechanical strength and better thermal shock resistance than those of YSZ. These composites containing 0-30 wt% of Al[sub 2]O[sub 3] were measured by AC impedance method at temperatures of 250-1,000[degree]C. Electrical conductivities of 8YSZ without Al[sub 2]O[sub 3] and a composite consisting of 80 wt% YSZ and 20 wt%Al[sub 2]O[sub 3] as sintered samples were 1.2 x 10[sup -1]S/cm and 1.0 x 10[sup -1]S/cm respectively at 1,000[degree]C. The composite containing 20 ...
1993-01-01
Interactions between organic anions on multiple transporters in Caco-2 cells.
In drug development, Caco-2 cells are often employed to study the influence of membrane transporters on drug permeability. The aim of the current study was to characterize permeability and kinetic parameters of selected organic anionic compounds in Caco-2 cells, and to investigate whether the Caco-2 cell line may be used as an overall model to predict interactions on multiple membrane transporters in the intestine. Taurocholic acid (TCA) and estrone-3-sulfate (E(1) S) were used as model substrates. Possible inhibitors studied were TCA, E(1) S, taurolithocholic acid, fluvastatin, and glipizide. The effects of these compounds on initial uptake, apparent permeability, and intracellular end-point accumulations of the probe substrates were studied. Both interactions on apical and basolateral influx transporters were observed. These interactions were proposed to be mediated mainly by the apical ...
2011-05-23
Electron impact excitation cross sections in F-like selenium
Cross sections for excitation induced by electron collision between low-lying 1s{sup 2}2s{sup 2}2p{sup 5} and 1s{sup 2}2s2p{sup 6} states of f-like selenium and from these states to singly excited states with the excited electron occupying the M shell have been calculated by relativistic distorted-wave Born procedures. The GRASP{sup 2} code was used for the atomic structure calculations. The continuum orbitals for the construction of continuum states were computed in the distorted-wave approximation, in which the distorted-wave potential used was the spherically averaged potential of the nucleus plus the potential of the bound electrons of the bound state. The cross sections for excitations were computed first by a 233-level multiconfiguration Dirac-Fock (MCDF) configuration expansion and then by a 279-level MCDF configuration expansion. The latter procedure, which also took into account contributions ...
1998-09-01
Chemical properties of positive singly charged astatine ion in aqueous solution
Energy Technology Data Exchange (ETDEWEB)
The mobility of oxidized astatine in solutions H(Na)ClO/sub 4/ (..mu..=0.4M)-1.10/sup -4/M K/sub 2/Cr/sub 2/O/sub 7/ has been measured at 25 degC in the interval 0.63<=pH<=1.68. Under these conditions astatine migrates to the cathode only. The speeds of the migration depends upon the concentration of hydrogen ions in solutions are: pH 1.68 Usub(c)=1.17.10/sup -4/ cm/sup 2/ V/sup -1/ s/sup -1/; pH 0.63 Usub(c)=2.67.10/sup -4/ cm/sup 2/ V/sup -1/ s/sup -1/. The effect agrees with the opinion that the singly charged cation of astatine formed in acidic solutions is a strong aquacomplex ((H/sub 2/O)sub(x)At)/sup +/ (x=1-2) (protonated hypoastatic acid). Deprotonation constant of this cation is Ksub(dp)=0.032+-0.005. Specific properties of the astatine cation are given. They can be explained, probably, through the peculiarities of its structure. 14 refs.
1984-08-01
Chemical properties of positive singly charged astatine ion in aqueous solution
International Nuclear Information System (INIS)
The mobility of oxidized astatine in solutions H(Na)ClO_4 (#mu#=0.4M)-1.10"-"4M K_2Cr_2O_7 has been measured at 25 degC in the interval 0.63<=pH<=1.68. Under these conditions astatine migrates to the cathode only. The speeds of the migration depends upon the concentration of hydrogen ions in solutions are: pH 1.68 Usub(c)=1.17.10"-"4 cm"2 V"-"1 s"-"1; pH 0.63 Usub(c)=2.67.10"-"4 cm"2 V"-"1 s"-"1. The effect agrees with the opinion that the singly charged cation of astatine formed in acidic solutions is a strong aquacomplex [(H_2O)sub(x)At]"+ (x=1-2) (protonated hypoastatic acid). Deprotonation constant of this cation is Ksub(dp)=0.032+-0.005. Specific properties of the astatine cation are given. They can be explained, probably, through the peculiarities of its structure. (author).
Anisotropy in Magnetic Properties and Electronic Structure of Single Crystal LiFePO4
Energy Technology Data Exchange (ETDEWEB)
We report the experimental and theoretical results on the anisotropies in the magnetic properties and x-ray absorption spectra of single-crystal LiFePO4. A mean-field theory is developed to explain the observed strong anisotropies in Lande g-factor, paramagnetic Curie temperature, and effective moment for LiFePO4 single crystals. The values of the in-plane nearest- and next-nearest-neighbor spin exchange (J1 and J2), interplane spin exchange (J{perpendicular}), and single-ion anisotropy (D), obtained recently from neutron scattering measurements, are used for calculating the Curie temperatures with the formulas derived from the mean-field Hamiltonian. It is found that the calculated Curie temperatures match well with that obtained by fitting the magnetic susceptibility curves to the modified Curie-Weiss law. For the polarized Fe K-edge x-ray absorption spectra of single-crystal LiFePO4, a different feature assignment for the 1s4p transition ...
2008-01-01
Mathematical analysis of DNA histograms from asynchronous and synchronous cell populations
A technique is presented for the analyss of DNA histograms which is an extension of earlier discrete Gaussian summing methods. It alleviates the problems encountered with previous methods by extending the S-phase portions of the distribution under the G/sub 1/ and G/sub 2/ + M peaks. The resuts obtained by this method for the fraction of cells in the G/sub 1/, S, and G/sub 2/ + M phases of the life cycle are compared with autoradiographic results. With one or two exceptions which are discussed, agreement between autoradiography and the analytical method is good.
1977-01-01
International Nuclear Information System (INIS)
The results of studies of the time-resolved luminescence of self-trapped excitons (STE) with different multiplicity as well as the X-ray emission in oriented BeO crystals under excitation in the vicinity of the 1 s Be photoabsorption edge are presented. The branching of the electronic excitations relaxation depends strongly on the crystal orientation after the inner-shell excitation. The common features between the processes of the STE luminescence and resonantly excited X-ray fluorescence have been discussed.
2007-05-21
Antiproton-Proton Channels in J/psi Decays
The recent measurements by the BES Collaboration of J/psi decays into a photon and a proton-antiproton pair indicate a strong enhancement at the proton-antiproton threshold not observed in the decays into a neutral pion and a proton-antiproton pair. Is this enhancement due to a proton-antiproton quasi-bound state or a baryonium? A natural explanation follows from a traditional model of proton-antiproton interactions based on G-parity transformation. The observed proton-antiproton structure is due to a strong attraction in the 1S0 state, and possibly to a near-threshold quasi-bound state in the 11S0 wave.
2005-01-01
Pulse radiolysis of aqueous solutions of tetraphenylphosphonium ions
International Nuclear Information System (INIS)
The reactions of tetraphenylphosphonium ion (Ar_4P"+) with esub(aq)"-, H atoms and OH radicals have been investigated. The absorption spectra of three transient species were obtained. Ar_4Psup(.) radicals formed by the reaction: Ar_4P"+ + esub(aq)"- #-># Ar_4Psup(.) have a maximum absorption at 305 nm [epsilon _3_0_5 = (9400 +- 300)dm"3mol"-"1cm"-"1] and decays by second-order kinetics with the rate constant 2k = (2.7 +- 0.4) x 10"9dm"3mol"-"1s"-"1. H atoms and OH radicals form transient adducts to the phenyl groups of the Ar_4P"+ ion with the rate constants of (1.5 +- 0.3) x 10"9 dm"3mol"-"1s"-"1 and (3.0 +- 0.3) x 10"9dm"3mol"-"1s"-"1, respectively. Both adducts have broad absorption spectra at 300 approximately 380 nm (lambdasub(max) = 340 nm) with the molar extinction coefficients epsilonsub(340) = 5400 +- 300 dm"3mol"-"1cm"-"1 for the H adduct and ...
1976-01-01
Genetic and physical mapping of the Chediak-Higashi syndrome on chromosome 1q42-43
Energy Technology Data Exchange (ETDEWEB)
The Chediak-Higashi syndrome (CHS) is a severe autosomal recessive condition, features of which are partial oculocutaneous albinism, increased susceptibility to infections, deficient natural killer cell activity, and the presence of large intracytoplasmic granulations in various cell types. Similar genetic disorders have been described in other species, including the beige mouse. On the basis of the hypothesis that the murine chromosome 13 region containing the beige locus was homologous to human chromosome 1, we have mapped the CHS locus to a 5-cM interval in chromosome segment 1q42.1-q42.2. The highest LOD score was obtained with the marker D1S235 (Z{sub max} = 5.38; {theta} = 0). Haplotype analysis enabled us to establish D1S2680 and D1S163, respectively, as the telomeric and the centromeric flanking markers. Multipoint linkage analysis confirms the ...
1996-09-01
Bombyx mandarina nucleopolyhedrovirus (BomaNPV) is a variant of Bombyx mori nucleopolyhedrovirus (BmNPV). BomaNPV S1 strain has been reported to be significantly less virulent than the BmNPV T3 strain via the oral infection route in B. mori larvae, but other features of S1 including budded virus (BV) infectivity and virus propagation in cultured cells are still unknown. In this study, we compared BV infectivity of S1 and T3 in B. mori larvae and cultured cells. Larval bioassays by intrahemocoelic BV injection revealed that the median lethal dose of S1's BV was approximately three times lower than that of T3. In addition, S1 produced more BVs and occlusion bodies (OBs) in the hemolymph of B. mori larvae compared with T3. Furthermore, we observed that the locomotion was enhanced earlier and the median lethal time was shorter in S1-infected larvae compared with those in T3-infected larvae. Western blot analysis of S1- and T3-infected BmN cells ...
2011-05-22
Energy Technology Data Exchange (ETDEWEB)
Er{sub 3}NbO{sub 7} phosphor was synthesized by sintering a mixture of Er{sub 2}O{sub 3} and Nb{sub 2}O{sub 5} powder in a molar ratio of 3:1 at 1600 deg. C over 55 h. Optical absorption and emission characteristics of Er{sup 3+} ions in the calcined Er{sub 3}NbO{sub 7} powder were investigated and discussed compared with ErNbO{sub 4} phosphor and a Z-cut congruent Er (2 mol%):LiNbO{sub 3} single crystal. The absorption and emission studies show that, due to different crystal structures, the spectroscopic properties of these niobates have some differences in spectral shape, peak position, and relative intensity, especially at 1.5 {mu}m. The most obvious spectral feature of the Er{sub 3}NbO{sub 7} is that the spectral structure of band instead of peak is observed in its absorption or emission spectrum due to the existence of local structural disorder and multiple Er{sup 3+} sites. The Er{sub 3}NbO{sub 4} shows stronger upconversion emission than the single crystal but weaker than the ...
2007-12-15
International Nuclear Information System (INIS)
The intensity of erbium up-conversion luminescence could be limited by a saturation effect due to increased pump power. We studied the luminescence saturation of the 550 nm emission on erbium-doped, SiO_2-TiO_2 sol-gel powders under pulsed excitation at 979 and 1532 nm. From the latter, the up-converted luminescence intensity decreased with increasing excitation power, whereas no saturation was observed at 979 nm excitation. We proposed that the saturation effect is determined by the pump power, the erbium content and the lifetime of the corresponding first excited states at different pumping schemes.
2010-12-01
Two-year diagnostic stability in early-onset first-episode psychosis
British Library Electronic Table of Contents (United Kingdom)
Background:- Only one study has used a prospective method to analyze the diagnostic stability of first psychotic episodes in children and adolescents. The Child and Adolescent First-Episode Psychosis Study (CAFEPS) is a 2-year, prospective longitudinal study of early-onset first episodes of psychosis (EO-FEP). Aim:- To describe diagnostic stability and the variables related to diagnostic changes. Methods:- Participants were 83 patients (aged 9-17-years) with an EO-FEP consecutively attended. They were assessed with a structured interview (Kiddie-Schedule for Affective Disorders and Schizophrenia, Present and Lifetime version) and clinical scales at baseline and after 2-years. Results:- The global consistency for all diagnoses was 63.9%. The small group of bipolar disorder had high stabilit...
2011-01-01
Time-resolved triple-axis spectroscopy - a new method for real-time neutron scattering
International Nuclear Information System (INIS)
A new method for kinetic experiments with neutrons is described. This method combines the conventional triple-axis neutron spectroscopy with relaxation-type experiments. Whereas the former method yields information about the microscopic dynamics of solids, the latter provides macroscopic relaxation times. The combination of both methods allows to determine the microscopic mechanism of relaxation processes. The time-resolved triple-axis spectroscopy is limited to reversible processes and to time scales from 10"-"3 to 10"4 s. Typical applications are the kinetics of phase transformations (structural and dynamical changes), kinetics of domain distributions, kinetics of (spinodal) decomposition, reversible solid state reactions, time-dependent occupation of phonon states or phonon lifetimes. (orig.).
1990-04-01
Third generation nuclear new builds: Opportunities and challenges
International Nuclear Information System (INIS)
Full text: The nuclear renaissance, anticipated by AREVA in the beginning of the century is now happening in several countries around the world. The fundamentals being the increasing demand of energy, the volatility of fossil fuel prices, the awareness of climate change threat connected with the extensive use of fossil fuels. The EPRTM reactor present significant improvements compared to previous generation reactors enabling to reach an outstanding safety level (redundancy of safety systems, airplane crash resistance), to improve the economics (extended plant lifetime, flexibility and availability during operation and, increased efficiency and fuel utilization) while limiting the impact on workers and the environment. Several countries have been implementing the transition to third generation reactors. The presentation will analyze different examples in order to draw the lessons learned from this first wave and to set-up the criteria for a successful transition ...
2009-10-12
Temperature dependence of threshold current of injection lasers for short pulse excitation
Energy Technology Data Exchange (ETDEWEB)
We report measurements of the temperature dependence of the threshold current of GaAs, 1.3-..mu..m InGaAsP, and 1.5-..mu..m InGaAsP double heterostructure lasers using short electrical pulses. T/sub 0/approx.200 K is observed for all the lasers. These high T/sub 0/ values show that the carrier density at threshold does not increase rapidly with increasing temperature in any of the lasers studied and thus the observed low cw T/sub 0/ of InGaAsP lasers is primarily due to a decrease of the carrier lifetime at threshold with increasing temperature.
1984-05-15
Studies of basic parameters of electron-counting detection
International Nuclear Information System (INIS)
Measurements have been made of certain parameters relevant to the operation of electron-counting detectors. An experimental chamber consisting of a uniform-field drift tube and a coaxial proportional counter thas been employed to obtain data, at very low drift fields (E/p<0.02 V/cm Torr), on electron mobility and lifetimes in a range of gas mixtures. These mixtures included argon, methane, nitrogen and carbon dioxide. Measurements of single-electron spectra showed that, unexpectedly for the standard gas mixtures employed, useful departure from an exponential spectrum was not possible without the production of cathode secondaries. Although the present studies employed only the counter electrical signal the information obtained should be directly relevant to the operation of practical light-pulse systems. Examples of electron-counting spectra for soft X-rays are shown. (orig.).
1990-05-21
Structure and properties of Li2Zn2(MoO4)3 crystals activated with copper and chromium ions
British Library Electronic Table of Contents (United Kingdom)
Based on the corrected phase diagrams proper growth conditions for Li2Zn2(MoO4)3 crystals are selected. Large crystals (up to 100 mm), both impurity-free and activated by transition metal ions (Cu, Cr), are grown by the low-gradient Czochralski method. By the EPR method the charge state and structural position of copper and chromium ions are determined. The performed studies of luminescent properties show that for impurity-free crystals luminescence with ? = 388 nm with a two-exponential luminescence decay with ?1 = 2 ns and ?2 = 6 ns is observed at room temperature. At 77 K for both impurity-free crystals and those activated with transition metal ions luminescence with ? = 560 nm and the luminescence lifetime ? = 100 ns is observed, the intensity of luminescence with ? = 560 nm depending ...
2011-01-01
International Nuclear Information System (INIS)
In this paper, steady-state isotopic transient kinetic analysis (SSITKA) is used to study two model reactions, CO oxidation and CO-NO reactions, on a typical formulation of a three-way auto-catalyst. Under steady-state conditions, abrupt switches in the isotopic composition of CO ("1"2C"1"6O/"1"3C"1"8O) were carried out to produce isotopic transients in both labeled reactants and products. Along with the determination of the average surface lifetimes and concentrations of reaction intermediates, an analysis of the transient responses along the carbon reaction pathway indicated that the distribution of active sites for the formation of CO_2 was bimodal for both reactions. Furthermore, relatively few surface sites contributed to the overall reaction rate.
1991-08-25
Spontaneously generated atomic entanglement in free space: reinforced by incoherent pumping
We study spontaneously generated entanglement (SGE) between two identical multilevel atoms in free space via vacuum-induced radiative coupling. We show that the SGE in two-atom systems may initially increase with time but eventually vanishes in the time scale determined by the excited state lifetime and radiative coupling strength between the two atoms. We demonstrate that a steady-state SGE can be established by incoherently pumping the excited states of the two-atom system. We have shown that an appropriate rate of incoherent pump can help producing optimal SGE. The multilevel systems offer us more chanel to establish entanglement. The system under consideration could be realized in a tight trap or atoms/ions doped in a solid substrate.
2009-01-01
Spectroscopy and photophysics of mono methyl-substituted alloxazines
Energy Technology Data Exchange (ETDEWEB)
Singlet-singlet and triplet-triplet absorption spectra of a series of methyl-alloxazines were calculated using the time-dependent density-functional theory approach and compared to experimental results. The B3LYP functional provides good correlation between experimental and theoretical results, given that solvent effects are disregarded in the present calculations. Substituent and solvent dependences of the lowest, closely spaced, n,{pi}* and {pi},{pi}* excited state energies are discussed, their order being of consequence in determining the non-radiative decay rates and thus emission quantum yields and lifetimes. The high quantum yields of singlet oxygen formation indicate that the triplet state is formed by efficient intersystem crossing from the first singlet excited state.
2004-05-31
British Library Electronic Table of Contents (United Kingdom)
Theory predicts trade-offs between investment in various life history traits, and it is also now generally accepted that reproduction is costly for males. Males must therefore optimize resource allocation across several episodes of reproduction, and this includes investment in both pre- and postcopulatory fitness components. We investigated this in the sperm-polymorphic Indian meal moth, Plodia interpunctella. Resource-limited males were smaller, and had decreased precopulatory mating success, measured as lifetime number of matings. However, they transferred similar numbers of fertile sperm as males reared under high-quality larval conditions, and more nonfertile sperm. By mating less frequently, resource-limited males may allocate sufficient resources to the matings they achieve to ensure...
2011-01-01
Severe mood dysregulation: In the "light" of circadian functioning
British Library Electronic Table of Contents (United Kingdom)
Severe affective and behavioral dysregulation, labeled as severe mood dysregulation (SMD), is a widely spread phenomenon among adolescent psychiatric patients. This phenotype constitutes severe impairment across multiple settings, including various symptoms, such as non-episodic anger, mood instability, and hyperarousal. Moreover, SMD patients often show depression and reduced need for sleep. Despite a lifetime prevalence of 3.3%, systematic research is still scarce, and treatments that have been established do not account for the range of symptoms present in SMD. Considering the circadian dysfunctions, two hormones, melatonin and cortisol, are essential. When these hormones are dysregulated, the circadian rhythm gets out of synchrony. Since evidence is emerging showing that the worse the ...
2011-01-01
Search for Neutron-Antineutron Oscillations Using Multiprong Events in Soudan 2
We have searched for neutron-antineutron oscillations using the 5.56 fiducial kiloton-year exposure of the Soudan 2 iron tracking calorimeter. We require candidate n-nbar occurrences to have .GE. 4 prongs (tracks and showers) and to have kinematics compatible with nbar-N annihilation within a nucleus. We observe five candidate events, with an estimated background from atmospheric neutrino and cosmic ray induced events of 4.5 \\pm 1.2 events. Previous experiments with smaller exposures observed no candidates, with estimated background rates similar to this experiment. We set a lifetime lower limit for oscillation time in iron: T_A(Fe) > 7.2x10^{31} years. The corresponding lower limit for oscillation of free neutrons is \\tau_{n-nbar} > 1.3x10^8 seconds.
2002-01-01
SP-100 fuel pin performance: Results from irradiation testing
Energy Technology Data Exchange (ETDEWEB)
A total of 86 experimental fuel pins with various fuel, liner, and cladding candidate materials have been irradiated in the Experimental Breeder Reactor-II (EBR-II) and the Fast Flux Test Facility (FFTF) reactor as part of the SP-100 fuel pin irradiation testing program. Postirradiation examination results from these fuel pin are key in establishing performance correlations and demonstrating the lifetime and safety of the reactor fuel system. This paper provides a brief description of the in-reactor fuel pin tests and presents the most recent irradiation data on the performance of wrought rhenium (Re) liner material and high density UN fuel at goal burnup of 6 atom percent (at. %). It also provides an overview of the significant variety of other fuel/liner/cladding combinations which were irradiated as part of this program and which may be of interest to more advanced efforts.
1993-09-01
Respiratory exposure in buildings due to radon progeny
International Nuclear Information System (INIS)
The #alpha# radiation dose to the lungs of people who live in buildings constructed of some granites, low density concretes, and gypsum boards is higher than for residents of most other types of dwellings due to the air-borne progeny of radon. There is evidence that sealing the interior surfaces with epoxy paint, for example, can reduce the #alpha# dose to the lung significantly without a compensating increase in whole-body exposure to the #gamma#-rays from radon progeny. Based on the incidence rates for lung cancer in uranium miners, a concentration of radon of the order of 1 to 5 pCi/l. appears to be a reasonable limit for 'lifetime' exposure indoors for 'typical' home ventilation conditions. (author).
1976-01-01
Recent strategy and progress in Korean nuclear PLIM program
International Nuclear Information System (INIS)
The strategy for the Korean nuclear power plant lifetime management (PLIM) program, which has been developed over the last 3 years, is introduced, together with descriptions of recent events and related maintenance activities. This leading Korean PLIM project has been focused on such areas as a plant data survey, screening and prioritization of systems, structures and components (SSCs), aging evaluation of major components, economic analysis and regulatory issues. The current status is outlined in terms of major tasks including aging evaluation of 13 major components. The future long-term plan which eventually aims at maximizing the economic benefit for both the utility and its customers is presented. Also described is the technical development required for plant life extension. (orig.).
1996-05-08
Radon concentration measurements in bituminous coal mines
Energy Technology Data Exchange (ETDEWEB)
Radon measurements were carried out in Kozlu, Karadon and Uzulmez underground coal mines of Zonguldak bituminous coal basin in Turkey. Passive-time integrating method, which is the most widely used technique for the measurement of radon concentration in air, was applied by using nuclear etched track detectors (CR-39) in the study area. The radon concentration measurements were performed on a total of 42 points in those three mines. The annual exposure, the annual effective dose and lifetime fatality risk, which are the important parameters for the health of workers, were estimated based on chronic occupational exposure to the radon gas, which is calculated using UNCEAR-2000 and ICRP-65 models. The radon concentrations at several coal production faces are higher than the action level of 1000 Bq m{sup -3}. It is suggested that the ventilation rates should be rearranged to reduce the radon concentration.
2005-07-01
Radioactive waste disposal for fission and fusion reactors
Energy Technology Data Exchange (ETDEWEB)
The calculated radioactive waste inventories of the Turkey Point pressurized water fission reactor (PWR) and the Starfire conceptual fusion tokamak are compared as a function of time from initial start-up to 10,000 years after decommissioning. Only material out of reactor at least one year is considered. The total activity in Ci/W(th) of the Starfire tokamak is slightly greater than that of the PWR during the active lifetimes of the two reactors and beyond 1000 years. However, using reduced activation materials in Starfire can result in about 1/2000 as much long-lived radioactivity as in the fission reactor. It is stressed that comparison of wastes on this basis is not straightforward, since the radioisotopes and methods required for their disposal are different for fusion and fission reactors. 2 refs., 1 fig., 2 tabs.
1989-01-01
Radiation hardening of smart electronics
International Nuclear Information System (INIS)
Microprocessor based ''smart'' pressure, level, and flow transmitters were tested to determine the radiation hardness of this class of electronic instrumentation for use in reactor building applications. Commercial grade Complementary Metal Oxide Semiconductor (CMOS) integrated circuits used in these transmitters were found to fail at total gamma dose levels between 2500 and 10,000 rad. This results in an unacceptably short lifetime in many reactor building radiation environments. Radiation hardened integrated circuits can, in general, provide satisfactory service life for normal reactor operations when not restricted to the extremely low power budget imposed by standard 4--20 mA two-wire instrument loops. The design of these circuits will require attention to vendor radiation hardness specifications, dose rates, process control with respect to radiation hardness factors, and non-volatile programmable memory technology. 3 refs., 2 figs.
Protoplanetary Disks of Binary Systems in Orion
Dusty primordial disks surrounding young low-mass stars are revealing tracers of stellar and planetary formation. The evolution and lifetime of these disks define the boundary conditions of the mechanisms of planet formation. Stellar companions, however, can significantly change this evolution through their tidal interactions. Stellar evolution and planet formation in binaries have to respond to an environment of truncated, quickly disappearing disks--very different compared to an isolated star environment. In order to investigate details of the influence of binarity on circumstellar disk evolution, we obtained adaptive optics supported near-infrared imaging and spectroscopy of the individual components of 22 low-mass binaries in the well-known Orion Nebula Cluster. Brackett gamma emission, which we detect in several systems, is used as a tracer for the presence of an active accretion disk around each binary component. We find a low fraction of accreting binary ...
2010-01-01
Permeation barrier properties of thin oxide films on flexible polymer substrates
Energy Technology Data Exchange (ETDEWEB)
Solar cells and organic electronic devices require an encapsulation to ensure sufficient lifetime. Key parameters of the encapsulation are permeation barrier, UV stability, temperature stability, optical transmission spectra and mechanical stability. The requirements depend very much on the specific application. Many work groups suggest multilayer stacks to meet the permeation requirements. In this paper the permeation barrier properties of the different constituents of such a multilayer stack are characterized. Different layer materials are compared regarding their water vapour and oxygen permeability as well as the influence of process parameters is examined. Finally temperature dependent permeation measurements are used to characterize the permeation mechanisms in the different constituents of the multilayer barrier.
2009-03-31
Optical properties and up-conversion of Pr"3"+ doped CdS nanoparticles in sol-gel glasses
International Nuclear Information System (INIS)
Silica glasses containing Pr"3"+ with and without CdS nanoparticles were prepared by sol-gel technique. The influence of CdS nanoparticles on Pr"3"+ doped glass was studied by absorption, photoluminescence and up-conversion. From the measured intensities of various absorption bands of these glasses, the Judd-Ofelt parameters ?_2, ?_4 and ?_6 have been evaluated. The radiative transition probability (A), radiative lifetime (?_R), branching ratio (?_R) and integrated emission cross-section (?_P) were calculated from excited states of "3P_1 and "3P_0 levels. The up-conversion emissions were found in the green, orange and red regions under 800 nm excitation with peaks 559, 612 and 688 nm respectively. On excitation with 370 nm also leads to similar green, orange and red regions.
2010-10-01
Nuclear magnetic moment measurements through hyperfine interactions in highly stripped ions
International Nuclear Information System (INIS)
Time-differential magnetic moment measurements on the first-excited Isup(#pi#)=2"+ states in "2"0Ne and "2"4Mg with mean lives of 1.0 and 2.1 ps, respectively are described. The lifetime of the latter state was determined simultaneously. A special detection geometry was designed to improve the experimental #gamma#-ray anisotropy measured with finite-size detectors. For "2"0Ne also a time-integral measurement with charge-state separation was performed. The necessary electronics circuitry built to perform these complicated measurements and the plunger assembly with laser interferometer are also described. A magnetic moment measurement of "2"2Ne(2_1"+) with tau=5.0 ps and transient field measurements at low and high recoil velocities are reported. A discussion of possible extensions of the techniques are given. (Auth.).
1975-09-15
Energy Technology Data Exchange (ETDEWEB)
This report describes progress during the first year of a three-year project. The objective of the research is to examine new design approaches for achieving very high conversion efficiencies. The program is divided into two areas. The first centers on exploring new thin-film approaches specifically designed for III-V semiconductors. The second area centers on exploring design approaches for achieving high conversion efficiencies without requiring extremely high quality material. Research activities consisted of an experimental study of minority carrier recombination in n-type, metal-organic chemical vapor deposition (MOCVD)-deposited GaAs, an assessment of the minority carrier lifetimes in n-GaAs grown by molecular beam epitaxy, and developing a high-efficiency cell fabrication process.
1993-01-01
New III-V cell design approaches for very high efficiency
Energy Technology Data Exchange (ETDEWEB)
This report describes progress during the first year of a three-year project. The objective of the research is to examine new design approaches for achieving very high conversion efficiencies. The program is divided into two areas. The first centers on exploring new thin-film approaches specifically designed for III-V semiconductors. The second area centers on exploring design approaches for achieving high conversion efficiencies without requiring extremely high quality material. Research activities consisted of an experimental study of minority carrier recombination in n-type, metal-organic chemical vapor deposition (MOCVD)-deposited GaAs, an assessment of the minority carrier lifetimes in n-GaAs grown by molecular beam epitaxy, and developing a high-efficiency cell fabrication process.
1993-01-01
Energy Technology Data Exchange (ETDEWEB)
Excitation of low temperature helium or helium/water plasma and subsequent exposure to air of polyacrylonitrile (PAN) ultrafiltration membranes was used to hydrophilize the surface of these materials. We analyzed the effectiveness of this approach as a function of plasma operating variables including gas phase composition, plasma power, treatment time and system pressure. Following the changes in physical and chemical composition of the PAN surface resulting from these modifications was a major aspect of this work. Techniques such as the captive bubble contact angle method, ellipsometry, ESCA, and FTIR-ATR were all used. In addition, the formation and life-time of peroxides during these processes were determined. At low powers (<25W) and short treatment periods ({<=}30 sec), the main chemical conversion of PAN surfaces was simultaneous hydrophilization and stabilization via PAN cyclization. Relatively small water permeability changes were observed as a result ...
1995-12-01
Energy Technology Data Exchange (ETDEWEB)
Lifetime observations on a group of 358 rhesus monkeys indicate that life expectancy loss from exposure to protons in the energy range encountered in the Van Allen belts and solar proton events is influenced primarily by the dose rather than the energy of radiation. After 24 years, life expectancy losses from similar surface doses of low-LET (138-2300 MeV) and high-LET (32-55 MeV) protons are not significantly different, but the high-LET protons are associated with more deaths in the early years, while the low-LET protons contribute more to mortality in later years. In males, the most significant cause of life shortening is nonleukemia cancers.
1990-05-01
Life span of multipotential hematopoietic stem cells in vivo
Energy Technology Data Exchange (ETDEWEB)
The findings reported in this study highlight several important features of the development of hematopoietic stem cells after transplantation into irradiated recipients. First, they demonstrate the existence of a class of primitive multipotential stem cells that can function for a significant portion of the lifetime of a mouse (15 mo). In addition, they clearly show that these primitive stem cells can be infected with recombinant retroviruses and thus would be appropriate targets for gene therapy in somatic tissues. Second, our data indicate that the progeny of some, but not all, of the primitive stem cells have fully expanded into the various hematopoietic lineages by 2 mo after reconstitution. Finally, our analysis of the secondary recipients provides strong evidence suggesting that the primitive stem cell population can actually clonally expand. Our current experiments are aimed at determining the extent to which this expansion can occur and whether or not this ...
1990-05-01
Increased performance of bearings using TiC-coated balls
Energy Technology Data Exchange (ETDEWEB)
The main purpose of solid or fluid lubricants in ball-bearings is to separate the balls and races from contacting each other in so-called asperity collisions. Steel to steel contacts lead to microwelds which roughen functional rolling-contacting surfaces and deteriorate the lubricant. By using balls with a ceramic TiC coating, two goals are achieved. First, there are fewer asperity collisions because of the extreme smoothness of the high precision polished TiC coated balls. Second, if collisions do occur, there is practically no microwelding taking place, leaving the surfaces and the lubricant in good condition. Examples are given where the bearing lifetime is increased up to 10 times if the steel balls are replaced by TiC-coated balls. (orig.).
1993-11-01
Energy Technology Data Exchange (ETDEWEB)
Contamination and blockages of the cooling tubes in the turbine condenser disturb the heat transfer, thereby causing power losses at the turbine and increasing the fuel demand. Corrosions cause tubing leakages which require operating downtimes and reduce the lifetime of the pipes. Tube cleaning systems and backflushing cooling water filters eliminate these problems. Nevertheless it can come to coatings in the condenser tubes, if the tube cleaning equipment does not operate optimally or if coarse dirt is entered. Under this aspect, the author of the contribution under consideration reports on these problems on the basis of practical examples. The author gives references to the optimized operation of the tube cleaning system and the cooling water filtration.
2010-07-01
Glance Information System for ATLAS Management
ATLAS Experiment is an international collaboration where more than 37 countries, 172 institutes and laboratories, 2900 physicists, engineers, and computer scientists plus 700 students participate. The management of this teamwork involves several aspects such as institute contribution, employment records, members' appointment, authors' list, preparation and publication of papers and speakers nomination. Previously, most of the information was accessible by a limited group of people and the system used was not designed to handle new requirements easily. Moreover, developers had to face problems such as different terminology, diverse data modeling, heterogeneous databases and unlike users needs. Besides that, the maintenance has to be an easy task considering the long lifetime experiment and professionals turnover. The Glance system, a generic mechanism for accessing any database, acts as an intermediate layer isolating the user from the particularities of each ...
2011-01-01
Fluctuons and large momentum transfer to complex systems
International Nuclear Information System (INIS)
Possible mechanisms of the cumulative production of particles in the processes of high momentum transfers to complex systems are discussed. Production of the multi-nucleon systems, the so-called fluctons, during collision of a high-energy particle with a nucleus, is proposed as a most realistic explanation of the cumulative effect. A probability of the flucton production in nucleus and its interaction with the incident particle are investigated. A possible origin of fluctons, considered, in the framework of the quark bag model, as quasistable states with the definite coupling energy and the lifetime, is studied. A probability for the presence of a flucton, as multibaryon configuration in a nucleus is evaluated. The production of multibaryon configurations in a nucleus is demonstrated to show up as a presence of strong multiparticle repulsion at small distances, which cannot be reduced only to two-particle interactions.
Fingerprint testing of contaminated ventilation extract filter systems at Sizewell B
International Nuclear Information System (INIS)
Sizewell B is Nuclear Electric's latest power station, and the Pressurised Water Reactor (PWR) design on which it is based represents a ''first'' for the UK. One of the integral components of the plant is the heating, ventilation and air-conditioning (HVAC) system, which performs a contamination control and gaseous waste management function for the site. During the commissioning of Sizewell B Power Station the extract systems of the HVAC plant underwent a procedure known as ''fingerprinting''. This entailed the characterisation of the facilities provided to test the filtration plant during its lifetime. The assessment of their adequacy was then used to identify necessary modifications and/or to propose the manner in which future in situ performance testing would be carried out. The paper outlines the basic principles and procedure that was used to ''fingerprint'' test systems during the commissioning of Sizewell B. A specific example is presented to demonstrate the ...
Familiar and environmental factors influencing atopic dermatitis in the childhood
British Library Electronic Table of Contents (United Kingdom)
Abstract Background The increase in the incidence of atopic dermatitis (AD) in developed countries has been related to familiar and environmental factors. This survey was undertaken to investigate the family background, birthweight and the home environment of children suffering from AD in order to point out the possible factors that provoke the development of the disease. Methods The study uses data collected by means of self-administered questionnaires and discusses 461 cases of children (age 0-12) with active skin signs of AD. The control group comprised of 343 children (age 0-12) with no skin signs or positive lifetime history of AD. Associations between familiar and various home environmental factors and the risk of AD were calculated by means of odds ratios. Results There were statist...
2006-01-01
Fabrication of core demonstration experiments for irradiation in FFTF [Fast Flux Test Facility
International Nuclear Information System (INIS)
A major initiative to develop and irradiate a long-life, mixed-oxide fuel system in the Fast Flux Test Facility (FFTF) has been implemented by Westinghouse Hanford Company for the US Department of Energy. The FFTF, shown in Figures 1 and 2, is a 400 megawatt thermal, fast liquid metal reactor that tests liquid metal, space and fusion fuels and materials. The new fuel system, called the Core Demonstration Experiment (CDE) demonstrates the capability of achieving a three- to four-year life in a prototypic heterogeneous reactor environment under prototypic power and temperature conditions. This fuel system will greatly increase fuel performance and lifetime from the current standard FFTF driver fuel. New design features, fabrication development, CDE assembly fabrication, and irradiation status have been described.
1990-06-10
British Library Electronic Table of Contents (United Kingdom)
BACKGROUND.The National Breast and Cervical Cancer Early Detection Program (NBCCEDP) covers the direct clinical costs of breast and cervical cancer screening and diagnostic follow-up for medically underserved, low-income women. Personal costs are not covered. In this report, the authors estimated personal costs per woman participating in NBCCEDP mammography screening by race/ethnicity and also estimated lifetime personal costs (ages 50-74 years).METHODS.A decision analysis model was constructed and parameterized by using empiric data from a retrospective cohort survey of mammography rescreening among women ages 50 years to 64 years who participated in the NBCCEDP. Data from 1870 women were collected from 1999 to 2000. The model simulated the flow of resources incurred by a woman participat...
2008-01-01
Dynamical Quasi-Stationary States in a system with long-range forces
The Hamiltonian Mean Field model describes a system of N fully-coupled particles showing a second-order phase transition as a function of the energy. The dynamics of the model presents interesting features in a small energy region below the critical point. In particular, when the particles are prepared in a ``water bag'' initial state, the relaxation to equilibrium is very slow. In the transient time the system lives in a dynamical quasi-stationary state and exhibits anomalous (enhanced) diffusion and L\\'evy walks. In this paper we study temperature and velocity distribution of the quasi-stationary state and we show that the lifetime of such a state increases with N. In particular when the $N\\to \\infty$ limit is taken before the $t \\to \\infty$ limit, the results obtained are different from the expected canonical predictions. This scenario seems to confirm a recent conjecture proposed by C.Tsallis.
2001-01-01
Calculation of the X-ray emission spectra of VC and VN
International Nuclear Information System (INIS)
From self-consistent band structure calculations using the 'augmented plane wave'(APW) method, the density of states can be decomposed into local partial (according to azimuthal quantum number l) components, the l-character densities. Within the APW formalism the intensity of X-ray emission spectra is determined by radial transition probabilities and l-character densities of such valence states, which reside inside the same atomic sphere as the core vacancy and whose quantum number l differs by +-1 from the one corresponding to the core state. By taking into account lifetime broadening of the core and valence states and also the instrumental broadening the computed spectra (non-metal K-, vanadium K- and Lsub(III)-spectra) agree well with experiment. (orig.).
Assessing the environmental impacts of resource recovery facilities
Energy Technology Data Exchange (ETDEWEB)
Technologies and practices that recover energy and materials from municipal solid waste present a technically and economically viable alternative to sanitary landfills and other solid waste disposal methods. However, community planners considering resource recovery should be aware of the potential environmental impacts of proposed projects. To assess these impacts, a planner should: identify the most significant types of impacts; establish boundaries beyond which impacts are not significant; characterize the environment as it would exist without the proposed project over the project's lifetime; predict the magnitude, and the distribution over time and space, of potential impacts; and relate the magnitude of predicted impacts to a scale of significance that will allow environmental values to be considered in decision-making. 24 references, 1 table.
1980-03-01
Analysis on anomalous degradation in silicon solar cell designed for space use
Energy Technology Data Exchange (ETDEWEB)
Recently, we have found the anomalous degradation of electrical performance in silicon solar cells irradiated with charged particles in a high-fluence region. This anomalous phenomenon has two typical features, which are sudden-drop-down of electrical performances in a high-fluence region and slight recovery of the short circuit current I{sub SC} just before the sudden-drop-down. These features cannot be understood by a conventional model coming from the decrease of minority-carriers life-time. We introduce this anomalous degradation of the electrical performance in Si solar cells irradiated with electrons or protons. We also report the result of simulation for the fluence dependence of the I{sub SC}, and discuss the mechanism of this anomalous phenomenon. (author)
1997-03-01
International Nuclear Information System (INIS)
The major degradation mechanisms acting during the aging of selected WWER-440/213 primary circuit facilities were assessed critically. The analysis gave evidence that such mechanisms include radiation and fatigue damage of the reactor pressure vessel (effect of the neutron flow, cyclic fatigue promoted by the corrosive medium, effect of thermal aging), corrosion-mechanical and thermo-mechanical (fatigue) damage of the steam generator (stress corrosion cracking, erosion corrosion, thermal aging, wear), thermal and dynamic aging of the pressurizer, and corrosion-mechanical damage of the primary circuit piping (thermal aging, corrosion). (J.B.). 5 tabs., 1 fig., 62 refs.
Alignment of nematic liquid crystals on mixed Langmuir-Blodgett mono-layers
Mono-layers of stearic and behenic acids and mixtures of them in different proportions, deposited with the Langmuir-Blodgett technique, were used to study the alignment and the alignment dynamics in nematic liquid crystal cells. A relaxation process from a splay-bend flow induced metastable orientation to the homeotropic one occurs. The lifetime of the metastable state was found to depend on the mono-layer composition. The transition between the homeotropic and the conical anchoring was found to be irreversible in the case of the mixed aligning mono-layers: on cooling from the isotropic phase a quasi-planar nematic state (schlieren texture) appears. It is stable in a range of a few degrees below the clearing point and, on decreasing the temperature, relaxes to the homeotropic state in form of expanding domains.
1998-01-01
Alignment and alignment dynamics of nematic liquid crystals on Langmuir-Blodgett mono-layers
Mono-layers of stearic and behenic acids deposited with the Langmuir-Blodgett technique, were used as aligning films in nematic liquid crystal cells. During the filling process the liquid crystal adopts a deformed quasi-planar alignment with splay-bend deformation and preferred orientation along the filling direction. This state is metastable and transforms with time into homeotropic once the flow has ceased. The transition is accompanied by formation of disclination lines which nucleate at the edges of the cell. The lifetime of the metastable splay-bend state was found to depend on the cell thickness. On heating, anchoring transition from quasi-homeotropic to degenerate tilted alignment in form of circular domains takes place near the transition to the isotropic phase. The anchoring transition is reversible with a small hysteresis.
1998-01-01
Ab initio relativistic many-body calculation of hyperfine splitting of ^{113}Cd^+
This work presents accurate ab initio determination of the hyperfine splitting for the ground state and few low-lying excited states of 113Cd+; important candidates for the frequency standard in the microwave region, using coupled-cluster theory (CC) in the relativistic framework. The calculated hyperfine splitting are well in agreement with recent experimental results. We have also carried out the lifetimes of the 5p2P1=2 and 5p2P3=2 states, which are in well agreement with recent experimental result (Moehring et al., PRA 73 023413, 2006). The roles of different electron correlation effects in the determination of these quantities are discussed and their contributions are presented in the CC terms.
2007-01-01
A model for Schottky-barrier solar cell analysis
A general model for the analysis of metal-semiconductor solar cells is presented. The model takes into account the cell optical properties, carrier recombination effects, semiconductor minority-carrier properties, series resistance, cell thickness, and active surface area. Numerical methods are used to solve the appropriate continuity equations and hence compute the photocurrent density under AMO conditions. The operation of the model is demonstrated using p- and n-type Si and GaAs with Au being taken as the barrier metal. Calculations are presented showing the effect on solar energy conversion efficiency of surface recombination velocity, barrier height, minority-carrier lifetime, barrier metal thickness, collecting grid configuration, and cell thickness. A comparison of practical and computed data for the Au/n-GaAs system yields good agreement. (AIP)
1976-05-01
A He-gas Cooled, Stationary Granular Target
In the CERN approach to the design of a neutrino factory, the repetition frequency of the proton beam is high enough to consider stationary solid targets as a viable solution for multi-MW beams. The target consists of high density tantalum spheres of 2 mm diameter which can efficiently be cooled by passing a high mass flow He-gas stream through the voids between the Ta-granules. Very small thermal shocks and stresses will arise in this fine grained structure due to the relatively long burst of 3.3 ms from the SPL-proton linac. In a quadruple target system where each target receives only one quarter of the total beam power of 4 MW, conservative temperature levels and adequate lifetimes of the target are estimated in its very high radiation environment. A conceptual design of the integration of the target into the magnetic horn-pion-collector is presented.
2003-01-01
International Nuclear Information System (INIS)
In 1959 Zeldovich pointed out to the possibility of storage in a closed vessel of very slow neutrons with energies below less than or equal to 10"-"7 eV noting that one may achieve the storage time up to the lifetime of a free neutron before #beta#-decay (approx.10"3 sec). This possibility is due to the effective repulsing potential which describes the interaction of slow neutrons with many substances employing a strong suppression of inelastic processes in the reflection of ultracold neutrons (UCN). In a series of experiments beginning 1968 the effective methods were developed of obtaining pure UCN beams from the maxwellian spectrum of thermal neutrons. The UCN beams of intensity about 10"3 n/sec and density up to 10"2 n/liter were obtained at the reactors with thermal neutron flux of 5 x 10"1"3 n/cm"2 sec. Such UCN beam parameters allow to measure easily the UCN storage time in different vessels and under different conditions. Maximum UCN storage time achieved in ...
1976-07-06
Structures and properties of fluorinated amorphous carbon films
International Nuclear Information System (INIS)
Fluorinated amorphous carbon (a-C:F) films were deposited by radio frequency bias assisted microwave plasma electron cyclotron resonance chemical vapor deposition with tetrafluoromethane (CF_4) and acetylene (C_2H_2) as precursors. The deposition process was performed at two flow ratios R=0.90 and R=0.97, where R=CF_4/(CF_4+C_2H_2). The samples were annealed at 300 deg. C for 30 min. in a N_2 atmosphere. Both Fourier transform infrared and electron spectroscopy for chemical analyzer were used to characterize the a-C:F film chemical bond and fluorine concentration, respectively. A high resolution electron energy loss spectrometer was applied to detect the electronic structure. The higher CF_4 flow ratio (R=0.97) produced more sp"3 linear structure, and it made the a-C:F film smoother and softer. A lifetime of around 0.34 #mu#s and an energy gap of #approx#2.75 eV were observed in both the as-deposited and after annealing conditions. The short carriers ...
2004-07-01
Luminescence and laser transition studies of Dy3+:K-Mg-Al fluorophosphate glasses
International Nuclear Information System (INIS)
Dysprosium ion doped fluorophosphate glasses with compositions of PKMAFDy: (56-x/2) P2O5+17K2O+8Al2O3+(15-x/2)MgO+4AlF3+xDy2O3 (x=0.01, 0.05, 0.1, 1.0 and 2.0 mol%) have been prepared by melt quenching technique and are characterized by optical absorption, emission spectra and fluorescence lifetime measurements. The observed bands in the absorption spectrum are analysed by using free-ion Hamiltonian (HFI) model. The Judd-Ofelt (JO) analysis has been performed and the intensity parameters (??, ?=2, 4, 6) have been evaluated that are used to predict radiative properties. From emission spectra, the effective bandwidth (??eff) and the stimulated emission cross-section (?(?p)) were evaluated. The fluorescence decay from the 4F9/2 level of Dy3+ ions have been measured by monitoring the intense 4F9/2#->#6H13/2 transition (573 nm). The lifetimes (?) are found to decrease with increasing concentration due to concentration quenching. The decay curves ...
2009-02-28
Higgs particles in the standard model and supersymmetric theories
International Nuclear Information System (INIS)
This thesis presents a theoretical analysis of the properties of the Higgs bosons in the standard model (SM) and the minimal supersymmetric extension (MSSM), which can be investigated at the LHC and e"+e"- linear colliders. The final goal is the reconstruction of the Higgs potential and thus the verification of the Higgs mechanism. MSSM Higgs boson production processes at future #gamma##gamma# colliders are calculated in several decay channels. Heavy scalar and pseudoscalar Higgs bosons can be discovered in the bb final state in the investigated mass range 200 to 800 GeV for moderate and large values of tan#beta#. The #tau#"+#tau#"- channel provides a heavy Higgs boson discovery potential for large values of tan#beta#. Several mechanisms that can be exploited at e"+e"- linear colliders for the measurement of the lifetime of a SM Higgs boson in the intermediate mass range are analysed. In the WW mode, the lifetime of Higgs scalars with masses ...
International Nuclear Information System (INIS)
The H-SAPS (Hydrogen Stand-Alone Power System) project, an EU project within the ALTENER programme in the period 2002-2004, was initiated to determine the potential for the introduction of environmentally benign hydrogen technology in what is believed to be a near-term market, namely stand-alone power systems (SAPS). The objective of the project was to examine the technological, political, social and economical factors affecting the emergence of hydrogen technology in the stand-alone power system market today and in the future. The scope of the project was limited to small and medium sized stand-alone power systems, up to a few hundred kilowatts (kW) power rating and based on renewable energy as the primary energy source. The work was divided into five phases: (1) Inception, (2) Data collection and analysis, (3) Market analysis and barrier removal, (4) Dissemination, and (5) Final report. Separate reports were written on these topics, and later summarised this final report. The ...
1992-10-01
Energy Technology Data Exchange (ETDEWEB)
This report for the Swiss Federal Office of Energy (SFOE) presents the overview reports made by SFOE Heads of Program on work done in 2007. Projects reported on in the natural gas-fired fuel cell area include the EU-project REAL-SFOC, the long-term testing of anode-supported SOFC stacks, intermediate-temperature fuel cells based on proton conducting electrolytes, the interdisciplinary ONEBAT project and lifetime-enhancement of SOFC stacks for CHP applications. In the polymer-electrolyte fuel cell (PEFC) area, projects concerning proton-conducting polymer membranes, factors limiting the lifetime of fuel cell membranes, a new highly active oxygen reduction electrode for PEM fuel cell and zinc/air battery applications, the enhancement of PEFC durability and reliability, model-based investigation of PEFC performance, and local gas analysis of PE fuel cells are briefly reported on. Long-term research activities in the hydrogen technology area ...
2008-07-01
Energy Technology Data Exchange (ETDEWEB)
Smooth and notched specimens of the bearing steel 100Cr6 (SAE 52100) in a bainitic condition were used to determine the S-N curves under tensile, torsional and combined in- and out-of-phase loading. In the area of high-cycle fatigue, crack initiation was most likely caused by inclusions like Titanium Carbonnitrides or Aluminium Oxides. A micro mechanical model for the crack initiation by inclusions was developed. Another model was developed to describe the influence of these inclusions on the lifetime. A weakest-link model, using the statistical distribution of inclusions and surface flaws, was used to describe the endurance limit. (orig.) [German] Es wurden Woehlerlinien unter Zug-Druck-, Torsions- sowie kombinierter phasengleicher und phasenverschobener Zug-Druck- und Torsionsbelastung fuer glatte und gekerbte Proben des Stahls 100Cr6 (SAE 52100) im bainitischen Zustand erstellt. Im Bereich der Langzeitermuedung gingen die Risse meistens von nichtmetallischen ...
2002-05-01
Expectations of immortality: dam safety management into the next millennium
Energy Technology Data Exchange (ETDEWEB)
Topics concerning the problems associated with older and aging dams are considered including: what can be done to extent the lifetime of an old dam, the decision to decommission a dam based on a value judgment that the risk of maintaining the dam is too great for society's acceptance, the possibility of change in the level of risk tolerance with time in a technological environment, traditional surveillance methods used by dam owners in the Y2K situation, and the unreality of dam immortality. Trends and means for preserving older dams for their owner's purposes are outlined, as well as their lifetime compared to that of the downstream systems they serve. Despite the fact that we live in a throwaway society, dam owners cannot just leave their dam asset when they are through with using it. Someone has to maintain the dam, or ensure that it is safely decommissioned when the owner is finished with it. On a worldwide scale the ...
1999-07-01
Energy Technology Data Exchange (ETDEWEB)
Section 127 of the Energy Policy Act requires that the Department of Energy (DOE) prepare a report to Congress on the potential for the development and commercialization of appliances that substantially exceed the present federal or state efficiency standards. Candidate high-efficiency appliances must meet several criteria including: the potential exists for substantial improvement (beyond the minimum established in law) of the appliance`s energy efficiency; electric, water, or gas utilities are prepared to support and promote the commercialization of such appliances; manufacturers are unlikely to undertake development and commercialization of such appliances on their own, or development and production would be substantially accelerated by support to manufacturers. This report describes options to improve the efficiency of residential appliances, including water heaters, clothes washers and dryers, refrigerator/freezers, dishwashers, space heating and cooling devices, as well as ...
1995-01-01
Energy Technology Data Exchange (ETDEWEB)
Experiments for lifetime prediction of the first wall are being carried out within the framework of the European fusion reactor programme. Defects such as notches and cavities may develop in the first wall and may initiate under cyclic thermal stress cracking processes which may reduce the service life of the material. For examination of crack growth, specimens with defined initial notches were prepared and subjected to cyclic thermal loads. The paper shows that the eddy current method is suitable for detecting and revealing the crack growth processes even under conditions of complex geometry, as e.g. cracks in inner bores. The experiments indicated particularly susceptible, critical spots in the first wall and yielded crack growth rates of use for lifetime calculations. (orig./CB) [Deutsch] Im Rahmen des europaeischen Fusionsreaktorprogramms werden Untersuchungen zur Lebensdauervorhersage der Ersten-Wand durchgefuehrt. Die Erste-Wand kann ...
1997-12-31
Energy Technology Data Exchange (ETDEWEB)
Corrosion characteristics of Al and Cu thin films have been studied in cyclic fog tests using tap water fog and fog created with 0.1% NaCl solution in tap water. Likewise, their corrosion features have been analyzed in continuous immersion testing in the laboratory in distilled water, tap water, in 0.1% NaCl and 3.5% NaCl solutions in distilled water. The corrosion potentials and the corrosion currents of these thin films change and reach steady state values after some time. However, steady state is not realized in 3.5% NaCl solutions. The corrosion current density data have been used to calculate lifetime of 1 {mu}m thick thin films of Al and Cu in the various tests, and assuming that the fog test data would hold under normal exposure conditions, life spans for these thin film sensor elements in actual exterior exposure have also been calculated. According to estimates, an Al-TF of about 1 {mu}m would last about 9 months in exterior exposure in chloride containing ...
1998-12-31
International Nuclear Information System (INIS)
The results of investigation into a new series of Z-even nuclei - precursors of delayed protons (PDP) -"6"5Ge, "8"9Se, "9"3Kr, "8"1Zr, and "8"5Mo are presented. PDP were obtained by irradiation of targets in the following reactions: Zn(He, 2n) "6"5Ge, 22 MeV; "4"0Ca("3"2S, 2 pn) "1"9Se, 100 MeV; "6"0Ni ("1"60, 3 n), "7"3Kr, 75 MeV; "5"2Cr ("3"2S, 3n)"8"1Zr, 110 MeV; "5"6Fe("3"2S, 3n)"8"5Mo, 120 MeV. The targets (self-sustaining foils of thickness approximately 1.2 mg/cm"2) were placed at an angle of 15 deg to the direction of the ion beam. Upon irradiation targets were moved downwards into a measuring position. The spectra of protons, X and gamma-rays, and also the spectra of p - x, p-#gamma#, x - #gamma# coincidences accompanying the decay of "6"5Ge, "6"9Se,"7"3Kr and "8"1Zr, and "8"5Mo were measured. The measured half-lives are equal, to 31.5+-1.9, 27.3+-0.5, 28.5+-1.1, 6.3+-0.5, and 5.6 +-0.9 s respectively. The experimental spectra are compared with the calculated ones. The proton ...
The population of U.S. Department of Defense military working dogs provides an opportunity to study the lifetime occurrence of neoplasia in 2 breeds of dogs--the German Shepherd Dog and the Belgian Malinois. Medical records were reviewed for all dogs that died or were euthanized in 1992 (135 German Shepherd Dogs and 106 Belgian Malinois). Histologically confirmed neoplasms were recorded. More than 30% of both breeds (41 German Shepherd Dogs and 33 Belgian Malinois) developed at least 1 primary neoplasm during their lives, with 10% developing more than 1 neoplasm. Nearly 57% of the neoplasms were benign, and approximately 43% were malignant. German Shepherd Dogs lived 9.7 years, on average, and Belgian Malinois lived 7.9 years, on average. Of the dogs that developed any neoplasm, Belgian Malinois had a mean age at 1st diagnosis that was 1.1 years younger and a mean age at 1st diagnosis of malignancy that was 1.7 years younger than those in German Shepherd Dogs. The ...
Energy Technology Data Exchange (ETDEWEB)
We report on the single and double multiphoton ionization of ground state Sr atoms observed in an atomic beam experiment with laser pulses of {approx}5 ns duration, maximum intensity {approx}4 x 10{sup 11} W cm{sup -2} and within the 710-740 nm wavelength range. The Sr{sup +} spectrum consists of two strong lines originating from three-photon resonant four-photon ionization of bound states, a number of weak autoionizing resonances and a broad line due to four-photon excitation of the doubly excited 5p{sup 2} {sup 1}S{sub 0} state. The latter, along with a strong, broad and structured spectral feature, is also evident in the wavelength dependence of the doubly charged Sr{sup 2+} ion. A weakly evident but reproducible inflection point ('knee' structure) appears in the intensity dependence of the Sr{sup 2+} yield at the location of the 5p{sup 2} {sup 1}S{sub 0} resonance. A complementary ...
2008-02-28
International Nuclear Information System (INIS)
Pulse radiolysis has been used to optically and kinetically characterize the transient free radicals formed by the reaction of H"s"m"-"b"u"l"l"e"t, N_3"s"m"-"b"u"l"l"e"t, or OH"s"m"-"b"u"l"l"e"t with 2,4,5-trichlorophenol (TCP-OH). The hydroxy-2,4,5-trichlorocyclohexadienyl radical (H-TCP-OH) formed by H"s"m"-"b"u"l"l"e"t addition to TCP-OH [k = (1.1 #+-# 0.2) x 10"9 M"-"1 s"-"1] has an absorption maximum at 360 nm with #epsilon#_3_6_0 = (4700 #+-# 1000) M"-"1 cm"-"1. The 2,4,5-trichlorophenoxyl radical (TCP-O"s"m"-"b"u"l"l"e"t) formed by the reaction of N_3"s"m"-"b"u"l"l"e"t with TCP-O- [k = (4.3 #+-# 0.8) x 10"9 M"-"1 s"-"1] has an absorption maximum at 430 nm with #epsilon#_4_3_0 = (3600 #+-# 600) M"-"1 cm"-"1. The dihydroxy-2,4,5-trichlorocyclohexadienyl radical (HO-TCP-OH) formed by OH"s"m"-"b"u"l"l"e"t radical addition to TCP-OH [k = (1.2 #+-# 0.1) x 10"1"0 M"-"1 ...
Upper bound for a three-photon excitation cross section in atomic argon in the ultraviolet regime
International Nuclear Information System (INIS)
A scheme of evaluating a generalized three-photon excitation cross section #sigma#/sub (3)/ in neutral atomic argon at 3144.67 A is outlined. Three photons at this wavelength can excite the neutral argon atoms from the ground 3p"6 "1S_0 state to the 3p"54s'[1/2]_1"0 state. The fourth photon will ionize the argon atoms. Assuming linear polarization of the incident laser radiation, contributions from several channels in various energy-level schemes are summed in the evaluation of the transition probability. For a laser linewidth of #DELTA##lambda#/sub L/ = 1 A, our maximum numerical value of the computed result for the three-photon excitation cross section is #sigma#/sub (3)/ = 1.414 x 10/sup -80/ cm"6 s"2. .AE.
8800-01-01
Transport properties of single-crystalline n-type semiconducting PbTe nanowires
International Nuclear Information System (INIS)
Single-crystalline PbTe nanowires were synthesized using the chemical vapor transport method. They consisted of rock-salt structure PbTe nanocrystals uniformly grown in the [100] direction. We fabricated field-effect transistors using a single PbTe nanowire, providing evidence for its intrinsic n-type semiconductor characteristics. The values of the carrier mobility and concentration were estimated to be 0.83 cm"2 V"-"1 s"-"1 and 8.8 x 10"1"7 cm"-"3, respectively. The Seebeck coefficients (-72 ?V K"-"1) of individual nanowires were measured to show their n-type carrier-dominated thermoelectric transport properties.
2009-10-14
British Library Electronic Table of Contents (United Kingdom)
The oxidation of n-butylbenzene was studied in a jet-stirred reactor (JSR) at 10atm in dilute conditions providing new experimental results over the low- and high-temperature range 550-1180K, and variable equivalence ratio (0.25ϕ1.5). They consisted of concentration profiles of the reactants, stable intermediates and final products, measured as a function of temperature, at a constant residence time of 1s, by sonic probe sampling followed by on-line GC-MS and off-line GC-TCD-FID and GC-MS analyses. The oxidation of n-butylbenzene in these conditions was modeled using a detailed chemical kinetic reaction mechanism (404 species and 2210 reactions, most of them reversible) deriving from a previous scheme proposed for the ignition, oxidation, and combustion of simple aromatics (benzene,...
2011-01-01
Structural changes in amorphous Pd/sub 80/Si/sub 20/ by neutron irradiation
Amorphous Pd/sub 80/Si/sub 20/ was irradiated with fast neutrons (>1 MeV) to a fluence of 5 x 10/sup 20/ neutrons/cm/sup 2/. X-ray scattering intensities were measured before and after the irradiation with monochromatic Cu-K..cap alpha../sub 1/ rays. Scattered intensities for s>0.4 A/sup -1/ (s=2 sintheta/lambda) proved unaffected, while intensities were found remarkably enhanced for s<0.4 A/sup -1/ after the irradiation, i.e., in the small-angle region and the leading edge of the first halo. The results are discussed in relation to the structural anomalies in amorphous solids.
1977-10-01
Energy Technology Data Exchange (ETDEWEB)
To measure electron reactions on a picosecond timescale the investigators developed a picosecond pulse-conductivity technique, which makes use of the electron fine-structure pulses of our LINAC (pulse width 25 vs FWHM) to produce excess electrons and now detects changes in sample conductance under optimum conditions with an instrumental response of 18 ps. This resolution is in agreement with a theoretical estimate. This technique has been successfully applied to study excess electron reactions in solvents covering a mobility range from 0.24 to 100 cm/sup 2/V/sup -1/s/sup -1/; extension to lower mobility liquids seem possible.
1983-01-01
Mother and infant coordinate heart rhythms through episodes of interaction synchrony
British Library Electronic Table of Contents (United Kingdom)
Animal studies demonstrated the powerful impact of maternal-infant social contact on the infant's physiological systems, yet the online effects of social interactions on the human infant's physiology remain poorly understood. Mothers and their 3-month old infants were observed during face-to-face interactions while cardiac output was collected from mother and child. Micro-analysis of the partners' behavior marked episodes of gaze, affect, and vocal synchrony. Time-series analysis showed that mother and infant coordinate heart rhythms within lags of less than 1s. Bootstrapping analysis indicated that the concordance between maternal and infant biological rhythms increased significantly during episodes of affect and vocal synchrony compared to non-synchronous moments. Humans, like other mamm...
2011-01-01
Length-sorted semiconducting carbon nanotubes for high-mobility thin film transistors
British Library Electronic Table of Contents (United Kingdom)
We have developed a process for chemical purification of carbon nanotubes for solution-processable thin-film transistors (TFTs) having high mobility. Films of the purified carbon nanotubes fabricated by simple drop coating showed carrier mobilities as high as 164 cm2V?1s?1, normalized transconductances of 0.78 Sm?1, and on/off current ratios of 106. Such high performance requires the preparation of a suspension of micrometer-long and highly purified semiconducting single-walled carbon nanotubes (SWCNTs). Our purification process includes length and electronic-type selective trapping of SWCNTs using recycling gel filtration with a mixture of surfactants. The results provide an important milestone toward printed high-speed and large-area electronics with roll-to-roll and ink-jet device fabri...
2011-01-01
Alcohol fermentation in olive oil extraction effluents
Energy Technology Data Exchange (ETDEWEB)
Eight culture-collection yeast strains of various species and five newly isolated stains were tested for both growth in olive oil extraction effluents and fermentation of the sugars in the same media. The culture-collection yeast strains did not grow in an effluent containing 2.86% sugar (w/v), 8 g/litre phenolic substances, 4.58 g/litre titratable acidity and pH 4.96, whereas the newly isolated strains of Torulopsis sp. MK-1, Saccharomyces norbensis MC-1, S. oleaceus MC-2 and S. oleaginosus grew well and fermented the sugars. In the medium mentioned above, they produced alcohol in amounts of 1.63 to 1.38%, respectively. None of the yeasts grew in an olive oil extraction effluent vacuum-concentrated to over 13-14% of dry matter. The strain of T. sp. MK-1 showed a higher stability.
1989-01-01
A more detailed calculation of particle evaporation and fission of compound nuclei
International Nuclear Information System (INIS)
We consider particle evaporation and fission of an ensemble of hot, rotating compound nuclei as a stochastic process. We derive a set of coupled differential equations formed by a Fokker-Planck equation describing fission, and master equations for calculating particle evaporation. From these equations, we are able to determine multiplicities of prefission neutrons, protons and #alpha#-particles, their energy spectra and their angular momentum distributions. A comparison of our results with experimental data provides us with information regarding the reduced friction coefficient #beta#, the fission barrier height and the level density parameter. For different iridium isotopes, ("1"8"1","1"8"5","1"8"7Ir), "1"8"5Os and "1"5"8Er, we obtain as an upper limit #beta##<=#8.0x10"2"1 s"-"1. (orig.).
Investigations on solar grade silicon and process engineering of advanced silicon solar cells
Energy Technology Data Exchange (ETDEWEB)
This thesis deals with the evaluation of Solar Grade Silicon (SoG-Si) purified by different techniques, and also the fabrication and characterization of high efficiency and advanced bifacial solar cells. In the beginning of Chapter 1, various SoG-Si production methods relevant for this work are qualitatively described. The three feedstock materials used in this work are from the Fluidized Bed Reactor (FBR) process, metallurgical feedstock-I and feedstock-II process. In metallurgical feedstock-I, the lifetime of the minority charge carriers in multicrystalline silicon (mc-Si) samples at the grain boundaries are found to be higher than the grains themselves possibly due to lower resistivities in the grain boundaries. The efficiency of the best solar cell obtained using the mc-Si metallurgical feedstock-I is 16.1%. It has been identified that the fast light induced degradation, whose magnitude is lower than that of a reference cell suggests the formation of a B-metal ...
2007-07-01
The performance of 250 different computational protocols (combinations of density functionals, basis sets and methods) was assessed on a set of 165 well-established experimental (1)H-(1)H nuclear coupling constants (J(H-H)) from 65 molecules spanning a wide range of "chemical space". Thereby we found that, if one uses core-augmented basis sets and allows for linear scaling of the raw results, calculations of only the Fermi contact term yield more accurate predictions than calculations where all four terms that contribute to J(H-H) are evaluated. It turns out that B3LYP/6-31G(d,p)u+1s is the best (and, in addition, one of the most economical) of all tested methods, yielding predictions of J(H-H) with a root-mean-square deviation from experiment of less than 0.5 Hz for our test set. Another method that does similarly well, without the need for additional 1s basis functions, is B3LYP/cc-pVTZ, which is, ...
2011-05-16
Observation of eta_c(1S) and eta_c(2S) decays to K+ K- pi+ pi- pi0 in two-photon interactions
We study the processes gamma gamma -> K^0_S K+/- pi-/+ and gamma gamma -> K+ K- pi+ pi- pi0 using a data sample of 519.2 fb-1 recorded by the BaBar detector at the PEP-II asymmetric-energy e+e- collider at center-of-mass energies near the Upsilon(nS) (n = 2,3,4) resonances. We observe the eta_c(1S), chi_c0(1P), chi_c2(1P), and eta_c(2S) resonances produced in two-photon interactions and decaying to K+ K- pi+ pi- pi0, with significances of 18.1, 5.7, 5.2, and 5.3 standard deviations (including systematic errors), respectively. We measure the eta_c(2S) mass and width in K^0_S K+/- pi-/+ decays, m(eta_c(2S))=3638.5 +/- 1.5 +/- 0.8 MeV/c^2 and Gamma(eta_c(2S)) = 13.4 +/- 4.6 +/- 3.2 MeV, where the first uncertainty is statistical and the second is systematic. We search for the Z(3930) resonance and find no significant signal. We also provide the two-photon width times branching fraction values for the observed resonances.
2011-01-01
In vertebrates, the positioning of the internal organs relative to the midline is asymmetric and evolutionarily conserved. A number of molecules have been shown to play critical roles in left-right patterning. Using representational difference analysis to identify genes that are differentially expressed on the left and right sides of the chick embryo, we cloned chick Claudin-1, an integral component of epithelial tight junctions. Here, we demonstrate that retroviral overexpression of Claudin-1, but not Claudin-3, on the right side of the chick embryo between HH stages 4 and 7 randomizes the direction of heart looping. This effect was not observed when Claudin-1 was overexpressed on the left side of the embryo. A small, but reproducible, induction of Nodal expression in the perinodal region on the right side of the embryo was noted in embryos that were injected with Claudin-1 retroviral particles on their right sides. However, no changes in Lefty,Pitx2 or cSnR expression were observed. ...
2006-02-24
A genetic model of melanoma tumorigenesis based on allelic losses
Energy Technology Data Exchange (ETDEWEB)
Previous karyotypic studies have indicated a possible series of non-random chromosomal events involved in the progression of melanoma. We sought to define a model of melanocyte tumorigenesis by studying allelic deletions of polymorphic simple tandem repeat markers mapping to chromosome 1, 6q, 7, 9p, 10, 11, 17, and 21 in thirty matched pairs of melanoma and constitutional DNAs. The most frequent and earliest deletions were found on 9p (57%) and 10q (32%) and with the exception of one case, no sample has loss of markers on another chromosome without concomitant loss of markers on 9p and/or 10q. Losses on 6q were also a frequent (32%) event that sometimes occurred in primary melanomas, whereas losses of loci on distal 1p (26%) or 11q (26%) occurred only in metastic melanomas. A background rate (0-17%) of allele loss was seen on chromosomes 7, 17, and 21. Homozygous deletions in a panel of 31 melanoma cell lines were only detected for markers on 9p (4 cases). These data strongly support ...
1994-09-01
{beta}-decay half-lives of very neutron-rich isotopes of elements from Ti to Ni
Energy Technology Data Exchange (ETDEWEB)
The unknown {beta}-decay half-lives of 22 isotopes far off stability (5 < T{sub Z} < 10) in the region from Ti to Ni were measured at GSI, Darmstadt. The nuclei were produced in a fragmentation reaction of 500 A.MeV {sup 86}Kr-projectile impinging on a thick Be target. The isotopes of interest were separated and identified with the fragment separator, FRS, by a combination of B{rho},Z, and ToF techniques. An additional range separation was performed by a selective implantation into granular detectors. The spatial and time correlations of the implant with the consecutively detected {beta}-particles were used to determine the unknown half-lives. For nuclei far off stability, {beta}-decay chains were measured and analyzed as well, leading to an even more reliable evaluation of the lifetimes. The large discrepancies found between the measured and the theoretical values emphasize that most recent theoretical work is not an improvement over calculations made almost ...
1998-03-01
International Nuclear Information System (INIS)
Ultraviolet (UV) upconversion (UC) luminescence in Yb3+/Er3+-codoped yttrium oxide (Y2O3) nanocrystals can be enhanced by orders of magnitude via tridoping further with Li+ ions under diode laser excitation of 970 nm. Sensitized three-photon UC radiations at 390 and 409 nm, corresponding to the 4G11/2?4I15/2 and 4H9/2?4I15/2 of Er3+ ions, respectively, present an enhancement time of about 33 times, which is larger than the 24 times enhancement for the UC green radiation. The UV UC radiation at 320 nm that corresponds to the 2P3/2?4I15/2 of Er3+ ions has also been greatly enhanced. Theoretical calculations interpret that all the observed enhancement times of UV UC radiations arise from the prolonged lifetimes of their intermediate states.
2009-03-01
Energy Technology Data Exchange (ETDEWEB)
Vanadium alloys exhibit important advantages as a candidate structural material for fusion first wall/blanket applications. These advantages include fabricability, favorable safety and environmental features, high temperature and high wall load capability, and long lifetime under irradiation. Vanadium alloys with (3-5)% chromium and (3-5)% titanium appear to offer the best combination of properties for first wall/blanket applications. A V-4Cr-4Ti alloy is recommended as the reference composition for the ITER application. This report provides a summary of the R&D conducted during 1994 in support of the ITER Engineering Design Activity. Progress is reported for Vanadium Alloy Production, Welding, Physical Properties, Baseline Mechanical Properties, Corrosion/Compatibility, Neutron Irradiation Effects, Helium Transmutation Effects on Irradiated Alloys, and the Status of Irradiation Experiments. Separate abstracts have been prepared for individual reports from this ...
1995-03-01
The review of radioactive waste management in the world
International Nuclear Information System (INIS)
Radioactive waste is generally classified on the basis of how much radiation and the type of radiation it emits as well as the length of time over which it will continue to emit radiation. Many activities dealing with radioactive materials produce nuclear wastes, including civilian nuclear power programs (nuclear Power plant operations and nuclear fuel-cycle activities), defense nuclear programs (nuclear weapons production, naval nuclear reactor programs, and related R and D), and industrial and institutional activities (scientific research, medical operations, and other industrial uses of Radioisotopic sources or Radio chemicals). To minimize the potential adverse health and environment impacts to people and other systems including of animals, plant and etc, during the entire lifetime of the radionuclides involved, nuclear waste must be carefully and properly managed. The scope of nuclear - waste management encompasses generation, processing (treatment and ...
A stellar evolution computer model has been used to determine changes in the luminosity L and effective temperature T(e) of single stars during their time on the main sequence. The range of stellar masses investigated was from 0.5 to 1.5 times that of the Sun, each with a mass fraction of metals (metallicity, Z) from 0.008 to 0.05. The extent of each star's habitable zone (HZ) has been determined from its values of L and T(e). These stars form a reference framework for other main sequence stars. All of the 104 main sequence stars known to have one or more giant planets have been matched to their nearest stellar counterpart in the framework, in terms of mass and metallicity, hence closely approximating their HZ limits. The limits of HZ, for each of these stars, have been compared to its giant planet(s)'s range of strong gravitational influence. This allows a quick assessment as to whether Earth-mass planets could exist in stable orbits within the HZ of such systems, both presently and ...
2003-01-01
The SysMES framework: System management for networked embedded systems and clusters
Energy Technology Data Exchange (ETDEWEB)
The ALICE heavy-ion particle physics experiment is currently being built at CERN near Geneva. It will use a PC cluster of 900 dual-processor machines for the last stages of the data readout process and a network of 400 microcomputers for the configuration and control of the cluster nodes. One of the most important objectives to be achieved in such experiments is to guarantee the utilized devices are running correctly during the experiment life-time. A second aspect is the extremely high availability and reliability requirements of the applications being run, the so called high level trigger (HLT). The SysMES framework is a scalable, decentralized, fault tolerant, dynamic, rule based tool set for the monitoring of networks of target systems and applications. The management algorithms consist of the following steps: system and application monitoring, recognition of undesirable states, event (message) generation, local event handling on the target, event forwarding to ...
2008-07-01
The Diagnostic Method of Inner Parts of Welded Joints at Nuclear Power Plant
International Nuclear Information System (INIS)
There is no possibility to check any inner part at real welded joint at nuclear power station (NPS) during operation because any destructive test cannot be used. In practice there is checked surface of weld. There are used four methodical instructions for the check of real welds: 1. The visual inspection, 2. The measurement of hardness, 3. The chemical composition checking and 4. The microstructure replica analysis. It is necessary to know how these information of weld surface are in accordance with characteristics of inner parts of weld. If there is not any difference between surface weld microstructure and internal weld microstructure of experimental weld it is supposed to that there is not any difference in other measured properties of welds. If is changed structural characteristics of microstructure, it is changed also hardness, chemical analysis etc. It was observed that the microstructure of real welds is almost the same with simulated weld and also the surface microstructure of ...
2010-06-22
Terrestrial Planet Formation in Extra-Solar Planetary Systems
Terrestrial planets form in a series of dynamical steps from the solid component of circumstellar disks. First, km-sized planetesimals form likely via a combination of sticky collisions, turbulent concentration of solids, and gravitational collapse from micron-sized dust grains in the thin disk midplane. Second, planetesimals coalesce to form Moon- to Mars-sized protoplanets, also called "planetary embryos". Finally, full-sized terrestrial planets accrete from protoplanets and planetesimals. This final stage of accretion lasts about 10-100 Myr and is strongly affected by gravitational perturbations from any gas giant planets, which are constrained to form more quickly, during the 1-10 Myr lifetime of the gaseous component of the disk. It is during this final stage that the bulk compositions and volatile (e.g., water) contents of terrestrial planets are set, depending on their feeding zones and the amount of radial mixing that occurs. The main factors that influence ...
2008-01-01
Tantalum capping on platinum thin heater for selective area heating
Energy Technology Data Exchange (ETDEWEB)
The thermal radiation which generated from the patterned Ta/Pt/Ta thin heater achieved a high temperature up to 1010 {sup o}C under applied current of 2.4 A. In order to reduce an electromigration at high current of 2 A, a Ta capping layer was placed on the Pt layer instead of conventional capping layer, such as SiNx and CoWP. Under the thermal radiation at the applied current of 2 A in the Ta/Pt/Ta thin heater, the Ta capping layer enhanced the lifetime of the Pt thin heater up to 5 h. A stamping process for the crystallization of a-Si was performed for 40 samples using the Ta/Pt/Ta thin heater. For all samples, a-Si has been selectively crystallized and Raman peaks were located near 519 cm{sup -} {sup 1}. These results indicated that the thermal radiation of the Ta/Pt/Ta thin heater was maintained constantly due to the Ta capping.
2009-05-29
THE EVOLUTION OF CLOUD CORES AND THE FORMATION OF STARS
International Nuclear Information System (INIS)
For a number of starless cores, self-absorbed molecular line and column density observations have implied the presence of large-amplitude oscillations. We examine the consequences of these oscillations on the evolution of the cores and the interpretation of their observations. We find that the pulsation energy helps support the cores and that the dissipation of this energy can lead toward instability and star formation. In this picture, the core lifetimes are limited by the pulsation-decay timescales, dominated by non-linear mode-mode coupling, and on the order of #approx =# few x 10"5-10"6 yr. Notably, this is similar to what is required to explain the relatively low rate of conversion of cores into stars. For cores with large-amplitude oscillations, dust continuum observations may appear asymmetric or irregular. As a consequence, some of the cores that would be classified as super-critical may be dynamically stable when oscillations are taken into account. Thus, ...
2010-09-20
International Nuclear Information System (INIS)
The interaction of the herbicide paraquat dichloride (P Q, substrate) with p-tert-butylcalix arenas (L, receptor) was investigated in both the solution and solid states. The isolated paraquat calixarene complexes were characterised by UV-visible, 1H NMR, ESI-Ms, Luminescence and IR spectroscopies and elemental analysis. The stoichiometry of complexes 1 and 2 was 1:1 (1 herbicide: 1 calixarene) and both revealed a biexponential luminescence decay with lifetimes depending on the size and the conformational particularity of the calixarenes. Molecular modelling suggested that both calixarenes interact with the herbicide through cation-? interaction. P Q in included in the p-tert butylcalix a rene cavity, a situation favoured by its pinched conformation in polar solvent while it is partially included in the p-tert butylcalix a rene cavity because of its in-out cone conformation. The theoretical results, in particular using Mopac procedures, were in agreement with the ...
Synthesis and photoluminescence properties of Sm3+-doped LaMgB5O10 and GdMgB5O10
International Nuclear Information System (INIS)
Luminescence and reflection spectra as well as luminescence kinetics of the 1 mol% Sm3+-doped crystalline lanthanum magnesium meta borate (LaMgB5O10) and gadolinium magnesium meta borate (GdMgB5O10) were analyzed. Materials were synthesized by conventional solid state route and showed bright orange-red emission under UV excitation. Emission spectra contain sharp and well resolved Sm3+4G5/2#->#6HJ transitions indicating a strong crystal-field effect. In case of gadolinium compound energy transfer between Gd3+ and Sm3+ was detected. The luminescent kinetics of the Sm3+ in analyzed powders is characterized by single exponential decay and experimental values vary in the range 2.2-2.4 ms. - Research highlights: ? Phosphorescence of samarium-doped lanthanide magnesium meta borates. ? Bright and well resolved orange-red emission of Sm3+ under UV excitation. ? Energy transfer from Gd3+ to Sm3+ in gadolinium magnesium meta borate is observed. ? The decay lifetimes is ...
2011-07-01
Structural analysis of experimental carbide fueled driver assmbly flow duct for testing in the FFTF
International Nuclear Information System (INIS)
Mixed carbide fueled driver assembly experiments will be tested in FFTF fuel driver positions as part of the National Advanced Fuel Program. The design of the experiment flow ducts must assure conformance to FFTF functional requirements in addition to service as a test vehicle for the carbide fuel irradiations. Test goals of damage fluence burnup, and fluence to burnup ratio exceed those of the standard oxide fueled drivers. As a consequence, the 20% cold worked type 316 stainless steel material of construction will experience significant irradiation induced creep and swelling. Additionally, the flow duct design must withstand the enhanced thermal transients produced by the action of carbide fuel during reactor scrams. A major FFTF functional requirement is that adjacent flow ducts do not touch each other except at the load pads. This requires a realistic analysis of the creep and swelling deformation of the flow duct during an experiment lifetime. Flow duct ...
Status Report of Simulated Space Radiation Environment Facility
Energy Technology Data Exchange (ETDEWEB)
The technology for performance testing and improvement of materials which are durable at space environment is a military related technology and veiled and securely regulated in advanced countries such as US and Russia. This core technology cannot be easily transferred to other country too. Therefore, this technology is the most fundamental and necessary research area for the successful establishment of space environment system. Since the task for evaluating the effects of space materials and components by space radiation plays important role in satellite lifetime extension and running failure percentage decrease, it is necessary to establish simulated space radiation facility and systematic testing procedure. This report has dealt with the status of the technology to enable the simulation of space environment effects, including the effect of space radiation on space materials. This information such as the fundamental knowledge of space environment and research ...
2007-11-15
Rhodopsin photochemistry is vibrationally coherent
Energy Technology Data Exchange (ETDEWEB)
Visual excitation is initiated by the absorption of a photon by the 11-cis retinal chromophore bound within the pigment called rhodopsin. We have used a variety of vibrational spectroscopies to obtain information about the vibrational nuclear dynamics that lead to this efficient photochemical isomerization. The cis-trans isomerization in rhodopsin is complete in only 200 fs. The extreme speed of this process, which is consistent with the {approximately}50 fs lifetime indicated by the spontaneous emission yield, suggests that the photochemistry involves non-stationary states or vibrational coherence. Recent studies have in fact observed vibrationally coherent oscillations of the ground state photoproduct called bathorhodopsin following impulsive excitation of the rhodopsin reactant. This conclusively demonstrates that the isomerization process in rhodopsin is vibrationally coherent. These observations further suggest that the isomerization quantum yield is directly ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
A trans-uranium (TRU) fuel should be manufactured and loaded in transmutation systems in order to transmute the long-lived TRU nuclides into short-lived ones. However, since all of the TRU nuclides are not completely transmuted in one cycle lifetime in transmutation systems, the spent TRU fuel has to be treated to recover the long-lived radionuclides or fuel matrix materials. One concept to manufacture TRU fuel for transmutation is to recover uranium from TRU and molten salt. If this type of fuel is adopted for transmutation, uranium could also be an objective material to be recovered and recycled. Since electrowinning is a promising technology to be employed for the recovery of uranium from fuel materials, some experimental work of electrowinning using anode of Cd-Li alloy was carried out in this study. The basic salt chosen was a mixture of LiCl-KCl which has an eutectic point at 357 .deg. C.
2005-07-01
International Nuclear Information System (INIS)
A trans-uranium (TRU) fuel should be manufactured and loaded in transmutation systems in order to transmute the long-lived TRU nuclides into short-lived ones. However, since all of the TRU nuclides are not completely transmuted in one cycle lifetime in transmutation systems, the spent TRU fuel has to be treated to recover the long-lived radionuclides or fuel matrix materials. One concept to manufacture TRU fuel for transmutation is to recover uranium from TRU and molten salt. If this type of fuel is adopted for transmutation, uranium could also be an objective material to be recovered and recycled. Since electrowinning is a promising technology to be employed for the recovery of uranium from fuel materials, some experimental work of electrowinning using anode of Cd-Li alloy was carried out in this study. The basic salt chosen was a mixture of LiCl-KCl which has an eutectic point at 357 .deg. C
2005-05-26
Recent Progress in CdTe and CdZnTe Detectors
Cadmium telluride (CdTe) and cadmium zinc telluride (CdZnTe) have been regarded as promising semiconductor materials for hard X-ray and Gamma-ray detection. The high atomic number of the materials (Z_{Cd} =48, Z_{Te} =52) gives a high quantum efficiency in comparison with Si. The large band-gap energy (Eg ~ 1.5 eV) allows us to operate the detector at room temperature. However, a considerable amount of charge loss in these detectors produces a reduced energy resolution. This problem arises due to the low mobility and short lifetime of holes. Recently, significant improvements have been achieved to improve the spectral properties based on the advances in the production of crystals and in the design of electrodes. In this overview talk, we summarize (1) advantages and disadvantages of CdTe and CdZnTe semiconductor detectors and (2) technique for improving energy resolution and photopeak efficiencies. Applications of these imaging detectors in future hard X-ray and ...
2001-01-01
Quantitative assessment of cancer risk from exposure to diesel engine emissions
Energy Technology Data Exchange (ETDEWEB)
Quantitative estimates of lung cancer risk from exposure to diesel engine emissions were developed using data from three chronic bioassays with Fischer 344 rats. Human target organ dose was estimated with the aid of a comprehensive dosimetry model. This model accounted for rat-human differences in deposition efficiency, normal particle clearance rates, transport of particles to lung-associated lymph nodes, respiration rates, and lung surface area, as well as high-dose inhibition of particle clearance. Recent evidence indicates that the inert carbon core of the diesel particulate matter is likely to be the primary source of carcinogenicity. The epithelial tissue lining the alveoli and lower airways is the primary target site for induction of lung tumors. Dose was therefore based upon the concentration of carbon particulate matter per unit lung surface area. Unit risk estimates were developed using either a time-to-tumor or a linearized multistage model. The unit risk estimates, defined ...
1993-02-01
International Nuclear Information System (INIS)
Technical developments in the construction of high power accelerators have created new research activities on accelerator-driven transmutation technologies (ADTT) with main applications for energy production and nuclear waste transmutation. The on-going research was reported and discussed at the conference. The studies of energy production based on ADTT indicate possible important advantages compared to the present nuclear power reactors. Natural Uranium or Thorium is burned in a subcritical reactor with or without simultaneous incineration and transmutation of nuclear waste. High level radioactive wastes and weapons Plutonium constitute an environmental and proliferation problem. Studies were reported on the possibilities to use ADTT to considerably shorten the life-time and reduce the amount of long-lived radioactive waste in order to decrease the volumes needed for long-term geologic deposition. A panel discussed the ADTT impact on nuclear waste disposal, ...
1996-06-03
Probabilistic fracture assessment of TAPP 3-4 PHT piping
International Nuclear Information System (INIS)
Methodology based on probabilistic fracture mechanics (PFM) is finding increasing acceptability in demonstrating safety of Nuclear Power Plant (NPP) piping. In PFM, the methods of fracture mechanics and reliability theory are combined for assessing the reliability of components, which contain cracks. In this work, reliability assessment of Tarapur Atomic Power Plant (TAPP) 3-4 Primary Heat Transport (PHT) piping is done using PFM. Monte Carlo simulation with stratified sampling is used as a variance reduction technique. PFM model assumes a pre-existing circumferential surface crack before the start of plant operation. The crack grows in size during the lifetime of the plant due to the fatigue loading. This part-through wall crack having escaped hydro-test and pre-service inspection, may result in either a through wall flaw (leak) or may lead to the rupture of the piping. R6 method is used as failure criteria. Steam generator inlet (SGI), steam generator outlet ...
2005-12-01
Prevention of lung cancer by remediation of residential exposure to radon daughters
Energy Technology Data Exchange (ETDEWEB)
The United States Bonneville Power Administration (BPA), as part of an energy conservation programme in the states of Washington, Oregon, Idaho, Wyoming, and Montana, has collected over 36,000 residential radon concentration measurements. Data were collected between 1983 and 1989 with ambient {alpha} etched track dosemeters. Based on the linear risk coefficient from the BEIR IV report for lifetime lung cancer in smokers and non-smokers, numbers of lung cancer cases attributable to radon exposure were predicted. Numbers of baseline lung cancer cases and numbers of these that were preventable by remediation were also estimated. Remediation to 10 pCi.1{sup -1}, to 4 pCi.1{sup -1}, and to outdoor levels were considered. With vital statistics data, results were extrapolated to populations in the states represented by the BPA data. Costs of remediation were estimated. Results were evaluated in terms of cost per cancer saved and per cent reduction in fatal lung cancer ...
1991-01-01
Energy Technology Data Exchange (ETDEWEB)
Heat exchangers for high and ultrahigh temperatures are a need and a precondition to realise high efficient fossil fired power plants based on the so-called Externally Fired Combined Cycle (EFCC) or the Indirect Fired Gas Turbines (IFGT). The main target of both processes is to increase the thermal efficiency of existing power plants by approximately 25% resulting in the same decrease in fuel consumption and, therefore, in the same reduction of CO{sub 2} formation. The main activities of the MPA University of Stuttgart in this project is focused on the characterisation and qualification of the structural material of the ultrahigh temperature heat exchanger (UHTHE) necessary in the above mentioned processes. The influence of the temperature and load on the material behaviour have been analysed by means of tensile tests and creep tests. The effectiveness of different coating systems and the interaction between coating system and basic material was also investigated. Additionally a set of ...
2004-07-01
Practical statistics for particle physicists
Learning to love the errror matrix lecture : Learning to love the errror matrix Introductory remarks. Conditional probability. Statistical and systematic errors. Combining results Binomial, Poisson and 1-D Gaussian 2-D Gaussian and the error matrix. Understanding the covariance. Using the error matrix. Estimating the error matrix. Combining correlated measurements Parameter determination by likelihood Do's and don'ts lecture : Parameter determination by likelihood : Do's and don'ts Introduction to likelihood. Error estimate. Simple examples: (1) Breit Wigner (2) Lifetime Binned and unbinned likelihood Several parameters Extended maximum likelihood. Common misapprehensions: Normalisation delta(lnL) = 1/2 rule and coverage Integrating the likelihood Unbinned L_max as goodness of fit Punzi effect Chi-squared and hypothesis testing lecture : Chi-squared and hypothesis testing Basic idea. Error estimates. Several parameters Correlated errors on y. Errors on x and y. ...
2006-01-01
International Nuclear Information System (INIS)
The proceedings include the following lectures: Facing the challenges - new structures for electricity production. Renewable energies in Europe - chances and challenges. Nuclear outlook in the UK. Sustainable energy for Europe. Requirements of the market and the grid operator at the electricity production companies. Perspectives for the future energy production. Pumped storage plants - status and perspectives. Nuclear power/renewable energies -partners or opponents? New fossil fired power stations in Europe - status and perspectives. Nuclear energy: outlook for new build and lifetime extension in Europe. Biomass in the future European energy market - experiences for dong energy. Meeting the EU 20:20 renewable energy targets: the offshore challenges. DESERTEC: sustainable electricity for Europe, Middle East and North Africa. New power plants in Europe - a challenge for project and quality management. Consideration of safely in new build activities of power plants. ...
2010-09-22
Photoluminescence of europium doped LiInO2 powder
British Library Electronic Table of Contents (United Kingdom)
Abstract Lithium-indium oxide is one of the candidate materials as solid-state scintillators for solar neutrinos due to an inverse --decay of 115In to 115Sn. On the other hand, when doped with rare-earth ions such as Eu3+ or Sm3+, it becomes a promising phosphor material. In this report we present a simple solid-state procedure for preparation of LiInO2:Eu3+ powders. X-ray diffraction confirmed prod-uct in tetragonal structural form (space group: I41/amd) and no impurity phases were detected. Then, high resolution photoluminescence emission measurements were performed at room and low temperatures to find 5D0 - 7FJ. Emission kinetics from 5D0 level exhibited pure single exponential behavior with lifetime of about 1.5 ms. Maximum energy splitting of 7F1 manifold is recorded as a function of ...
2011-01-01
Photochemical energy conversion by membrane-bound photoredox systems. Final report
Energy Technology Data Exchange (ETDEWEB)
This project has received DOE support since July 1, 1978. During this period, 40 papers have been published dealing predominantly with chlorophyll-photosensitized electron transfer reactions in a variety of media (solutions, polymer films, lipid bilayer membranes). The overall theme of this work has been to develop mechanistic strategies f or photochemical energy storage via chlorophyll, using the green plant photosynthetic system as a paradigm for designing in vitro systems. Microheterogeneous lipid vesicle suspensions allow ready application of time-resolved optical spectroscopy to follow the course of light-induced electron transfer processes. Both the yields and the lifetimes of electron transfer products were markedly improved in the vesicle systems. In subsequent studies, this compartmentalization was favorably manipulated by controlling the electrical charge on the membrane surface, by controlling the solubility properties of the acceptors, by varying the ...
1994-06-16
Energy Technology Data Exchange (ETDEWEB)
Transient experiments in a Temporal Analysis of Products (TAP) Reactor were performed to elucidate the role of surface oyxgen species in the oxidation of benzene to phenol on ZSM-5 type zeolites with nitrous oxide as a selective oxidant. It was shown by puls experiments with nitrous oxide that the mean lifetime of the generated surface oxygen species is between 0.2s at 500 C and about 4.2 s at 400 C. Afterwards the surface oxygen species desorb as molecular oxygen into the gas phase where total oxidation will take place if hydrocarbons are present. Dual puls experiments consisting of a nitrous oxide puls followed by a benzene puls allowed studying the reactivity of the surface oxygen species formed during the first puls. The observation of the phenol formation was impeded due to the strong sorption of phenol. Multipulse experiments were necessary to reach a pseudo steady state phenol yield. (orig.)
1998-12-31
Multipass laser mass spectrometer with extreme jet-cooled pulsed gas
International Nuclear Information System (INIS)
We have developed a photon accumulated laser mass spectrometer that enables us to identify isomers of polychlorinated dibenzo-p-dioxin and polychlorinated dibenzofuran. This system is comprised of a high temperature (230 deg. C) pulsed gas injector (PGI), multimirror multipath system (MMS), and the conventional time-of-flight mass spectrometer. The PGI induces the formation of a choked supersonic jet gas pulse that cools down to a temperature to restrain fragmentation and reduces vibrational and rotational thermal noises. The results suggest that the excited lifetime numbers and fragment dynamics of these species change completely with jet cooling of molecules. The MMS enhances the soft ionization efficiency (by a factor of 1000 over a single path system) through photon accumulation by extending the irradiation duration (to about 40 ns) and volume, and it further minimizes fragmentation by carefully controlling the laser intensity distribution within the ionization ...
2006-09-01
Micromechanical characterization tools for highly-filled polymers
Energy Technology Data Exchange (ETDEWEB)
We are attempting to characterize and model the micromechanical response of highly-filled polymers. In this class of materials, the continuous plastic binder used to bond the highly-filled material dominates the observed viscoelastic response. As a result, realistic lifetime analysis of these materials will require a thorough understanding of the contribution of the plastic binder. Laboratory applications of these materials include plastic bonded explosives, propellants, a variety of specialized filled organic materials for stockpile systems, and highly filled epoxy dielectric materials for the National Ignition Facility. We have explored numerous techniques to characterize the local microstructure of plastic bonded explosives. However, insufficient funding was obtained to bring these technologies to maturity, nevertheless our present tool set is significantly better than 2 years ago. We have also made some progress in developing an appropriate micromechanical ...
2000-02-16
International Nuclear Information System (INIS)
A merged-beams electron-energy-loss technique is described, by which absolute cross sections can be measured for near-threshold electron-impact excitation of multipy charged ions. Results are reported here for absolute total electron-impact excitation cross sections for the O"5"+(2s#->#2p) transition from below threshold to 1.6 eV above threshold. The experimental data are in good agremeent with a seven-state close-coupling calculation throughout the energy range of the experiment. Results agree with calculations showing that more than 90% of the electrons causing excitation are ejected in the backward direction in the center-of-mass frame. This backscattering is shown in both quantum-mechanical and semiclassical calculations. Evidence is observed for high-lying metastable autoionizing states with a lifetime of approximately 0.9 #mu#s which are made to ionize by electron impact.
Luminescence of CaGa2Se4:Eu crystals
International Nuclear Information System (INIS)
We have studied photoluminescence and thermoluminescence (PL and TL) in CaGa2Se4:Eu crystals in the temperature range 77-400 K. We have established that broadband photoluminescence with maximum at 571 nm is due to intracenter transitions 4f6 5d-4f7 (8S7/2) of the Eu2+ ions. From the temperature dependence of the intensity (log I-103/T), we determined the activation energy (Ea = 0.04 eV) for thermal quenching of photoluminescence. From the thermoluminescence spectra, we determined the trap depths: 0.31, 0.44, 0.53, 0.59 eV. The lifetime of the excited state 4f6 5d of the Eu2+ ions in the CaGa2Se4 crystal found from the luminescence decay kinetics is 3.8 ?sec. (authors)
Long-term corrosion study at nuclear power plant Bohunice (Slovakia)
International Nuclear Information System (INIS)
Steam generators of four VVER-440 units at nuclear power plants V-1 and V-2 in Jaslovske Bohunice (Slovakia) were gradually changed by new original 'Bohunice' design in period 1994-1998. Corrosion processes before and after these design and material changes in Bohunice secondary circuit were studied using Moessbauer spectroscopy during last 25 years. Innovations in the feed water pipeline design as well as material composition improvements were evaluated positively. Moessbauer spectroscopy studies of phase composition of corrosion products were performed on real specimens scrapped from water pipelines or in form of filter deposits. The corrosion of new feed water pipelines system (from austenitic steel) in combination to innovated operation regimes goes dominantly to magnetite. The hematite presence is mostly on the internal surface of steam generator body and its concentration increases towards the top of the body. In the results interpretation it is necessary to consider also erosion ...
2010-03-01
Long-life bismuth liquid metal ion source for focussed ion beam micromachining application
International Nuclear Information System (INIS)
Liquid metal ion sources (LMISs) with Ga as ion species are widely used in focused ion beam (FIB) technology for micromachining and surface treatment on the sub-micron and nano-scale. Key features of a LMIS for investigating mechanical properties and 3D-microfabrication of materials are long life-time, high brightness, stable ion current and a highly effective milling ability for the material to be modified. In order to increase the material removal rate, heavier ions than Ga and their clusters should be applied. Bismuth (Bi) is the heaviest, non-radio-active element in the periodic table, is non-toxic and exhibits a low melting point. We have thus produced a long-life (about 1000 h) Bi LMIS with a good beam performance, applicable in any FIB system. Since Bi is the only element in this source, it is not necessary to separate it from other ions by a mass filter. Investigation of the sputtering rate of NiTi shape memory alloys using Ga and Bi LMIS showed that, for ...
2008-09-15
Energy Technology Data Exchange (ETDEWEB)
This work concerns the study of the nuclear superdeformation phenomenon in the rare earth region (A {approx} 150). The superdeformed (SD) states in Gadolinium and Dysprosium isotopes were produced via heavy-ion induced reactions and studied with the (EUROGAM EUROpean GAmma-ray Microscope) gamma multidetector array. Precise level attenuation method (DSAM). From the derived quadrupole moments, we find large differences in deformation between the yrast bands in neighbour nuclei explained in terms of the case of nuclei corresponding to an axis ratio of 2:1, the shell gaps are not fixed at a specific particle number and deformation. Furthermore the present results indicate that the deformations associated with identical bands are different supporting the picture that mass and deformation changes tend to compensate in SB bands with the same moments of inertia. (author). 114 refs.
1996-05-13
Lifetime and {ital g}-factor measurements of the 11{sup {minus}} isomer in {sup 92}Tc
Energy Technology Data Exchange (ETDEWEB)
The half-life ({ital T}{sub 1/2}) and {ital g} factor of the 2002 keV 11{sup {minus}} isomer in the odd-odd nucleus {sup 92}Tc produced by the pulsed heavy-ion reaction {sup 68}Zn({sup 28}Si,{ital p}3{ital n}){sup 92}Tc have been measured using time differential perturbed angular distribution method. The measured {ital T}{sub 1/2} value is 3.15(20) ns. From the observed spin precession frequency {omega}{sub {ital L}} of a {sup 92}Tc recoil implanted into a ferromagnetic Ni host, we obtain the {ital g} factor to be 0.806(20). The measured value of the {ital g} factor is in good agreement with a shell model analysis carried out using {pi}({ital p}{sub 1/2}{ital g}{sub 9/2}) and {nu}({ital p}{sub 1/2}{ital g}{sub 9/2}) orbitals for the proton particles and neutron holes outside the {sup 88}Sr core. {copyright} {ital 1996 The American Physical Society.}
1996-12-01
Life history consequences of growth variation
Environmental Research Database
ObjectivesThe main objective of this study is to address the following specific questions: 1. Are the delayed effects of poor early diet on whole organism performance and senescence contingent on, or exacerbated by, the subsequent occurrence of compensatory growth? 2. Does the rate of growth influence levels of resting metabolism and/or oxidative stress, and if so, for how long does this persist? 3. How are the levels of early nutrition, growth, resting metabolism and oxidative stress linked to the lev [continued...]DescriptionIt is now widely appreciated that, while animals may appear to recover from periods of poor food quality or quantity experienced in early development, adverse effects may occur later in adult life. Such effects can influence the performance of complete cohorts of animals, and have important consequences for population dynamics. The reasons why such delayed effects occur across the animals' lifetimes are poorly understood. Following a period ...
2009-01-30
Irradiation-effects considerations for the SP-100 space reactor
International Nuclear Information System (INIS)
The Sp-100 reactor is a lithium-cooled high-temperature fast-spectrum reactor. The fuel is UN. The cladding is fabricated from PWC-11, a Nb alloy, as are all the primary structural components. A reactor lifetime of up to ten years with an operating temperature of 1370 K is required. The accumulated fluence is expected to be 6 x10"2"2 n/cm"2. The damage, which could result in swelling or embrittlement, anneals out as fast as it occurs for the majority of the structure. This has been confirmed by earlier radiation testing. A number of components, however, are exposed to lower temperatures and the reactor design and materials selection for these components must take this into consideration. Radiation effects must also be considered for the UN fuel, bearing materials, etc. To data an instrumented experiment, MOTO 1000A, has been conducted in the FFTF reactor and as uninstrumented experiment SPM-1 in the EBR-II reactor. In this paper the post-irradiation examination and ...
1992-03-01
Investigations of biomimetic light energy harvesting pigments
Energy Technology Data Exchange (ETDEWEB)
This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). Nature uses chlorophyll and other porphyrinic pigments to capture and transfer light energy as a preliminary step in photosynthesis. The design of synthetic assemblies of light harvesting and energy directing pigments has been explored through synthesis and characterization of porphyrin oligomers. In this project, pigment electronic and vibrational structures have been explored by electrochemistry and dynamic and static optical measurements. Transient absorption data reveal energy transfer between pigments with lifetimes on the order of 20--200 picoseconds, while Raman data reveal that the basic porphyrin core structure is unperturbed relative to the individual monomer units. These two findings, along with an extensive series of experiments on the oxidized oligomers, reveal that coupling between the pigments is ...
1998-12-01
Energy Technology Data Exchange (ETDEWEB)
The study presented in this thesis is a contribution toward improving the reliability of Metallized Polypropylene Film (MPPF) capacitors achieved by a better design. A temperature distribution in the roll is assumed with the aim of optimizing its thermal performance. It appears that the heating of long capacitor is higher than that of equivalent flat capacitor subjected to the same electric stresses. Standard accelerated aging tests (temperature and voltage) of MPPF capacitors have been performed with the aim to evaluate the dielectric performance and thus the capacitor lifetime. The statistical approach showed that the failure mode may be represented by two parameter Weibull distribution and the experimental approach proved that long capacitor deteriorates faster than a plate-shaped having the same features. Although capacitors with long geometry seem to have a poor pulse handling performance, we found that the quality of the, end-edge contact is strongly ...
2001-12-01
How cells tiptoe on adhesive surfaces before sticking
Cell membranes are studded with protrusions that were thoroughly analyzed with electron microscopy. However, the nanometer-scale three-dimensional motions generated by cell membranes to fit the topography of foreign surfaces and initiate adhesion remain poorly understood. Here, we describe the dynamics of surface deformations displayed by monocytic cells bumping against fibronectin-coated surfaces. We observed membrane undulations with typically 5 nm amplitude and 5-10 second lifetime. Cell membranes behaved as independent units of micrometer size. Cells detected the presence of foreign surfaces at 50 nm separation, resulting in time-dependent amplification of membrane undulations. Molecular contact then ensued with apparent cell-membrane separation of 30-40 nm, and this distance steadily decreased during the following tens of seconds. Contact maturation was associated with in-plane egress of bulky molecules and robust membrane fluctuations. Thus, membrane ...
2008-01-01
Enhancement of surface properties of 45{number_sign} steel using plasma immersion ion implantation
Energy Technology Data Exchange (ETDEWEB)
45{number_sign} steel, which has good mechanical strength and is relatively cheap, is a common constituent in industrial components, such as precision gears, piston columns of oil pumps, and so on. However, since the working environment of these industrial parts is sometimes quite harsh and unforgiving, they are vulnerable to wear and corrosion. Replacing 45{number_sign} steel with stainless or alloy steel increases the cost significant, and a better alternative is to improve its surface properties and lifetime using plasma immersion ion implantation (PIII). The authors have devised a variety of treatment processes using PIII, including radio-frequency (RF) plasma nitriding, RF plasma nitriding and nitrogen PIII, Ti deposition in conjunction with nitrogen PIII (IBED), as well as Cr deposition followed by nitrogen PIII (IBED). To assess the efficacy of the processes, the microhardness and mass loss due to wear were measured for both the untreated and treated ...
1997-12-31
Efficient modeling for pulsed activation in inertial fusion energy reactors
International Nuclear Information System (INIS)
First structural wall material (FSW) materials in inertial fusion energy (IFE) power reactors will be irradiated under typical repetition rates of 1-10 Hz, for an operation time as long as the total reactor lifetime. The main objective of the present work is to determine whether a continuous-pulsed (CP) approach can be an efficient method in modeling the pulsed activation process for operating conditions of FSW materials. The accuracy and practicability of this method was investigated both analytically and (for reaction/decay chains of two and three nuclides) by computational simulation. It was found that CP modeling is an accurate and practical method for calculating the neutron-activation of FSW materials. Its use is recommended instead of the equivalent steady-state method or the exact pulsed modeling. Moreover, the applicability of this method to components of an IFE power plant subject to repetition rates lower than those of the FSW is still being studied. The ...
2000-11-01
Effect of crevice environment PH on corrosion damage of horizontal steam generator tubes
Energy Technology Data Exchange (ETDEWEB)
In support of a project on lifetime calculation experiments were carried out to evaluate the resistance to environmentally assisted cracking (EAC) of steam generator tubes during operation. Estimations of the incubation period for crack initiation and the threshold K value, K{sup Iscc}, and the crack growth rate were made to predict evolution of damage in tube walls. The paper summarizes results of experiments of C ring specimen for the initiation testing and results of SENT (single edge notch tensile) specimen for the crack growth rate (CGR) testing. The specimens were exposed to concentrated environments at elevated temperatures simulating crevice environments in secondary side crevices in horizontal steam generators. The results show that the material of SG tubes is sensitive to transgranular environmentally assisted cracking in the three basic concentrated environments used, alkaline, neutral and acid. The most corrosive medium was the acid environment. The ...
2002-07-01
Effect of crevice environment PH on corrosion damage of horizontal steam generator tubes
International Nuclear Information System (INIS)
In support of a project on lifetime calculation experiments were carried out to evaluate the resistance to environmentally assisted cracking (EAC) of steam generator tubes during operation. Estimations of the incubation period for crack initiation and the threshold K value, K"I"s"c"c, and the crack growth rate were made to predict evolution of damage in tube walls. The paper summarizes results of experiments of C ring specimen for the initiation testing and results of SENT (single edge notch tensile) specimen for the crack growth rate (CGR) testing. The specimens were exposed to concentrated environments at elevated temperatures simulating crevice environments in secondary side crevices in horizontal steam generators. The results show that the material of SG tubes is sensitive to transgranular environmentally assisted cracking in the three basic concentrated environments used, alkaline, neutral and acid. The most corrosive medium was the acid environment. The crack ...
2002-05-05
International Nuclear Information System (INIS)
We have investigated the correlation between V-shaped defect formation and the optical properties of AlGaN/(In)GaN multiple quantum wells (MQWs) grown under different growth conditions and then demonstrated the characteristics of fabricated ultraviolet (UV) light emitting diodes (LEDs). From the temperature-dependent photoluminescence (PL) measurement, the internal quantum efficiency for 300 K was obtained as 43.6% for a sample with a low density of V-defects in a MQW and 13.7% for a sample with a high density of V-defects. The carrier lifetime based on the time resolved PL measurement at room temperature was 0.32 ns for a sample with a high density of V-defects and 1.26 ns for a sample with a low density of V-defects. And we also found that the density of V-defects affected the external quantum efficiency and wall plug efficiency of the fabricated UV LEDs. (fast track communication)
2008-07-07
Economic analysis of fuel recycle
International Nuclear Information System (INIS)
Economic analysis was performed at KAERI with the assistance of US DOE to compare single reactor fuel cycle costs for a once-through option and a thermal recycle option to operate 1 GWe of a PWR plant for its lifetime. A reference fuel cycle cost was first calculated for each option with best estimated reference input data. Then a sensitivity analysis was performed changing each single value of such fuel cycle component costs as yellow cake price, enrichment charges, spent fuel storage cost, reprocessing cost, spent fuel disposal cost and reprocessing waste disposal cost. Savings due to thermal recycle in requirements of uranium, conversion, and enrichment were examined using formulas suggested by US DOE, while MOX fabrication penalty was accounted for. As a result of the reference fuel cycle cost analysis, it is calculated that the thermal recycle option is marginally more economical than the once-through option. The major factors affecting the comparative costs ...
1985-05-19
Energy Technology Data Exchange (ETDEWEB)
The major objective of this work is to seek for new solutions that can lead to significant lifetime improvement of submerse lines which experience severe wear processes on the polymeric layer coating used for protection of the touch down point (TDP) region. Four different materials were selected as possible candidates for the coating layer of this critical region. They are commercially available and posses well known processing technologies. The materials are two polymers: nylon 66 and polyacetal; and two composites: nylon 66 reinforced with 13 or 33% glass fiber. Stress-strain behavior was evaluated using two deformation rates in order to characterize the viscoelastic behavior proper of polymeric materials. It was observed that increasing the amount of glass fiber in the matrix leads to a stronger material and a consequent decrease of elongation to break. Additionally, abrasion tests were carried out using a Taber equipment in three distinct conditions. Results ...
2003-07-01
Development of high-efficiency GaAs solar cells on polycrystalline Ge substrates
Energy Technology Data Exchange (ETDEWEB)
Progress in the development of high-efficiency GaAs solar cells on low-cost, large-area, large-grain, optical-grade polycrystalline Ge substrates is described in this paper. First, we present results on the growth of specular GaAs-AlGaAs layers, across the various crystalline orientations of a polycrystalline Ge substrate, by metallorganic chemical vapor deposition (MOCVD). Second, we present the preliminary optimization of minority-carrier properties of GaAs-AlGaAs structures on poly-Ge substrates towards the improvement of GaAs solar cells. We have demonstrated comparable minority-carrier lifetimes in GaAs double-hetero structures grown on optical-grade poly-Ge substrates and electronic-grade single-crystal Ge substrates. In addition, we describe device-structure optimization that have led us to achieve a open-circuit voltage of {approximately}1 Volt in a GaAs solar cell on poly-Ge and to improve our previous best efficiency from 15.8{percent} for a 1-cm{sup ...
1996-01-01
Degradation mechanisms of nylon separator materials for a nickel-cadmium cell in KOH electrolytes
Energy Technology Data Exchange (ETDEWEB)
Degradation reactions of a nylon 6 battery separator material have been studied in 4-34% aqueous KOH electrolytes at 35/sup 0/-110/sup 0/C. In a Ni/Cd cell, this degradation involves a slow hydrolysis reaction followed by fast electrochemical oxidations of the hydrolysis reaction products. Arrhenius activation energy of the hydrolysis reaction in 34% KOH was 20.0 +- 0.3 kcal/mole. A plot of the hydrolysis rate at 100/sup 0/C vs. hydroxyl ion concentration gave a rate maximum at about 16% KOH, and the mechanism for this effect is discussed. Electrochemical oxidations of the hydrolysis product, 6-aminocaproate ion, appear to proceed rapidly in several sequential steps at a nickel oxide electrode. In a Ni/Cd cell, the combination of nylon separator hydrolysis followed by electrochemical oxidation of the products can seriously degrade the battery lifetime. The rate of the hydrolysis of nylon 66 separator material was approximately one half of that of the nylon 6 ...
1989-03-01
Energy Technology Data Exchange (ETDEWEB)
The microelectronic cable diagnosis is a substantial tool to determine destruction free the residual strength and the lifetime of laid PE/XLPE medium voltage cables. Fundamentals of the ageing diagnosis and a cost reduced inspection concept are the `Isothermal-Relaxation-Current` Analysis and the Neuro-Fuzzy evaluation software. These new tools are able to determine the ageing status of the investigated cable without any references. The authors also show that the test breakdown during the assessment of the ageing status of criterial systems can be reduced by this approach. The cable diagnosis equipment KDA is also useful for the steering of investment as well as for preventive maintenance. (orig.) [Deutsch] Die zerstoerungsfreie dielektrische Kabeldiagnostik kann heute einen wesentlichen Beitrag zur Bestimmung der Restfestigkeit und der Restlebensdauer eines PE/VPE-isolierten Mittelspannungskabels leisten. Basis der Alterungsdiagnose und des Konzeptes zur ...
1997-12-15
The primary concern of this work is to study the emission characteristics of a series of chiral nematic liquid crystal lasers doped with different laser dyes (DCM, pyrromethene 580, and pyrromethene 597) at varying concentrations by weight (0.5-2 wt %) when optically pumped at 532 nm. Long-wavelength photonic band-edge laser emission is characterized in terms of threshold energy and slope efficiency. At every dye concentration investigated, the pyrromethene 597-doped lasers exhibit the highest slope efficiency (ranging from 15% to 32%) and the DCM-doped lasers the lowest (ranging from 5% to 13%). Similarly, the threshold was found to be, in general, higher for the DCM-doped laser samples in comparison to the pyrromethene-doped laser samples. These results are then compared with the spectral properties, quantum efficiencies and, where possible, fluorescence lifetimes of the dyes dispersed in a common nematic host. In accordance with the low thresholds and high slope ...
2010-02-01
CleverFarm - A SuperSCADA system for wind farms
Energy Technology Data Exchange (ETDEWEB)
The CleverFarm project started out to build an integrated monitoring system for wind farms, where all information would be available and could be used across the wind farm for maintenance and component health assessments. This would enable wind farm operators to prioritise their efforts, since they have a good view of the farm status from home. A large emphasis was placed on the integration of condition monitoring approaches in the central system, enabling estimates of the remaining lifetime of components, especially in the nacelle. During the 3,5 years of the project, software and hardware was developed and installed in two wind farms in Denmark and Germany. The connected hardware included two different condition monitoring systems based on vibration sensors from Gram&Juhl and ISET, plus a camera system developed by Overspeed. Additionally, short-term predictions of the wind farm output were delivered by DMI and Risoes Prediktor system throughout the ...
2004-08-01
COLLISIONAL AND LUMINOSITY EVOLUTION OF A DEBRIS DISK: THE CASE OF HD 12039
International Nuclear Information System (INIS)
Extrasolar debris disks that are bright enough to be observed are dense enough to be collision-dominated; i.e., the small grains that produce their infrared excess have collisional lifetimes shorter than their Poynting-Robertson decay times. This paper describes a numerical code for the modeling of such disks, including accretion and gravitational stirring as well as disruptive collisions. A constraint relating the mass of a debris disk and the sizes of the largest embedded bodies to its luminosity is demonstrated. The collisional code is applied to the debris disk around HD 12039, which has been intensively observed by the Spitzer Space Telescope. The evolution in time of the disk's luminosity is computed for a range of initial disk masses and planetesimal sizes. The luminosity at a given age depends on both the initial disk mass and the initial size of the planetesimals. Luminosity decays more rapidly for massive disks due to the combination of collisional ...
2010-10-20
International Nuclear Information System (INIS)
The CAMDU 6 reactor has an international reputation as one of the world's best performing and safe reactors. CANDU 6 reactors are consistently ranked in the world's top 10 for annual and lifetime performance. Six CANDU 6 units are currently in operation in four continents; in Quebec, New Brunswick, South Korea, Argentina and Romania. There are another two CANDU 6 units currently under construction at wolsong, in Korea which ore scheduled to go into service in 1998 and 1999 respectively. A second CANDU 6 unit is currently being considered for Romania. The construction of two CANDU 6 units at Qinshan, in China, is now underway. The performance of the four first-generation CANDU 6 plants, which have now been in service for 15 years, continue to show very good performance, with capacity factors on average since in-service of over 85%. The annual capacity factor of 10.21% during 1997 has been achieved by the Wolsong-1 unit in South Korea. These high capacity factors ...
1998-03-23
Beta-decay studies of neutron-rich Sc-Cr nuclei
International Nuclear Information System (INIS)
The neutron-rich nuclei"5"7","5"8_2_1Sc,"5"8"-"6"0_2_2Ti,"6"0"-"6"3_2_3V,"6"2"-"6"6_2_4Cr have been produced at Ganil via interactions of a 61.8A MeV "7"6Ge beam with a "5"8Ni target. Beta-decay studies have been performed using combined #beta#- and #gamma#-ray spectroscopy. Half-lives have been determined and #beta#-decay schemes are proposed for "5"8Ti, "6"1V and "6"2Cr. From these studies, new hints for the existence of #beta#-decaying isomers in "6"0V and in "6"2Mn are provided. These results are compared to shell model calculations. The role of the #pi#f_7_/_2- #nu#f_5_/_2 proton-neutron interaction is examined through its influence on the lifetime values. (orig.)
2005-01-01
Are HI Supershells the Remnants of $\\gamma$-Ray Bursts?
Gamma-Ray Bursts (GRBs) are thought to originate at cosmological distances from the most powerful explosions in the Universe. If GRBs are not beamed then the distribution of their number as a function of gamma-ray flux implies that they occur once per (0.3-40) million years per bright galaxy and that they deposit >10^{53} ergs into their surrounding interstellar medium. The blast wave generated by a GRB explosion would be washed out by interstellar turbulence only after tens of millions of years when it finally slows down to a velocity of 10 km/s. This rather long lifetime implies that there could be up to several tens of active GRB remnants in each galaxy at any given time. For many years, radio observations have revealed the enigmatic presence of expanding neutral-hydrogen (HI) supershells of kpc radius in the Milky Way and in other nearby galaxies. The properties of some supershells cannot be easily explained in terms of conventional sources such as stellar ...
1998-01-01
Energy Technology Data Exchange (ETDEWEB)
A combined PVD/PECVD process for the vacuum deposition of titanium containing amorphous hydrogenated carbon films is described. Elemental compositions of the deposited films have been determined by in situ core level photoelectron spectroscopy (XPS). The long-term stability of the plasma process has been demonstrated. Target poisoning has not been observed. We have fabricated optical selective surfaces by the deposition of a-C:H/Ti multilayers onto aluminum substrates. Even though we have not optimized layer thicknesses and stoichiometries so far, the experimental results are promising: solar absorptance {alpha}{sub S} of 0.876 and thermal emittance {epsilon}{sub 100C} of 0.061 have been achieved yielding an optical selectivity sis defined as{alpha}{sub S}/{epsilon}{sub 100C} of 14.4. Accelerated aging tests of these coatings have demonstrated their aging stability: the service lifetime is predicted to amount to more than 25 years. Raman spectroscopy has been used ...
2000-01-31
Energy Technology Data Exchange (ETDEWEB)
Ex situ and in situ fuel cell degradation of a sPAEK membrane were investigated. Post-mortem analyses of the aged membrane and of the degradation products eluted in water were carried out by NMR, IR, SEC and EDX. Ex situ agings were performed in a low concentration H{sub 2}O{sub 2} solution (0.07%) without any metallic catalyst. We exemplify that ex situ accelerated aging tests in such hydrogen peroxide solution are relevant to the chemical degradation in fuel cell. We have shown that a 500 h fuel cell test at moderate temperature (60 C) induces significant modifications on the macromolecules such as a 40% molecular weight reduction. Degradation appears heterogeneous and limited to the cathode side. The model compound approach developed in the previous article (Perrot et al.) has allowed the identification of the aging path in fuel cell. Phenolic and carboxylic acid chain ends have been identified as the main products resulting from polymer chain scissions. The ex situ ...
2010-01-15
Energy Technology Data Exchange (ETDEWEB)
Wind power is an increasingly significant renewable energy resource, producing no environmentally damaging C0{sub 2} emissions. The efficient production of electricity by wind turbines relies on aerodynamics: aerodynamics of wind turbines provides the fundamental solutions to efficient wind turbine design. Following a historical introduction, Part 1 of Aerodynamics of Wind Turbines is concerned with basic rotor aerodynamics, while Part 2 deals with structural aspects of the wind turbine and calculation of the loads on it. Topics covered include increasing mass flow through the turbine, performance at low and high wind speeds, assessment of the extreme conditions under which the turbine will perform and the theory for calculating the lifetime of the turbine. The classical Blade Element Momentum method is also covered, as are eigenmodes and the dynamic behaviour of a turbine. Aerodynamics of Wind Turbines is an essential reference for both engineering students and ...
2000-06-15
Energy Technology Data Exchange (ETDEWEB)
Wind power is an increasingly significant renewable energy resource, producing no environmentally damaging CO2 emissions. The efficient production of electricity by wind turbines relies on aerodynamics. Aerodynamics of Wind Turbines provides the fundamental solutions to efficient wind turbine design. Following a historical introduction, Part 1 of Aerodynamics of Wind Turbines is concerned with basic rotor aerodynamics, while Part 2 deals with structural aspects of the wind turbine and calculation of the loads on it. Topics covered include increasing mass flow through the turbine, performance at low and high wind speeds, assessment of the extreme conditions under which the turbine will perform and the theory for calculating the lifetime of the turbine. The classical Blade Element Momentum method is also covered, as are eigenmodes and the dynamic behaviour of a turbine. Aerodynamics of Wind Turbines is an essential reference for both engineering students and others ...
2001-01-01
Energy Technology Data Exchange (ETDEWEB)
Chromium containing amorphous hydrogenated carbon films (a-C : H/Cr) have been prepared by simultaneous rf plasma activated chemical vapour deposition of methane and magnetron sputtering of a chromium target. During deposition the substrates were heated (up to 300C) and DC biased (-200 and -600 V) in order to obtain films with high chemical stability. Constant temperature tests were performed at 250C in air with coatings deposited on silicon substrates. The degradation of the coatings was monitored by Raman spectroscopy and reflectance and transmission measurements. The main degradation mechanisms are discussed and the relevant parameters which improve the durability of the coatings are presented. Furthermore, the durability of solar selective, multilayered coatings which were deposited on copper sheets was investigated. Based on accelerated aging tests at different temperature loads in air (at 220C, 250C and 300C) and in a humid environment (80C sample temperature in humid air with ...
1998-07-13
A wavelet approach to fault diagnosis of a gearbox under varying load conditions
Varying load can cause changes in a measured gearbox vibration signal. However, conventional techniques for fault diagnosis are based on the assumption that changes in vibration signal are only caused by deterioration of the gearbox. There is a need to develop a technique to provide accurate state indicator of gearbox under fluctuating load conditions. This paper presents an approach to gear fault diagnosis based on complex Morlet continuous wavelet transform under this condition. Gear motion residual signal, which represents the departure of time synchronously averaged signal from the average tooth-meshing vibration, is analyzed as source data due to its lower sensitiveness to the alternating load condition. A fault growth parameter based on the amplitude of wavelet transform is proposed to evaluate gear fault advancement quantitatively. We found that this parameter is insensitive to varying load and can correctly indicate early gear fault. For a comparison, the advantages and ...
2010-04-01
A pulse-width modulated, high reliability charge controller for small photovoltaic systems
Energy Technology Data Exchange (ETDEWEB)
This report presents the results of a development effort to design, test and begin production of a new class of small photovoltaic (PV) charge controllers. Sandia National Laboratories provided technical support, test data and financial support through a Balance-of-System Development contract. One of the objectives of the development was to increase user confidence in small PV systems by improving the reliability and operating life of the system controllers. Another equally important objective was to improve the economics of small PV systems by extending the battery lifetimes. Using new technology and advanced manufacturing techniques, these objectives were accomplished. Because small stand-alone PV systems account for over one third of all PV modules shipped, the positive impact of improving the reliability and economics of PV systems in this market segment will be felt throughout the industry. The results of verification testing of the new product are also ...
1997-02-01
A comparison of the low-cycle fatigue behavior of Alloy 800 and Alloy 800H
International Nuclear Information System (INIS)
At 650"0C, the low-cycle fatigue life was essentially the same for the two alloys on the basis of strain amplitude, but Alloy 800H had a longer life on the basis of stress amplitude. A 500"0C, Alloy 800 and 800H exhibited longer fatigue lifetime than at 650"0C, with Alloy 800 exhibiting a 2-3 times longer life than Alloy 800H when compared on the basis of plastic strain range, whereas the difference was less pronounced when compared on the basis of stress amplitude. When a creep effect was introduced either by way of a hold time or a reduced frequency, Alloy 800 exhibited a greater reduction in life than did Alloy 800H. The dislocation structure changed from planar to cellular with increase in strain range, and extensive precipitation of M_2_3C_6 was noted within the grains for Alloy 800H and along grain boundaries for both alloys. (Auth.).
#beta#-decay half-lives of very neutron-rich isotopes of elements from Ti to Ni
International Nuclear Information System (INIS)
The unknown #beta#-decay half-lives of 22 isotopes far off stability (5 < T_Z < 10) in the region from Ti to Ni were measured at GSI, Darmstadt. The nuclei were produced in a fragmentation reaction of 500 A.MeV "8"6Kr-projectile impinging on a thick Be target. The isotopes of interest were separated and identified with the fragment separator, FRS, by a combination of B#rho#,Z, and ToF techniques. An additional range separation was performed by a selective implantation into granular detectors. The spatial and time correlations of the implant with the consecutively detected #beta#-particles were used to determine the unknown half-lives. For nuclei far off stability, #beta#-decay chains were measured and analyzed as well, leading to an even more reliable evaluation of the lifetimes. The large discrepancies found between the measured and the theoretical values emphasize that most recent theoretical work is not an improvement over calculations made almost a decade ...
Upper bound for a three-photon excitation cross section in atomic argon in the ultraviolet regime
Energy Technology Data Exchange (ETDEWEB)
A scheme of evaluating a generalized three-photon excitation cross section sigma/sub (3)/ in neutral atomic argon at 3144.67 A is outlined. Three photons at this wavelength can excite the neutral argon atoms from the ground 3p/sup 6/ /sup 1/S/sub 0/ state to the 3p/sup 5/4s'(1/2)/sub 1//sup 0/ state. The fourth photon will ionize the argon atoms. Assuming linear polarization of the incident laser radiation, contributions from several channels in various energy-level schemes are summed in the evaluation of the transition probability. For a laser linewidth of ..delta..lambda/sub L/ = 1 A, our maximum numerical value of the computed result for the three-photon excitation cross section is sigma/sub (3)/ = 1.414 x 10/sup -80/ cm/sup 6/ s/sup 2/. .AE
1989-04-15
International Nuclear Information System (INIS)
A 2-stage cold (non-tritium) PMR system was tested with the ITER mix in 61 days of continuous operation. No decrease in performance was observed over the duration of the test. Decontamination factor (DF) was found to increase with decreasing inlet rate. Decontamination factors in excess of 1.4x10"5 were obtained, but the exact value of the highest DF could not be determined because of analysis limitations. Results of the 61-day test were used to design a 2-stage PMR system for use in tritium testing. The PMR system was scaled up by a factor of 6 and built into a glovebox in the Tritium Systems Test Assembly (TSTA) of the Los Alamos National Laboratory. This system is approximately 1/5"t"h of the expected full ITER scale. The ITER mix was injected into the PMR system for 31 hours, during which 4.5 g of tritium were processed. The 1"s"t stage had DF =200 and the 2"n"d stage had DF=2.9x10"6. The overall DF=5.8x10"8, which is greater than ITER ...
1996-06-16
Three-step photoionization of mercury for application to separation of mercury isomers
International Nuclear Information System (INIS)
Development of techniques for separating isomeric nuclides is important to the investigation of schemes for gamma-ray lasers. In preparation for an experiment to separate 10_1_4 atoms of the /sub 197m/Hg (299 keV, tau/sub 1/2/ = 24 hours) isomer, we report isotopically selective resonance ionization of mercury atoms. This has been accomplished by three-step excitation via the 6_3P"1 and 8_1S"0 excited states, using three collinear pulsed laser beams of 254, 286, and 532 nm wavelengths from a Nd:YAG and two dye lasers. These beams were passed through a closed mercury-vapor cell containing electrostatic plates to which the ions were drawn. Ion current and fluorescent radiation were measured as a function of laser frequency. Hyperfine structures for the 254- and 286-nm transitions were observed.
Radiation reduction of dicarboxylatoimidazole platinum(II) complexes in the water-methanol system
Energy Technology Data Exchange (ETDEWEB)
The radiation reduction of bis(1-ethylimidazole)tartratoplatinum(II) (EITPt(II)) complexes in methanol-water solution have been examined. The yields of Pt(I) depend on the presence of O{sub 2} in solutions as well as the dose applied. The rate constants of e{sub s}{sup -} scavenging by EITPt(II) and cis(diammine-1,1-cyclobutanedicarboxylato) platinum(II) (CBDCAPt(II)) have been determined by pulse radiolysis to be equal to 5.4 x 10{sup 9} and 6.4 x 10{sup 9} M{sup -1} s{sup -1}, respectively. The efficiencies of e{sub t}{sup -} scavenging by EITPt(II) and the rate of e{sub t}{sup -} photobleaching have also been determined in LiCl : H{sub 2}O : CH{sub 3}OH and MgCl{sub 2} : H{sub 2}O : CH{sub 3}OH glasses, respectively. (author).
1997-10-01
Pulse radiolysis study of reactions of tetracycline with radiolytically generated reducing species
Energy Technology Data Exchange (ETDEWEB)
The transients involved in the reaction of tetracycline (TC) with reducing radicals such as e{sub aq}{sup -}, (CH{sub 3}){sub 2}COH and CO{sub 2}{sup .-}have been characterized by the pulse radiolysis technique. The semi-reduced species formed ({lambda}{sub max} = 630 nm, {epsilon} 3.4 x 10{sup 3} dm{sup 3} mol{sup -1} cm{sup -1}) has been found to be a strong reductant with reduction potential lying in the range -0.450 to -1.40 V vs NHE. TC reacts with e{sub aq}{sup -} at diffusion-controlled rates and the rate constant, depending upon the ionic form of TC existing at a particular pH, varies from 1.2 x 10{sup 10} to 2.8 x 10{sup 10} dm{sup 3} mol{sup -1} s{sup -1}. Based on these results a plausible site of electron addition has been suggested. Reaction of H atoms with TC gives rise to a transient which exhibits spectral and kinetic features different from that of semi-reduced species. (author).
1994-11-01
Potassium deposition on a thiophene-terminated alkanethiol monolayer
International Nuclear Information System (INIS)
Potassium deposition in ultrahigh vacuum on 12-(3-thienyl)dodecanethiol monolayers assembled on gold surfaces has been investigated using X-ray and ultraviolet photoelectron spectroscopies (XPS and UPS). Angle-resolved XPS indicates that initially deposited potassium penetrates the self-assembled monolayer (SAM) and diffuses to the SAM/Au interface. Even after large metal doses, the presence of thiophene ring valence electronic states in the UPS spectra confirms that most of the thiophene rings (at the SAM/vacuum interface) are not covered by potassium. The binding energy shifts of the thiophene ring valence states and the C1s and thiophene S2p peaks, referenced to the Fermi level, are due to the work function changes of the gold substrate. This indicates that these electronic states are pinned to the vacuum level, in contrast to the thiolate S2p orbital, which is pinned to the Fermi level. For large potassium doses, the appearance of new ...
2009-05-01
International Nuclear Information System (INIS)
Current advanced CMOS source/drain engineering involves the use of amorphizing implants with 3D geometry. Upon annealing, the induced transient enhanced diffusion (TED) can only be accurately predicted if the amorphized region is correctly modeled, as well as the formation and evolution of extended defects, particularly 3 1 1's and dislocation loops. In addition to the extended defects, already modeled in the atomistic kinetic Monte-Carlo simulator DADOS, we have developed a physically based modeling approach for the implant-induced damage build-up, amorphization and recrystallization, suitable to handle device-size process simulation. It is based on amorphous pockets (3D, irregular shape agglomerates of an arbitrary number of interstitials and vacancies, plus trapped impurities) with a size-dependent activation energy for recombination. The model is able to reproduce experimental aspects like the crystal-amorphous transition temperature and ...
2004-12-15
Pa0148 from Pseudomonas aeruginosa Catalyzes the Deamination of Adenine.
Four proteins from NCBI cog1816, previously annotated as adenosine deaminases, have been subjected to structural and functional characterization. Pa0148 (Pseudomonas aeruginosa PAO1), AAur1117 (Arthrobacter aurescens TC1), Sgx9403e, and Sgx9403g have been purified and their substrate profiles determined. Adenosine is not a substrate for any of these enzymes. All of these proteins will deaminate adenine to produce hypoxanthine with k(cat)/K(m) values that exceed 10(5) M(-1) s(-1). These enzymes will also accept 6-chloropurine, 6-methoxypurine, N-6-methyladenine, and 2,6-diaminopurine as alternate substrates. X-ray structures of Pa0148 and AAur1117 have been determined and reveal nearly identical distorted (?/?)(8) barrels with a single zinc ion that is characteristic of members of the amidohydrolase superfamily. Structures of Pa0148 with adenine, 6-chloropurine, and hypoxanthine were also determined, thereby permitting identification of the ...
2011-07-06
Optical Feshbach Resonances in Alkaline Earth Atoms
Recent proposals have shown that a quantum degenerate gas of alkaline earth atoms can be used for a number of novel quantum computing and quantum simulation experiments. Strontium is a good candidate for such experiments because it can be controlled with high precision, as demonstrated in recent atomic clock experiments. Unfortunately, the small scattering length of strontium is not amenable to evaporative cooling techniques that are used to reach quantum degeneracy. Furthermore, increasing the scattering length of alkaline earths with a magnetic Feshbach resonance is not possible due to their spinless electronic ground state configuration. However, recent theoretical and experimental work suggests the possibility of changing scattering lengths in alkaline earths with laser light. Using this optical Feshbach resonance near strontium's narrow ^1S0->^3P1 intercombination transition might allow its scattering length to be controlled without ...
2009-10-01
Energy Technology Data Exchange (ETDEWEB)
Fine-grained AZ31 magnesium alloy sheets were prepared through hot rolling process. The superplastic properties of hot-rolled AZ31 Mg alloy was examined by uniaxial tensile tests at a temperature range 250{proportional_to}450 C and strain rate range 0.7 x 10{sup -3}{proportional_to}1.4 x 10{sup -1} s{sup -1}. Optical and scanning electronic microscope (SEM) were used to observe the microstructure evolution and fracture behavior in superplastic deformation of AZ31 Mg alloy and the values of deformation activation energy at various temperatures were calculated. It is demonstrated that, the hot-rolled AZ31 alloy begins to exhibit superplasticity from 300 C and a maximum elongation of 362.5% is obtained at 400 C and 0.7 x 10{sup -3} s{sup -1}. In the temperature range 300{proportional_to}400 C, the dominant superplastic deformation mechanism is grain boundary sliding (GBS) controlled by grain boundary diffusion and the influence of temperature on ...
2005-07-01
Kinetics of the stress induced phase transition in quartz by real-time neutron scattering
International Nuclear Information System (INIS)
Complete text of publication follows. The stability regime of the incommensurate phase of quartz is influenced by uniaxial stress. Hence, the phase transition can be induced under isothermal conditions by the application of external mechanical forces. Using real-time neutron scattering the time evolution of structural changes is investigated id detail during stress variations. The time dependent behaviour of the satellite reflection is compared with that one of the fundamental Bragg reflection which - via primary extinction - gives information about the perfection of the crystal. On increasing stress the perfection of the lattice is destroyed immediately while the modulated structure is built up with a delay of about 1 s. Decreasing the stress leads to a reverse behaviour. Moreover, there is evidence that under periodical load residual non-relaxed strain fields survive leading to a different temperature dependence as compared to static ...
1999-09-01
Energy Technology Data Exchange (ETDEWEB)
The effective electron mobility was measured as a function of surface field in polysilicon thin film transistors having the following three types of gate dielectrics; silicon dioxide deposited by low temperature (350degC) plasma-enhanced chemical vapor deposition (PECVD), low temperature (400degC) nitrogen-rich PECVD silicon nitride and high temperature (1050degC) thermally grown silicon dioxide. At low surface fields, the maximum true effective electron mobility was 40[+-]3 cm[sup 2] V[sup -1] s[sup -1] in all devices independent of the type of gate dielectric, indicating that the quality of the interface is the same. However, at high surface fields a stronger degradation of the mobility was observed in devices having the thermally grown silicon dioxide as gate dielectric, indicating the presence of surface roughness within the interfacial region. The polysilicon structure was studied by transmission electron microscopy in order to ensure that ...
1992-08-28
Identification of water quality and benthos characteristics in Daya Bay, China, from 2001 to 2004
British Library Electronic Table of Contents (United Kingdom)
Physicochemical and benthos data were collected from 12 marine monitoring stations in Daya Bay, during 2001-2004. 12 stations in Daya Bay could be grouped into three clusters: cluster I consisted of stations in the southern part of Daya Bay (stations S1, S2 and S6); cluster II consisted of stations in the cage culture areas (stations S3, S4, S5 and S8); cluster III consisted of stations in the southwest, the middle and the northeast of the Bay (stations S7, S9, S10, S11 and S12). Calculation with bivariate correlations between benthos and major physicochemical factors showed that the density of benthos in all stations correlated positively with temperature, DO, pH, NH4-N, SiO3-Si, SiO3-Si /PO4-P and chlorophyll a and was negatively correlated with salinity, Secchi, COD, NO3-N, NO2-N, TIN, ...
2011-01-01
Hydrogen synthesis via combustion of fuel-rich natural gas/air mixtures at elevated pressure
Energy Technology Data Exchange (ETDEWEB)
Combustion of extremely fuel-rich ({phi}=4) methane/air mixtures at elevated pressures is investigated as a potential means to generate molecular hydrogen by non-catalytic partial oxidation. This system is investigated both computationally and experimentally. The computations use a perfectly-stirred reactor model and an explicit methane cool-flame mechanism to investigate the effects of reactor parameters on reaction time and product composition. Under adiabatic conditions, such mixtures are predicted to autoignite at low temperatures {approx}700 K for pressures exceeding 8.5 atm. Above 15 atm, conversion to products is complete in roughly 1 s. The dependence of reaction time and hydrogen yield is investigated as a function of inlet temperature, system pressure, and flame equivalence ratio. Actual product yields are measured in a tube reactor facility, and many of the predictions of the model, including long relaxation times to chemical ...
2005-07-01
High temperature deformation behavior of AZ31 Mg alloy
Energy Technology Data Exchange (ETDEWEB)
High temperature deformation behavior of AZ31 Mg alloy was investigated in this study on the basis of a processing map ({epsilon} {approx} 0.6). To construct a processing map, compression tests were carried out at various temperatures and strain rates. Two regions of high deformation efficiency ({eta}) were identified as: (1) a dynamic recrystallization (DRX) domain at 250 C and 1/s and (2) a superplasticity domain at 450 C and 10{sup -4}/s. The average grain size observed in the DRX region was considerably smaller (2.9{mu}m) than in any other region. In the superplastic condition, tensile elongation to failure approached to 1040%. At the high Z regions, flow softening occurred resulting from the dynamic recrystallization but below 10{sup 10} of Z value, flow hardening occurred due to the grain growth. Possible deformation mechanisms operating at high temperature were discussed in relation to the activation energy. A two-stage deformation ...
2005-07-01
Evidence for the h_b(1P) meson in the decay Upsilon(3S) --> pi0 h_b(1P)
Using a sample of 122 million Upsilon(3S) events recorded with the BaBar detector at the PEP-II asymmetric-energy e+e- collider at SLAC, we search for the h_b(1P) spin-singlet partner of the P-wave chi_b(1P) states in the sequential decay Upsilon(3S) --> pi0 h_b(1P), h_b(1P) --> gamma eta_b(1S). We observe an excess of events above background in the distribution of the recoil mass against the pi0 at mass 9902 +/- 4 (stat.) +/- 1 (syst.) MeV/c^2. The width of the observed signal is consistent with experimental resolution, and its significance is 3.0 sigma, including systematic uncertainties. We obtain the value (3.7 +/- 1.1 (stat.) +/- 0.7 (syst.))x 10^{-4} for the product branching fraction BF(Upsilon(3S) --> pi0 h_b) x BF(h_b --> gamma eta_b).
2011-01-01
Enthalpy measurements of La_2Te_3O_9 and La_2Te_4O_1_1
International Nuclear Information System (INIS)
Enthalpy increment measurements on La_2Te_3O_9(s) and La_2Te_4O_1_1(s) were carried out using a Calvet micro-calorimeter. The enthalpy values were analyzed using the non-linear curve fitting method. The dependence of enthalpy increments with temperature was given as: H"o(T) - H"o(298.15 K) (J mol"-"1) = 360.70T + 0.00409T "2 + 133.568 x 10"5/T - 149 923 (373 #<=# T (K) #<=# 936) for La_2Te_3O_9 and H"o(T) - H"o(298.15 K) (J mol"-"1) = 331.927T + 0.0549T "2 + 29.3623 x 10"5/T - 114 587 (373 #<=# T (K) #<=# 936) for La_2Te_4O_1_1.
2007-02-01
Electron spin resonance investigation of Mn^{2+} ions and their dynamics in manganese doped SrTiO_3
Using electron spin resonance, lattice position and dynamic properties of Mn2+ ions were studied in 0.5 and 2 % manganese doped SrTiO3 ceramics prepared by conventional mixed oxide method. The measurements showed that Mn2+ ions substitute preferably up to 97 % for Sr if the ceramics is prepared with a deficit of Sr ions. Motional narrowing of the Mn2+ ESR spectrum was observed when temperature increases from 120 K to 240-250 K that was explained as a manifestation of off-center position of this ion at the Sr site. From the analysis of the ESR spectra the activation energy Ea = 86 mV and frequency factor 1/?0 ? (2-10)x10^(-14) 1/s for jumping of the impurity between symmetrical off-center positions were determined. Both values are in agreement with those derived previously from dielectric relaxation. This proves the origin of dielectric anomalies in SrTiO3:Mn as those produced by the reorientation dynamics of Mn2+ dipoles.
2007-01-01
Energy Technology Data Exchange (ETDEWEB)
Rotationally resolved spectra of kinetic energy releases epsilon-c in predissociations of H/sub 2/, after dissociative charge exchange of H/sub 2/ /sup +/ with Cs atoms, are obtained. The experiments are performed with natural and with pure parahydrogen. The predissociations with epsilon-c<1.9 eV constitute less than 5% of the total amount of dissociations to HXchemically bondH at a beam energy of 5 keV. All strong rotational peaks observed could be attributed to n = 3 Rydberg states which predissociate to H(1s)+H(2l). Vibrational-rotational series are observed of the d /sup 3/Pi/sub u//sup +/, D /sup 1/Pi/sub u//sup +/, and J /sup 1/..delta../sub g//sup +/ states. Predissociation by barrier tunneling is reported of v = 4 levels of the h /sup 3/..sigma../sub g//sup +/ state and of v = 4 and 5 levels of the i /sup 3/Pi/sub g/ state. Selectivity of the charge-exchange process for different n = 3 states, or even for different parity states, is ...
1986-11-01
Two enantioselective, potentiometric membrane electrodes (EPMEs) based on maltodextrins with different value of dextrose equivalent (DE) (maltodextrin I: DE 4.0-7.0; maltodextrin II: DE 16.5-19.5) were proposed for the assay of baclofen enantiomers in baclofen raw materials and from its pharmaceutical formulation, Norton-Baclofen tablets. The slopes of the electrode function of the proposed electrodes were 55.0 mV/pS-baclofen for maltodextrin I-based electrode and 59.0 mV/pR-baclofen for maltodextrin II-based electrode and the detection limits were 1.34 x 10(-6) mol l(-1) (S-baclofen) and 2.52 x 10(-10) mol l(-1) (R-baclofen), respectively. The surfaces of the electrodes are stable and easily renewable by simply polishing on alumina paper. PMID:15598435
2004-12-01
Let $M$ be a complex manifold of complex dimension $n+k$. We say that the functions $u_1,...s,u_k$ and the vector fields $\\xi_1,...,\\xi_k$ on $M$ form a \\emph{complex gradient system} if $\\xi_1,...,\\xi_k,J\\xi_1,...,J\\xi_k$ are linearly independent at each point $p\\in M$ and generate an integrable distribution of $TM$ of dimension $2k$ and $du_\\alpha(\\xi_\\beta)=0$, $\\d^c\\u_\\alpha(\\xi_\\beta)=\\delta_{\\alpha\\beta}$ for $\\alpha,\\beta=1,...,k$. We prove a Cauchy theorem for such complex gradient systems with initial data along a $\\CR-$submanifold of type $(\\CRdim,\\CRcodim)$. We also give a complete local characterization for the complex gradient systems which are \\emph{holomorphic} and \\emph{abelian}, which means that the vector fields $\\xi_\\alpha^c=\\xi_\\alpha-J\\xi_\\beta$, $\\alpha=1,...,k$ are holomorphic and satisfy $[\\xi_alpha^c,\\bar{\\xi_\\beta^c}]=0$ for each $\\alpha,\\beta=1,...,k$.
2011-01-01
Biophysical analysis of DNA modified by 1,2-diaminocyclohexane platinum(II) complexes
Energy Technology Data Exchange (ETDEWEB)
Modification of DNA and double-stranded deoxyoligonucleotides with antitumor 1,2-diamino-cyclohexanedinitroplatinum(II) (Pt-dach) complexes was investigated with the aid of physico-chemical methods and chemical probes of nucleic acid conformation. The three Pt-dach complexes were used which differed in isomeric forms of the dach non-leaving ligand-Pt(1R,2R-dach), Pt(1S,2S-dach) and Pt(1R,2S-dach) complexes. The latter complex has lower antitumor activity than the other two Pt-dach complexes. Pt(1R,2S-dach) complex exhibits the slowest kinetics of its binding to DNA and of the conversion of monofunctional binding to bifunctional lesions. The anomalously slow electrophoretic mobility of multimers of the platinated and ligated oligomers suggests that bifunctional binding of Pt-dach complexes to a d(GG) site within double-stranded oligonucleotides induces bending of the oligomer. It is proposed that different effects of the Pt-dach complexes on DNA ...
1992-01-25
A transient enhanced diffusion model of lattice restoration during rapid thermal annealing (RTA)
International Nuclear Information System (INIS)
A transient-enhanced diffusion has been observed during the furnace or rapid thermal annealing of As-implanted Si. The relations of the enhanced diffusion to residual defects and lattice restoration have been studied in detail. The As concentration profiles and residual defects are measured. It is found from the data that the lattice has been restored when the implanted sample is annealed at 1150 deg C (or 1050 deg C) for 1s. The defect density decreases rapidly with increase of annealing time (from 1 to 12s). The enhanced diffusion coefficient maximum appears in the annealing time ranging from 1 to 5s. Allmost a 'complete' annealing of displacemet damage is obtained and the diffusion coefficient is less than that in above-mentioned conditions when the implanted samples are annealed at 1150 deg C in the time ranging from 12 to 20s. the mechanism of lattice restoration and enhanced diffusion in annealing process have been discussed.
Energy Technology Data Exchange (ETDEWEB)
The possibility of improving the cold formability of wrought magnesium alloys is considered in light of their good hot forming characteristics. Magnesium alloy AZ31B sheet is selected as a model system. Parameters affecting formability, such as strain hardening rate, strain rate sensitivity, and the degree of anisotropy are examined systematically by conducting tensile tests over a range of temperatures (room temperature to 250 C) and strain rates (1 x 10{sup -5} to 0.1 s{sup -1}). The plastic anisotropy and deformation texture evolution are examined in samples aligned with the sheet rolling and transverse directions. Polycrystal plasticity simulations using a viscoplastic self-consistent (VPSC) formulation are used to model the observed anisotropy and texture evolution. The adjustable parameters in the model are the relative critical resolved shear stresses of the dislocation mechanisms known to operate within magnesium. The experimental ...
2003-07-01
Energy Technology Data Exchange (ETDEWEB)
This dissertation describes a measurement of the rate ofnuclear muon capture by the proton, performed by the MuCap Collaborationusing a new technique based on a time projection chamber operating inultraclean, deuterium-depleted hydrogen gas at room temperature and 1 MPapressure. The hydrogen target's low gas density of 1 percent compared toliquid hydrogen is key to avoiding uncertainties that arise from theformation of muonic molecules. The capture rate was obtained from thedifference between the mu- disappearance rate in hydrogen--as determinedfrom data collected in the experiment's first physics run in fall2004--and the world averagefor the mu+ decay rate. After combining theresults of my analysis with the results from another independent analysisof the 2004 data, the muon capture rate from the hyperfine singlet groundstate of the mu-p atom is found to be Lambda_S = 725.0 +- 17.4 1/s, fromwhich the induced pseudoscalar ...
2007-07-10
British Library Electronic Table of Contents (United Kingdom)
Pyrrolo[2,1-c][1,4]benzodiazepine (PBD) chemicals are antitumor antibiotics inhibiting nucleic acid synthesis. An indole carboxylate-PBD hybrid with six-carbon spacer structure (IN6CPBD) has been previously demonstrated to induce melanoma cell apoptosis and reduce metastasis in mouse lungs. This study aimed at investigating the efficacy of the other hybrid compound with four-carbon spacer (IN4CPBD) and elucidating its anti-metastatic mechanism. Human melanoma A375 cells with IN4CPBD treatment underwent cytotoxicity and apoptosis-associated assays. Transwell migration assay, Western blotting, and ELISA were used for mechanistic study. IN4CPBD exhibited potent melanoma cytotoxicity through interrupting G1/S cell cycle progression, increasing DNA fragmentation and hypodipoidic DNA contents, a...
2011-01-01
Vacuum arc ignition by penning discharge in a strong magnetic field
Energy Technology Data Exchange (ETDEWEB)
Vacuum arc with cathode spots on the cold electrode is widely used as a plasma generator in a such kind of devices like metal ion sources, plasma cathode electron guns, thing films deposition facilities and others. Most vacuum arc devices utilize a high voltage discharge across an insulator surface to provide a trigger plasma which in turn initiates the main arc discharge. Operation of vacuum arc in a repetitively pulsed mode required a stable triggering system for the long time. But with a discharge across the insulators the number of stable pulses is limited by 100,000 or little bit more. The better method for vacuum arc ignition is low pressure discharge. As shown in this paper it is possible to increase the lifetime of the ignition system in 10 times at least, but negative characteristic of this system is a relatively high pressure (about 0.1 mtorr). In some kinds of vacuum arc applications it is impermissible because it leads to the ...
1995-12-31
Thermal fatigue of HIPed W/Cr-bronze divertor small scale mock-ups
International Nuclear Information System (INIS)
Thermal fatigue is one of the key factors governing the lifetime of the divertor plate. Tungsten is a promising candidate to cover the surface of the divertor plate in the design of the international thermonuclear experimental reactor (ITER). The W/Cr-bronze divertor small scale mock-ups were manufactured by hot isostatic pressing (HIPing) technique. Thermal fatigue tests of W/Cr-bronze divertor mock-ups have been carried out by an electron beam facility. The mock-ups were tested under a cyclic surface heat flux of 9 MW m"-"2 for 1000 cycles. The electron beam was loaded on the mock-up surface for 20 s and unloaded for 20 s, alternately. The flow rate of water coolant was 0.1 L s"-"1. The 0.3 mm diameter NiCr-NiSi thermocouples were used to monitor the temperature distribution of the mock-up. It was found that the maximum temperature of the tungsten surface was about 400 degree sign C. The saturated temperature at the joint of tungsten and Cr-bronze was 160 degree ...
2004-11-15
The pisa experiment: spallation products identified by bragg curve spectroscopy
International Nuclear Information System (INIS)
In the framework of spallation neutron sources and accelerator-driven systems, the international PISA (Proton-induced Spallation) collaboration has initiated measurements of total- and double-differential cross-sections for products of spallation reactions in a wide range of target nuclei (GU) at the COSY proton accelerator in Julich (Germany). The purpose is to study secondary particle production created in structural, window and target materials via proton beams up to 2.5 GeV of incident kinetic energy. Residual nuclei [H, He up to intermediate mass fragment (IMF)] production cross-sections are of great importance for estimating the damage to target and structure materials involving the planned spallation neutron sources, given that the lifetime of window and target materials is directly associated to those cross-sections. The demand for reliable theoretical predictions on production cross-sections is by no means satisfied by the models and codes that are ...
2004-05-17
The advanced manufacturing science and technology program. FY 95 Annual Report
Energy Technology Data Exchange (ETDEWEB)
This is the Fiscal Year 1995 Annual Report for the Advanced Manufacturing Science and Technology (AMST) sector of Los Alamos Tactical Goal 6, Industrial Partnering. During this past fiscal year, the AMST project leader formed a committee whose members represented the divisions and program offices with a manufacturing interest to examine the Laboratory`s expertise and needs in manufacturing. From a list of about two hundred interest areas, the committee selected nineteen of the most pressing needs for weapon manufacturing. Based upon Los Alamos mission requirements and the needs of the weapon manufacturing (Advanced Design and Production Technologies (ADaPT)) program plan and the other tactical goals, the committee selected four of the nineteen areas for strategic planning and possible industrial partnering. The areas selected were Casting Technology, Constitutive Modeling, Non-Destructive Testing and Evaluation, and Polymer Aging and Lifetime Prediction. For each ...
1996-03-01
Synthesis, structure, and spectroscopic properties of ortho-metalated platinum(II) complexes
Energy Technology Data Exchange (ETDEWEB)
The ortho-metalated Pt(II) complexes Pt(ppy)(CO)Cl (1), Pt(ptpy)(CO)Cl (2), and Pt(ppy)(Hppy)Cl (3) (where ppy and ptpy are respectively the ortho-C-deprotonated forms of 2-phenylpyridine and 2-p-tolylpyridine and Hppy is 2-phenylpyridine) have been prepared. The CO ligand is coordinated trans to the nitrogen atom of the ortho-metalated ligand and exerts a strong trans effect resulting in a relatively long Pt-N bond [2.114(19) {angstrom}]. This structure shows both the bidentate ppy ligand and the monodentate Hppy with the nitrogens of these ligands trans to each other. The UV/vis electronic absorption spectra of 1-3 have intense bands in the near-UV region ({approximately}375 nm) which have been assigned as metal to ligand charge transfer (MLCT) transitions, and higher energy bands were assigned as ligand-centered transitions. Each complex exhibits relatively long-lived structured emissions in the solid state at ambient temperature and at 77 K and 77 K glassy toluene solutions. These ...
1995-04-26
Supramolecular selectivity of [60]-fullerene among equivalently photoactive porphyrins
International Nuclear Information System (INIS)
The photophysical investigation of different para-substituted tetraphenylporphyrins (TP), viz., meso-tetra(4'-hydroxyphenyl)-21H-23H-porphyrin(1),meso-tetrakis (4'-hex-5-enyloxyphenyl)-21H-23H-porphyrin(2), meso-tetrakis(4'-oct-7-enyloxyphenyl)-21H-23H-porphyrin(3) and meso-tetrakis(4'-undecyloxyphenyl)-21H-23H-porphyrin (4) revealed that except for quantum yield (#phi#) the para-substitution has little effect on any other photophysical properties like lifetime, excitation, emission wavelength, etc. The host-guest type interactions of these tetraarylporphyrins (TP 1-4), with [60]-fullerene (F) have been studied with "1H NMR and fluorescence spectrometric techniques in carbon tetrachloride medium. Fluorescence studies revealed that the Q band of the TPs was sufficiently quenched upon addition of F. All the fullerene/porphyrin systems were found to produce stable complexes with 1:1 stoichiometry. Binding constants (K) of all the fullerene/porphyrin complexes have ...
2010-10-01
Success in geothermal development
International Nuclear Information System (INIS)
Success in geothermal development can be defined as the ability to produce geothermal energy at compatible energy prices to other energy sources. Drilling comprises usually the largest cost in geothermal development, and the results of drilling is largely influencing the final price of geothermal energy. For 20 geothermal fields with operating power plants, the ratio between installed capacity and the total number of well in the field is 1.9 MWe/well. The drilling history in 30 geothermal fields are analyzed by plotting the average cumulative well outputs as function of the number of wells drilled in the field. The range of the average well output is 1-10 MWe/well with the mean value 4.2 MWe/well for the 30 geothermal fields studied. A leaning curve is defined as the number of wells drilled in each field before the average output per well reaches a fairly constant value, which is characteristic for the geothermal reservoir. The range for this learning time is 4-36 wells and the average ...
Subseabed disposal: systematic application of the site qualification plan
Energy Technology Data Exchange (ETDEWEB)
Two criteria, geologic stability and barrier effectiveness, form the basis of the Subseabed Disposal Program's site qualification plan to evaluate the ocean basins and identify those regions having characteristics most favorable for containment of radioactive waste. Stability criteria are used to define those regions least likely to be disturbed by tectonic forces or oceanographic changes during the lifetime of a waste repository. Barrier criteria define those lithologies most likely to form an effective barrier to the release of radionuclides. Two north Pacific regions and three north Atlantic regions (PAC I and II and ATL I, II, and III, respectively) have thus far been selected for further investigation based on the site qualification plan. The PAC I region, centered on the Shatsky Rise in the northwest Pacific, has been subdivided into areas and locations on the basis of an exhaustive review of data available in the archives of national and ...
1982-01-01
Energy Technology Data Exchange (ETDEWEB)
This study focuses on a series of Pt{sup II}(L-L{prime})(dppm){sup n+} complexes, where dppm is bis(diphenylphosphino)methane and L-L{prime} are C(caret)C{prime} (n = 0), C(caret)N (n = 1), and N(caret)N{prime} (n = 2) aromatic ligands. Structural characteristics are reported. Structural features indicate that the Pt-C bond distance is shorter than the Pt-N bond distance in symmetrical complexes and that the Pt-P bond distance trans to N is shorter than the Pt-P bond trans to C. This is consistent with the {sup 31}P NMR spectra where the chemical shift of the P trans to C is {approximately}10 ppm less than found for P trans to N. The energy maxima of the metal-to-ligand charge-transfer band for the complexes containing various L-L{prime} ligands occur in the near-UV region of the spectrum and fall into the energy series bpy > bph > phen > 2-phpy > 2-ptpy > 2-phq > 7,9-bzq, where bpy is 2,2{prime}-bipyridine, 2-phpy is 2-phenylpyridine, 2-ptpy ...
2000-05-01
Session 1: Geothermal Pumping Systems and Two-Phase Flow Studies
Energy Technology Data Exchange (ETDEWEB)
Improvements in electric submersible pumping systems have resulted in a demonstrated downhole running life of one year for low horsepower units operating in 180 C brine. The implementation of a prototype pressurized lubrication system to prevent brine intrusion and loss of lubricating oil from the motor and protector sections has been successfully tested. Second generation pressurized lubrication systems have been designed and fabricated and will be utilized in downhole production pumping tests during FY84. Pumping system lifetime is currently limited by available power cable designs that are degraded by high-temperature brine. A prototype metal-sheathed power cable has been designed and fabricated and is currently undergoing destructive and nondestructive laboratory testing. This cable design has the potential for eliminating brine intrusion into the power delivery system through the use of a hermatically sealed cable from the surface to the downhole motor. The ...
1983-12-01
Repowering: improving the economics of existing assets
Energy Technology Data Exchange (ETDEWEB)
Restructured power markets require concepts not only for extending the lifetime of existing plants, but also concepts for reducing the life-cycle costs of existing older steam power plants in order to remain competitive with the most modern and advanced power generation technology such as combined cycle power plants. Out of the broad range of methods to extend service life and increase availability, and to increase power output and efficiency, this paper focuses on full repowering. Full repowering replaces the old fired boiler with gas turbine(s) and heat-recovery steam generators (HRSG) as heat input to the existing bottoming cycle and reuses the steam turbine (ST) condenser and further balance of plant (BOP) equipment. The potential offered by this concept is demonstrated. Repowering and modernization projects are executed if they result in economic benefits for the operator. Investment decisions need to be prepared based on an estimate or proof of an adequate ...
2005-07-01
Recycle of iodine-loaded silver mordenite by hydrogen reduction
In 1977 and 1978, workers at Idaho National Engineering Laboratory (INEL) developed and tested a process for the regeneration and reuse of silver mordenite, AgZ, used to trap iodine from the dissolver off-gas stream of a nuclear fuel reprocessing plant. We were requested by the Airborne Waste Management Program Office of the Department of Energy to perform a confirmatory recycle study using repeated loadings at about 150/sup 0/C with elemental iodine, each followed by a drying step at 300/sup 0/C, then by iodine removal using elemental hydrogen at 500/sup 0/C. The results of our study show that AgZ can be recycled. There was considerable difficulty in stripping the iodine at 500/sup 0/C.; however, this step went reasonably well at 550/sup 0/C or slightly higher, with no apparent loss in the iodine-loading capacity of the AgZ. Large releases of elemental iodine occurred during the drying stage and the early part of the stripping stage. Lead zeolite, which was employed in the original ...
1982-11-01
Recent developments and applications for the University of Texas thermal neutron imaging facility
Energy Technology Data Exchange (ETDEWEB)
The full text follows. A thermal neutron imaging facility (TNIF) capable of real time neutron radiography and computed tomography was developed for the University of Texas TRIGA Mark II (UT-TRIGA) reactor from 1994-1998. The facility was developed with a through reactor beam port capable of producing a 5.2 x 10{sup 6} n/cm{sup 2}/s thermal neutron flux with a gamma dose rate of less than 1 mR/s after collimation. The original TNIF included the UT-TRIGA reactor, neutron collimation array, sample positioning system, neutron image intensifier tube, video camera, computerized image acquisition system, and a radiation shield. A 0.7 mm slit in cadmium was easily detectable using neutron radiography, and 1.4 mm diameter holes bored in an aluminum block were easily resolved using computed neutron tomography. Precise lower limits of the system resolution have hot been determined. The TNIF is currently being revamped to begin work with the non-destructive evaluation (NDE) of carbon fiber ...
2001-07-01
Energy Technology Data Exchange (ETDEWEB)
A major factor for the achievement of the desirable performance, efficiency and lifetime of flexible organic electronic devices is the optimization of the encapsulation layers that protect the device active layers by atmospheric gas molecule permeation. The active layers consisted of small molecule and/or polymer organic semiconductors as well as the organic conductors need to be encapsulated into a transparent medium that will provide the necessary protection and maintain their charge generation and transport characteristics. The encapsulation layers are generally consisted of inorganic thin films (silicon oxide-SiO{sub x} and aluminium oxide-AlO{sub x}) deposited onto the polymeric substrates, such as PolyEthylene Terephthalate (PET). In this work, in situ and real-time Spectroscopic Ellipsometry in the ultraviolet spectral region has been implemented in order to investigate the growth of inorganic SiO{sub x} and AlO{sub x} nano-layers onto PET flexible polymeric ...
2010-01-15
Rate and mechanism of the atmospheric degradation of 2 H-heptafluoropropane (HFC-227)
Energy Technology Data Exchange (ETDEWEB)
The atmospheric chemical behaviour of 2H-Heptafluoropropane (CF[sub 3]CHFCF[sub 3], HFC-227) with respect to its rate and mechanism of degradation in the troposphere has been investigated. The rate coefficient for the reaction of HFC-227 with OH radicals has been determined in direct time resolved experiments using a combination of laser-pulse initiation and LIF. In the temperature range T=298-463 K the Arrhenius expression k(T)=(3.8[+-]0.8) 10[sup -13] exp(-1596[+-]77 K/T) cm[sup 3]/s, which corresponds to k (298 K) = (1.8[+-]0.3) 10[sup -15] cm[sup 3]/s, was found. The mechanism of the atmospheric degradation of HFC-227 has been investigated using both, laser-pulse initiated/time resolved and UV photolysis/FTIR product studies. It is concluded that the major carbonyl products are CF[sub 3]COF and CF[sub 2]O which result from the decomposition of the oxy radical CF[sub 3]CF(O)CF[sub 3] by C-C bound fission. The rate coefficient for this decomposition process has been determined to be ...
1994-02-01
Radiation testing of organic ion exchange resins
International Nuclear Information System (INIS)
A number of ion exchange materials are being evaluated as part of the Tank Waste Remediation System (TWRS) Pacific Northwest Laboratory (PNL) Pretreatment Project for the removal of "1"3"7Cs from aqueous tank wastes. Two of these materials are organic resins; a phenol-formaldehyde resin (Duolite CS-100) produced by Rohm and Haas Co. (Philadelphia, Pennsylvania) and a resorcinol-formaldehyde (RF) resin produced by Boulder Scientific Co. (Mead, Colorado). One of the key parameters in the assessment of the organic based ion exchange materials is its useful lifetime in the radioactive and chemical environment that will be encountered during waste processing. The focus of the work presented in this report is the radiation stability of the CS-100 and the RF resins. The scope of the testing included one test with a sample of the CS-100 resin and testing of two batches of the RF resin (BSC-187 and BSC-210). Samples of the exchangers were irradiated with a "6"0Co source to ...
1983-04-11
Radiation testing of organic ion exchange resins
Energy Technology Data Exchange (ETDEWEB)
A number of ion exchange materials are being evaluated as part of the Tank Waste Remediation System (TWRS) Pacific Northwest Laboratory (PNL) Pretreatment Project for the removal of {sup 137}Cs from aqueous tank wastes. Two of these materials are organic resins; a phenol-formaldehyde resin (Duolite CS-100) produced by Rohm and Haas Co. (Philadelphia, Pennsylvania) and a resorcinol-formaldehyde (RF) resin produced by Boulder Scientific Co. (Mead, Colorado). One of the key parameters in the assessment of the organic based ion exchange materials is its useful lifetime in the radioactive and chemical environment that will be encountered during waste processing. The focus of the work presented in this report is the radiation stability of the CS-100 and the RF resins. The scope of the testing included one test with a sample of the CS-100 resin and testing of two batches of the RF resin (BSC-187 and BSC-210). Samples of the exchangers were irradiated with a {sup 60}Co ...
1995-09-01
Energy Technology Data Exchange (ETDEWEB)
A new series of heteroleptic cyclometalated platinum(II) complexes Pt-1a-f was synthesized, employing 2-arylpyridine (or 1-arylisoquinoline) (HC{sup L}AMDAN-1) and 1,3-bis(3,4-dibutoxyphenyl)propane-1,3-dione (HO{sup L}AMDAO-1) for cyclometalation and as ancillary ligands, respectively, and photoluminescent properties were investigated. Focusing on red-shifted phosphorescence, C{sup L}AMDAN ligands containing pi-extended aromatics and electron-rich heterocycles were examined. All obtained complexes exhibited photoluminescence at ambient temperature, and the emission maxima ranged from green (lambda{sub PL}=518 nm) to far red (lambda{sub PL}=708 nm). The large Stokes shifts of more than 100 nm and sub-microsecond or microsecond emission lifetimes revealed that these complexes are phosphorescent emissive. The quantum yield of Pt-1 ranged from 0.02 to 0.59 at ambient temperature and decreased as the emission maximum was red-shifted. In comparison with the reference ...
2010-02-15
International Nuclear Information System (INIS)
A new dirhenium(I) complex fac-[{Re(CO)3(4,7-dinonadecyl-1,10-phenanthro -line)}2 (4,4'-bipyridyl)] (trifluoromethanesulfonate)2 (denoted as D-Re(I) ) is assembled in MCM-41 and SBA-15 type mesoporous silica support. The emission peaks of D-Re(I) in D-Re(I)/MCM-41 and D-Re(I)/SBA-15 are observed at 522 and 517 nm, respectively. Their long excited lifetimes, which are of the order of microseconds, indicate the presence of phosphorescence emission arising from the metal to ligand charge-transfer (MLCT) transition. The luminescence intensities of D-Re(I)/MCM-41 and D-Re(I)/SBA-15 decrease remarkably with increase in the oxygen concentration, meaning that they can be used as optical oxygen sensing materials based on luminescence quenching. The ratios I0/I100 of D-Re(I)/MCM-41 and D-Re(I)/SBA-15 are estimated to be 5.6 and 20.1, respectively. The obtained Stern-Volmer oxygen quenching plots of the mesoporous sensing materials could be fitted well to the two-site Demas ...
2011-04-01
Nature Of Tube Degradation In Horizontal Steam Generators
Energy Technology Data Exchange (ETDEWEB)
Nature of tube degradation was studied in support of horizontal steam generator lifetime calculations. Experiments were carried out to evaluate the resistance to environmentally assisted cracking (EAC) of steam generator tubes during operation. Estimations of the incubation period for crack initiation and the threshold K value, K(ISCC), and the crack growth rate were made to predict evolution of damage in tube walls. Experimental results were compared with in-service inspections experience. The paper summarizes results of experiments of C ring specimen for the initiation testing and results of SENT (single edge notch tensile) specimen for the crack growth rate (CGR) testing. The specimens were exposed to concentrated environments at elevated temperatures simulating crevice environments in secondary side crevices in horizontal steam generators. The results show that material of SG (steam generator) tubes is sensitive to transgranular environmentally assisted ...
2002-07-01
Nature Of Tube Degradation In Horizontal Steam Generators
International Nuclear Information System (INIS)
Nature of tube degradation was studied in support of horizontal steam generator lifetime calculations. Experiments were carried out to evaluate the resistance to environmentally assisted cracking (EAC) of steam generator tubes during operation. Estimations of the incubation period for crack initiation and the threshold K value, K(ISCC), and the crack growth rate were made to predict evolution of damage in tube walls. Experimental results were compared with in-service inspections experience. The paper summarizes results of experiments of C ring specimen for the initiation testing and results of SENT (single edge notch tensile) specimen for the crack growth rate (CGR) testing. The specimens were exposed to concentrated environments at elevated temperatures simulating crevice environments in secondary side crevices in horizontal steam generators. The results show that material of SG (steam generator) tubes is sensitive to transgranular environmentally assisted ...
2002-09-23
NPOESS Interface Data Processing Segment (IDPS) Hardware
The National Oceanic and Atmospheric Administration (NOAA), Department of Defense (DoD), and National Aeronautics and Space Administration (NASA) are jointly acquiring the next-generation weather and environmental satellite system; the National Polar-orbiting Operational Environmental Satellite System (NPOESS). NPOESS replaces the current Polar-orbiting Operational Environmental Satellites (POES) managed by NOAA and the Defense Meteorological Satellite Program (DMSP) managed by the DoD. The NPOESS satellites carry a suite of sensors that collect meteorological, oceanographic, climatological, and solar-geophysical observations of the earth, atmosphere, and space. The NPOESS design allows centralized mission management and delivers high quality environmental products to military, civil and scientific users. The ground data processing segment for NPOESS is the Interface Data Processing Segment (IDPS), developed by Raytheon Intelligence and Information Systems. IDPS processes NPOESS ...
2008-12-01
International Nuclear Information System (INIS)
Brachytherapy refers to short distance treatment of cancer with radiation from small, encapsulated radionuclide sources. This type of treatment is given by placing sources directly into or near the volume to be treated. The dose is then delivered continuously, either over a short period of time (temporary implants) or over the lifetime of the source to a complete decay (permanent implants). This technique is extensively used in the treatments of gynecological, breast, prostate, head and neck, and other soft tissue cancers. The clinical outcomes of this treatment depend on accurate dosimetry and dose delivery. The patient is generally considered to be water equivalent. So the treatment planning system software generally is based on measured or calculated dose distributions in homogenous water medium. In real situation, the treatment volume is not homogenous water medium, but it is a heterogeneous medium consisting of bone, soft tissue, lung, air etc. For better ...
2009-04-01
Maximum imaging depth of two-photon autofluorescence microscopy in epithelial tissues
Endogenous fluorescence provides morphological, spectral, and lifetime contrast that can indicate disease states in tissues. Previous studies have demonstrated that two-photon autofluorescence microscopy (2PAM) can be used for noninvasive, three-dimensional imaging of epithelial tissues down to approximately 150 ?m beneath the skin surface. We report ex-vivo 2PAM images of epithelial tissue from a human tongue biopsy down to 370 ?m below the surface. At greater than 320 ?m deep, the fluorescence generated outside the focal volume degrades the image contrast to below one. We demonstrate that these imaging depths can be reached with 160 mW of laser power (2-nJ per pulse) from a conventional 80-MHz repetition rate ultrafast laser oscillator. To better understand the maximum imaging depths that we can achieve in epithelial tissues, we studied image contrast as a function of depth in tissue phantoms with a range of relevant optical properties. The phantom data agree ...
2011-02-01
Mapping Strain in Nanocrystalline Nitinol: an X-ray Diffraction Method (SULI paper)
Energy Technology Data Exchange (ETDEWEB)
Understanding the mechanical properties of biomedical devices is critical in predicting and preventing their failure in the body. Such knowledge is essential, for example, in the design of biomedical stents, which must undergo repeated strain over their ten year lifetimes without breaking. Computational models are used to predict mechanical response of a device, but these models are not complete; there are significant deviations from the predictions, especially when devices are subjected to repeated multi-axial loads. Improving these models requires comparisons with actual measurements of strained nitinol. Local measurements of the full strain tensor can be made using X-ray diffraction techniques, but they are currently limited to materials whose grain size is larger than the X-ray beam size or require several diffraction patterns produced by rotation of the sample. Nitinol stents are nanocrystalline, with grains smaller than any available X-ray beam. We present a ...
2006-01-04
Magnetic moments of "1"7"7Ta apd sup(181,182,187)Re states
International Nuclear Information System (INIS)
The magnetic moments of "1"7"7Ta and sup(181,182,187)Re levels decaying via the K-forbidden transitions are measured. The nuclei studied are produced via the "1"7"7W and sup(181,182)Os and "1"8"7W #beta#-decay respectively. The magnetic moments have been measured using the method of the differential #gamma##gamma# angular correlations, perturbed by an external magnetic field. The following magnetic moments and lifetimes are obtained: for the 5/2"-1/2"-[541] "1"8"1Re level with excitation energy of 357 keV #mu#/#mu#sub(n)=2.00+-0.10, Tsub(1/2)=(76+-8)x10sup(-8) s; for the 186.4 keV 5/2"-1/2"-[541] "1"7"7Ta level #mu#/#mu#sub(n)=2.02+-0.13, Tsub(1/2)=(2.78+-0.09)x10sup(-6) s; for the 236 keV 2"- "1"8"2Re level #mu#/#mu#sub(n)=2.12+-0.08; for the 203 keV 9/2"- [514] "1"8"7Re level #mu#/#mu#sub(n)=5.04+-0.09.
1978-03-01
International Nuclear Information System (INIS)
?-Y(IO3)3 and ?-Y(IO3)3 are transparent until 12.8 and 13.4 ?m, respectively; thus they are interesting as a potential laser matrix in the mid- and beginning of the far-infrared. So, in order to investigate the properties of lanthanides- doped anhydrous yttrium iodate, polycrystalline samples of ?-Y1-xNdx(IO3)3 (0.01?x?0.05), ?-Y1-xNdx(IO3)3 (0.001?x?0.1), ?-Y1-xYbx(IO3)3 (0.01?x?0.33) and ?-Y1-xYbx(IO3)3 (0.01?x?0.25) were synthesized. For Nd3+ ions, fluorescent emissions from the 4F3/2 multiplet were observed at 300 K under pulsed laser excitations at 750 nm and for Yb3+, fluorescent emissions from the 2F5/2 multiplet were observed at 300 K under pulsed laser excitations at 980 nm. The decays of all these emissions were measured. They are exponential and the fluorescence lifetimes are in the range 0.093-0.193 ms for Nd3+ and 0.370-0.541 ms for Yb3+, depending on the nature of the host and the concentration of doping.
2009-03-01
Load-carrying capabilities of refractory alloys for space reactor power applications
International Nuclear Information System (INIS)
To achieve sufficient thermodynamic efficiency, space nuclear power systems must operate above 1000"0C. A quantitative evaluation of the existing mechanical properties data for the refractory alloys relevant to space nuclear power systems design lifetimes up to seven years at temperatures up to 1400"0C is being conducted. The most important properties for space nuclear power systems are long-term high-temperature (>1000"0C) creep strength and ductility, low-temperature (<400"0C) fracture toughness [including ductile-to-brittle transition temperature, (DBTT)], and ductility at high strain rates; of special concern are the above properties for weldments of refractory alloys, composition, applied stress, test temperature, test environment (e.g., vacuum, lithium), and thermomechanical treatment (TMT) history. Currently being evaluated are, in order of ascending mp, selected alloys of niobium (e.g., Nb-1% Zr, Nb-1% Zr-0.1% C), molybdenum (e.g., Mo-13% Re), ...
1985-01-14
Load-carrying capabilities of refractory alloys for space reactor power applications
Energy Technology Data Exchange (ETDEWEB)
To achieve sufficient thermodynamic efficiency, space nuclear power systems must operate above 1000/sup 0/C. A quantitative evaluation of the existing mechanical properties data for the refractory alloys relevant to space nuclear power systems design lifetimes up to seven years at temperatures up to 1400/sup 0/C is being conducted. The most important properties for space nuclear power systems are long-term high-temperature (>1000/sup 0/C) creep strength and ductility, low-temperature (<400/sup 0/C) fracture toughness (including ductile-to-brittle transition temperature, (DBTT)), and ductility at high strain rates; of special concern are the above properties for weldments of refractory alloys, composition, applied stress, test temperature, test environment (e.g., vacuum, lithium), and thermomechanical treatment (TMT) history. Currently being evaluated are, in order of ascending mp, selected alloys of niobium (e.g., Nb-1% Zr, Nb-1% Zr-0.1% C), molybdenum (e.g., ...
1985-01-01
Liquid radwaste processing with spiral wound reverse osmosis
International Nuclear Information System (INIS)
Two different reverse osmosis systems were investigated. The first was a 50-element plant-scale system that is used to treat 2200 m"3 of AECL liquid radwastes annually.It uses thin-film composite (TFC) membranes and operates at an applied pressure of 2760 kPa, with a fixed crossflow of about 40 L/min. The other system uses the same thin-film composite membranes for waste processing but is a two-element pilot-scale system. It is operated at pressures m ranging between 1500 and 7000 kPa, at a fixed crossflow of 55 L/min. The average lifetime of the thin-film composite membranes in the plant-scale processing application at AECL is about 3000 h. After this service life has expired the rejection efficiency declines rapidly from 99.5% to about 95% as the membranes become impaired from chemical cleaning procedures that are required after each 100 m"3 of waste is treated. The permeation flux for the plant-scale system decreases from about 2.2 L/min/element to below 0.5 ...
1996-02-25
Energy Technology Data Exchange (ETDEWEB)
A study has been made of the reaction [sup 86]Kr + [sup 63]Cu at incident energies of 486, 550, 640, and 730 MeV. Measurements include cross sections, angular distributions, and energy spectra for light charged particles ([sup 1,2,3]H and [sup 4]He), intermediate mass fragments (IMF) (4 [le] Z [le] 17), and heavy fragments (Z [ge] 18). Coincidences between light charged particles and between particles and fragments have been measured to obtain cross sections, energy spectra, and angular distributions. Statistical model analysis of the energy spectra for [sup 1]H and [sup 4]He detected in coincidence with the fragments has allowed estimation of [sup 1]H and [sup 4]He multiplicities associated with the evaporation residues, fragments, and composite nuclei prior to scission. A comparison of cross sections, energy spectra, angular distributions, and particle multiplicities for these matched entrance channels has provided the means for a detailed test of the Bohr Independence Hypothesis. ...
1992-01-01
International Nuclear Information System (INIS)
Norway is a member of Annex 29, 'Ground-Source Heat Pump Systems Overcoming Technical and Market Barriers' (2004-2006), organized under the umbrella of the International Energy Agency (IEA) and the IEA Heat Pump Programme (HPP). The 7 participating countries are Austria (Operating Agent), Canada, Japan, Norway, Spain, Sweden and the USA. The Norwegian participation is financed by ENOVA SF, and SINTEF Energy Research is responsible for planning and carrying out the Norwegian activities. This report provides a status for ground-source heat pump (GSHP) systems in Norway with regard to state-of-the-art technology, installation examples, geological data, costs and market opportunities. A Norwegian Internet home page for ground-source heat pump systems (www.energy.sintef.no/prosjekt/Annex29) is also presented. GSHP systems in Norway are classified as direct systems (groundwater and soil/ground) and indirect closed-loop systems (vertical-rock and horizontal-soil/ground). The vast majority of ...
High-speed surface temperature measurements on plasma facing materials for fusion applications
International Nuclear Information System (INIS)
For the lifetime evaluation of plasma facing materials in fusion experimental machines, it is essential to investigate their surface behavior and their temperature responses during an off-normal event such as the plasma disruptions. An infrared thermometer with a sampling speed as fast as 1x10"-"6 s/data, namely, the high-speed infrared thermometer (HSIR), has been developed by the National Research Laboratory of Metrology in Japan. To evaluate an applicability of the newly developed HSIR on the surface temperature measurement of plasma facing materials, high heat flux beam irradiation experiments have been performed with three different materials under the surface heat fluxes up to 170 MW/m"2 for 0.04 s in a hydrogen ion beam test facility at the Japan Atomic Energy Research Institute. As for the results, HSIR can be applicable for measuring the surface temperature responses of the armor tile materials with a little modification. It is also confirmed that surface ...
Hawaii demand-side management resource assessment. Final report: DSM opportunity report
Energy Technology Data Exchange (ETDEWEB)
The Hawaii Demand-Side Management Resource Assessment was the fourth of seven projects in the Hawaii Energy Strategy (HES) program. HES was designed by the Department of Business, Economic Development, and Tourism (DBEDT) to produce an integrated energy strategy for the State of Hawaii. The purpose of Project 4 was to develop a comprehensive assessment of Hawaii`s demand-side management (DSM) resources. To meet this objective, the project was divided into two phases. The first phase included development of a DSM technology database and the identification of Hawaii commercial building characteristics through on-site audits. These Phase 1 products were then used in Phase 2 to identify expected energy impacts from DSM measures in typical residential and commercial buildings in Hawaii. The building energy simulation model DOE-2.1E was utilized to identify the DSM energy impacts. More detailed information on the typical buildings and the DOE-2.1E modeling effort is available in Reference ...
1995-08-01
Energy Technology Data Exchange (ETDEWEB)
This thesis is concerned with the crystallisation behaviour of polymers near to a free surface or a buried interface. The properties of polymers are expected to differ significantly near to an interface (either with air or another polymer), due to the contributions of (a) chain configurations induced at the interface, and (b) different mobilities between interfacial regions and the bulk of the sample. For a semi-crystalline polymer, properties such as the degree of crystallinity and the crystallisation kinetics may be enhanced near to a free surface. Grazing incidence x--ray diffraction (GIXD) is used to investigate such effects in poly(ethylene terphthalate) (PET), showing that a lower crystallisation temperature is obtained at the surface, and the crystallisation kinetics are faster at the surface for all temperatures. It is proposed that in thin films of PET, this surface-induced ordering provides nucleation sites for crystallisation in the bulk. GIXD is also used to investigate the ...
2002-07-01
Formation of the natural sulfate aerosol
Energy Technology Data Exchange (ETDEWEB)
Anthropogenic sulfate aerosol, together with particles from biomass burning, may significantly reduce the climatic warming due to man-made greenhouse gases. The radiative forcing of aerosol particles is based on their ability to scatter and absorb solar radiation (direct effect), and on their influences on cloud albedos and lifetimes (indirect effect). The direct aerosol effect depends strongly on the size, number and chemical composition of particles, being greatest for particles of 0.1-1 {mu}m in diameter. The indirect aerosol effect is dictated by the number of particles being able to act as cloud condensation nuclei (CCN). For sulfate particles, the minimum CCN size in tropospheric clouds is of the order of 0.05-0.2 {mu}m. To improve aerosol parameterizations in future climate models, it is required that (1) both primary and secondary sources of various particle types will be characterized at a greater accuracy, and (2) the influences of various atmospheric ...
1996-12-31
International Nuclear Information System (INIS)
This report summarizes work performed by Argonne National Laboratory (ANL) on fatigue and environmentally assisted cracking (EAC) in light water reactors (LWRs) during the six months from October 1993 to March 1994. EAC and fatigue of piping, pressure vessels, and core components in LWRs are important concerns in operating plants and as extended reactor lifetimes are envisaged. Topics that have been investigated include (a) fatigue of low-alloy steel used in piping, steam generators, and reactor pressure vessels, (b) EAC of wrought and cast austenitic stainless steels (SSs), and (c) radiation-induced segregation and irradiation-assisted stress corrosion cracking (IASCC) of Type 304 SS after accumulation of relatively high fluence. Fatigue tests have been conducted on A302-Gr B low-alloy steel to verify whether the current predictions of modest decreases of fatigue life in simulated pressurized water reactor water are valid for high-sulfur heats that show ...
2007-09-01
Energy Technology Data Exchange (ETDEWEB)
Several technological alternatives have been studied taking into consideration that one of the biggest problems of the electric power companies is to provide electric power during the peak consumption periods, which largest contribution to the increase of the demand comes from the residential sector, especially by the use of electric showers. One of the most promising alternatives is the pre-water heating system for reduced power showers, developed by Universidade de Campinas and Companhia Paulista de Forca e Luz. The goal of this system is basically to reduce demand during the peak periods, in order to avoid heavy investments by the electric power companies in generation, transmission and distribution of electric power directed to low acquisitive power customers, a sector in which the electric power price is not enough to recover such investments. The objective of this paper is to evaluate the total energy required in the construction of one of these systems and compare it to the ...
1996-12-31
Effective stress of a 4.2 K beam tube in a quenching collider 50 mm dipole magnet for the SSC
Energy Technology Data Exchange (ETDEWEB)
Two mechanical design requirements are defined for the SSC Collider beam tube. First, the vacuum requirement (luminosity lifetime = 150 hrs). It requires the design of a pressure boundary within the cold mass vessel to provide a vacuum tunnel for the proton beam and to minimize the synchrotron radiation gas desorbtion with a suitable material. The Collider beam tube design is under an intensive activity to search for a material that will meet the luminosity requirement without a distributed pump or liner. Second is the tube wall`s resistivity requirement ({sigma}*t = 2E5 {Omega}{sup {minus}1}). For a 4.2 K beam tube the Cu thickness is 100 {mu}m (RRR=30,6.7 T, {sigma}=2E9{Omega}{sup {minus}1}m{sup {minus}1}). The copper yield strength is relatively low in comparison to steel and, therefore, the design of the steel layer is governed by the copper layer yield stress limit. A beam tube subjected to eddy current load in a quenching dipole requires an optimum diameter ...
1993-05-01
Effective stress of a 4. 2 K beam tube in a quenching collider 50 mm dipole magnet for the SSC
Energy Technology Data Exchange (ETDEWEB)
Two mechanical design requirements are defined for the SSC Collider beam tube. First, the vacuum requirement (luminosity lifetime = 150 hrs). It requires the design of a pressure boundary within the cold mass vessel to provide a vacuum tunnel for the proton beam and to minimize the synchrotron radiation gas desorbtion with a suitable material. The Collider beam tube design is under an intensive activity to search for a material that will meet the luminosity requirement without a distributed pump or liner. Second is the tube wall's resistivity requirement ([sigma]*t = 2E5 [Omega][sup [minus]1]). For a 4.2 K beam tube the Cu thickness is 100 [mu]m (RRR=30,6.7 T, [sigma]=2E9[Omega][sup [minus]1]m[sup [minus]1]). The copper yield strength is relatively low in comparison to steel and, therefore, the design of the steel layer is governed by the copper layer yield stress limit. A beam tube subjected to eddy current load in a quenching dipole requires an optimum ...
1993-05-01
Effect of neutron irradiation on DHC velocity at CANDU Zr-2.5Nb pressure tube
Energy Technology Data Exchange (ETDEWEB)
The objective of this study is to evaluate the lifetime of Zr-2.5Nb pressure tube at Wolsung Unit-1. The testing materials (Effective full power year: 9.3 year, Accumulated nuetron fluence: 7.66{approx}8.91 x 1025 n/m{sup 2}) were sampled from M-11 tube at various position(inlet, middle and outlet). The cutting was carried out at hot cell to fabricate CT(Compact tension) specimen with 48 ppm hydrogen content. In the result of DHC test, irradiation-damaged specimen showed 4{approx}6 times faster DHC velocity(5.298E-0.8{approx}7.039E-8 m/s: 182 .deg. C) than non-irradiated specimen. These DHCV results also show slight faster than one of specimen from Pickering plant (average DHCV: 4.5E-8 m/s: 182 .Deg C). This faster DHCV can be explained with the fact that Wolsung Unit-1 have been operated in a severe conditions(higher cooling water temperature, high power and efficiency) than Pickering one. The striation spacing which was seen DHC fracture surface at irradiated ...
2003-10-01
Effect of neutron irradiation on DHC velocity at CANDU Zr-2.5Nb pressure tube
International Nuclear Information System (INIS)
The objective of this study is to evaluate the lifetime of Zr-2.5Nb pressure tube at Wolsung Unit-1. The testing materials (Effective full power year: 9.3 year, Accumulated nuetron fluence: 7.66#approx#8.91 x 1025 n/m"2) were sampled from M-11 tube at various position(inlet, middle and outlet). The cutting was carried out at hot cell to fabricate CT(Compact tension) specimen with 48 ppm hydrogen content. In the result of DHC test, irradiation-damaged specimen showed 4#approx#6 times faster DHC velocity(5.298E-0.8#approx#7.039E-8 m/s: 182 .deg. C) than non-irradiated specimen. These DHCV results also show slight faster than one of specimen from Pickering plant (average DHCV: 4.5E-8 m/s: 182 .Deg C). This faster DHCV can be explained with the fact that Wolsung Unit-1 have been operated in a severe conditions(higher cooling water temperature, high power and efficiency) than Pickering one. The striation spacing which was seen DHC fracture surface at irradiated specimen ...
2003-10-01
Energy Technology Data Exchange (ETDEWEB)
The Alloy 800 tubes used in CANDU 6 steam generators have not experienced significant corrosion damage to date, which may be attributed to successful water chemistry control strategies. However, it is known that Alloy 800, like other steam generator (SG) tubing materials, is not immune to corrosion, especially pitting, under some plausible but off-specification operating scenarios. Electrochemical measurements provide information on corrosion susceptibility and rate, which are known to be a function of water chemistry. Using laboratory data in combination with chemistry monitoring and diagnostic software it is possible to assess the impact of plant operating conditions on SG tube corrosion for plant life management (PLIM). In this context, this paper discusses the results of electrochemical measurements made to elucidate the corrosion behaviour of Alloy 800 SG tubes under conditions simulating those plausible in SG crevices. In addition to crevice pH, the influence of PbO, acting alone ...
2001-09-01
Economic evaluation of dual purpose desalination plants by fuel type in Korea
Energy Technology Data Exchange (ETDEWEB)
In light of the recent rapid increase in the fossil fuel prices it is meaningful to evaluate the impact of these price changes in the economics of dual-purpose desalination projects producing electricity and fresh water simultaneously. The price of crude oil and LNG (Liquefied Natural Gas) has increased by about 200% and 100% during the past three or four years. The uranium price has also increased by nearly 500% during the same period. The purpose of this paper is to analyze and compare the economics of SMART (System-integrated Modular Advanced ReacTor) which is being developed as a small size PWR type and the LNG Combine Cycle coupled with MED (Multi-Effect Distillation) which are being acknowledged as promising energy sources for the future in Korea. The methods of analysis used in this paper are the lifetime leveled cost method for the power and water cost calculation and the power credit method for the total cost allocation. DEEP (Devaluation Economic ...
2007-07-01
Economic evaluation of dual purpose desalination plants by fuel type in Korea
International Nuclear Information System (INIS)
In light of the recent rapid increase in the fossil fuel prices it is meaningful to evaluate the impact of these price changes in the economics of dual-purpose desalination projects producing electricity and fresh water simultaneously. The price of crude oil and LNG (Liquefied Natural Gas) has increased by about 200% and 100% during the past three or four years. The uranium price has also increased by nearly 500% during the same period. The purpose of this paper is to analyze and compare the economics of SMART (System-integrated Modular Advanced ReacTor) which is being developed as a small size PWR type and the LNG Combine Cycle coupled with MED (Multi-Effect Distillation) which are being acknowledged as promising energy sources for the future in Korea. The methods of analysis used in this paper are the lifetime leveled cost method for the power and water cost calculation and the power credit method for the total cost allocation. DEEP (Devaluation Economic ...
2007-05-13
Development of next-generation light water reactor in Japan
International Nuclear Information System (INIS)
In Japan, the development of next-generation Light Water Reactor has been launched since April 2008. The development program will be completed in 2015. The purpose of development is to cope with the replacement for existing nuclear power plants after 2030 in Japan and the expanding demand for nuclear power in the world; 'Nuclear Renaissance.' The reactor also aims to be global standard at around 2030. The requirements for global standard and domestic users have been investigated through the feasibility study of past 2 years, 2006-2007, and six innovative features or 'Core-Concepts' were established as follows. A) Reactor core system with uranium enrichment above 5% for significant decrease of spent fuel discharge and prominent higher availability B) Long-life materials and innovative water chemistry technologies for 80 years plant lifetime and significant reduction of occupational dose C) Seismic isolation technologies to standardize plant design independent from ...
2009-10-27
International Nuclear Information System (INIS)
In order to predict or to evaluate the structural reliability of a variety of nuclear components under actual changing operating conditions, it is necessary to take the detailed geometrical features of components into consideration on one hand, and thermo-mechanical loading conditions with space and time variations during the lifetime, on the other hand. This consideration leads the authors to develop a super large-scale structural analysis program based on a parallel computational FEM with a variable scale of PC cluster architecture, whose prototype system is presented in a companion paper in this Symposium. Development of the PC cluster technology is one of the most important subjects in large-scale structural simulation, reducing computer costs and thus making simulation more acceptable to the engineering community. This paper presents the developmental status of the parallel FEM solver, demonstrating computational capabilities with three dimensional effects ...
2000-09-01
The commercial solid phase microextraction (SPME) fibers are not stable enough in organic solvent and tend to swell and strip off from the silica fiber in the high performance liquid chromatography (HPLC) mobile phase, and therefore the application of SPME coupled online with HPLC is limited. In this study, an SPME fiber coated with single walled carbon nanotubes (SWCNTs), prepared by means of electrophoretic deposition, was coupled on line to HPLC for the determination of four endocrine-disrupting compounds, i.e. bisphenol A (BPA), estrone (E(1)), 17?-ethynylestradiol (EE(2)) and octylphenol (OP), in aqueous samples. The results showed that the SWCNTs coating on the prepared fiber did not swell and strip off from the platinum fiber throughout the experiment, thus indicating a high resistance to the HPLC mobile phase, the mixture of water and acetonitrile. The SWCNTs fiber had similar (for OP) or higher (for BPA, EE(2) and E(1)) extraction efficiencies than the commonly used ...
2011-07-27
Energy Technology Data Exchange (ETDEWEB)
This thesis examines the design of a propulsion system for a series hybrid vehicle and includes the study of an energy storage unit using double-layer capacitors and a lightweight soft-switched converter system, and two new components in series hybrid vehicles. The development of environmentally sustainable vehicles is more urgent now given the fact that pollution levels are ever increasing. No electric vehicle has yet been developed that can compete with a normal vehicle based only on internal combustion engines. The dilemma lies in the difficulty of storing the amount of energy needed and supply it a high power levels. An attractive and viable option to reducing pollution and maintaining good performance may lie in hybrid electric-powered vehicles. The double-layer power capacitors are an interesting option because of their high power density and long lifetime. The devices are new and assembling large energy storage units must be thoroughly examined before using ...
2001-07-01
Crystal structure of ABPO{sub 5} and optical study of Pr{sup 3+} embedded in these compounds
Energy Technology Data Exchange (ETDEWEB)
The crystal structure of borophosphates ABPO{sub 5} (A = alkaline earth or Pb) was resolved on a polycrystalline sample using the Rietveld method. The x-ray diffraction patterns data show that ABPO{sub 5} crystallize in a centrosymmetric space group P3{sub 1}21 and their structure is related to the borogermanates REBGeO{sub 5} with a stillwellite-type structure. Pr{sup 3+} ion was used as a local structural probe to corroborate the structural resolution results. Absorption and fluorescence spectra of A{sub 1-x}Pr{sub x}BP{sub 1-x}Ge{sub x}O{sub 5} (A alkaline earth or Pb; x = 0.05) have been investigated at different temperatures. At 9 K the 3{sup H}{sub 4}{yields}{sup 3}P{sub 0} transition of trivalent praseodymium ion (4f{sup 2} configuration) is observed as a single line. This indicates a unique crystallographic site for the rare earth ion in these compounds replacing the divalent cation. Energy level schemes were deduced from the low-temperature spectroscopic measurements. ...
2001-10-22
Crystal structure of ABPO_5 and optical study of Pr"3"+ embedded in these compounds
International Nuclear Information System (INIS)
The crystal structure of borophosphates ABPO_5 (A = alkaline earth or Pb) was resolved on a polycrystalline sample using the Rietveld method. The x-ray diffraction patterns data show that ABPO_5 crystallize in a centrosymmetric space group P3_121 and their structure is related to the borogermanates REBGeO_5 with a stillwellite-type structure. Pr"3"+ ion was used as a local structural probe to corroborate the structural resolution results. Absorption and fluorescence spectra of A_1_-_xPr_xBP_1_-_xGe_xO_5 (A alkaline earth or Pb; x = 0.05) have been investigated at different temperatures. At 9 K the 3"H_4#->#"3P_0 transition of trivalent praseodymium ion (4f"2 configuration) is observed as a single line. This indicates a unique crystallographic site for the rare earth ion in these compounds replacing the divalent cation. Energy level schemes were deduced from the low-temperature spectroscopic measurements. Comparing the electronic level splittings of studied compounds with the already ...
2001-10-22
Crack growth in welded turbine materials at elevated temperatures
International Nuclear Information System (INIS)
Due to thermal gradients and load changes steam-turbine casings suffer combined creep-fatigue loading. Creep and fatigue portions depend on service conditions. Special interest is focused on the behaviour of creep-fatigue cracks, originated from potential defects due to construction and manufacturing weldments, on residual lifetime assessment. The project deals with the crack-growth behaviour at 530deg C and r.t. of welded and unwelded heat-resistant cast steels: 1% CrMoV-cast (GS-17 CrMoV 5 11, two melts: low and high V-content) and 12% CrMoV-cast (G-X 22 CrMoV 12 1). The crack planes of CT-specimens investigated, taken from manual arc-welded plates, were situated in the heat-affected zone (HAZ). The fatigue, creep and combined creep-fatigue crack-growth behaviour was investigated by means of low-frequency (0.5 and 0.05 Hz) tests, holding-time (20 min) tests and constant load tests up to about 5 000 h. Metallographic investigations show that in the case of both 1% ...
1989-12-01
Computational fluid dynamic analysis of core bypass flow phenomena in a prismatic VHTR
International Nuclear Information System (INIS)
The core bypass flow in a prismatic very high temperature reactor (VHTR) is an important design consideration and can have considerable impact on the condition of reactor core internals including fuels. The interstitial gaps are an inherent presence in the reactor core because of tolerances in manufacturing the blocks and the inexact nature of their installation. Furthermore, the geometry of the graphite blocks changes over the lifetime of the reactor because of thermal expansion and irradiation damage. The occurrence of hot spots in the core and lower plenum and hot streaking in the lower plenum (regions of very hot gas flow) are affected by bypass flow. In the present study, three-dimensional computational fluid dynamic (CFD) calculations of a typical prismatic VHTR are conducted to better understand bypass flow phenomena and establish an evaluation method for the reactor core using the commercial CFD code FLUENT. Parametric calculations changing several factors ...
2010-09-01
Computational Fluid Dynamic Analysis of Core Bypass Flow Phenomena in a Prismatic VHTR
Energy Technology Data Exchange (ETDEWEB)
The core bypass flow in a prismatic very high temperature gas-cooled reactor (VHTR) is one of the important design considerations which impacts considerably on the integrity of reactor core internals including operating fuels. The interstitial gaps are an inherent presence in the reactor core because of tolerances in manufacturing the blocks and the inexact nature of their installation. Furthermore, the geometry of the graphite blocks changes over the lifetime of the reactor because of thermal expansion and irradiation damage. The occurrence of hot spots in the core and lower plenum and hot streaking in the lower plenum (regions of very hot gas flow) will be affected by the bypass flow. In the present study, three-dimensional computational fluid dynamic (CFD) calculations of a typical prismatic VHTR are conducted to understand better the bypass flow phenomenon and establish the evaluation method in the reactor core using commercial CFD code FLUENT. Parametric ...
2010-09-01
Energy Technology Data Exchange (ETDEWEB)
Molten salt oxidation (MSO) is proposed as a {sup 238}Pu waste treatment technology that should be developed for volume reduction and recovery of {sup 238}Pu and as an alternative to the transport and permanent disposal of {sup 238}Pu waste to the WIPP repository. In MSO technology, molten sodium carbonate salt at 800--900 C in a reaction vessel acts as a reaction media for wastes. The waste material is destroyed when injected into the molten salt, creating harmless carbon dioxide and steam and a small amount of ash in the spent salt. The spent salt can be treated using aqueous separation methods to reuse the salt and to recover 99.9% of the precious {sup 238}Pu that was in the waste. Tests of MSO technology have shown that the volume of combustible TRU waste can be reduced by a factor of at least twenty. Using this factor the present inventory of 574 TRU drums of {sup 238}Pu contaminated wastes is reduced to 30 drums. Further {sup 238}Pu waste costs of $22 million are avoided from not ...
1998-05-01
Energy Technology Data Exchange (ETDEWEB)
The acid-base behavior of the ground and excited states of Pt(qdt){sub 2}{sup 2{minus}} and Pt(phen)(qdt), where qdt=quinoxaline-2,3-dithiolate and phen = 1,10-phenanthroline, has been studied. The pH-dependent changes in the charge-transfer absorption and emission spectra for both complexes are attributed to protonation of the quinoxalinedithiolate ligand at the imine nitrogen. For Pt(qdt){sub 2}{sup 2{minus}}, single protonation leads to a large red shift (2582 cm{sup {minus}1}) of the low-energy charge-transfer-to-dithiolate absorption band and the emergence of a new red-shifted emission feature at 728 nm. In solutions of pH below 6, a second protonation takes place at the other qdt ligand, yielding Pt-(Hqdt){sub 2}. This neutral complex has been isolated and characterized by {sup 1}H NMR spectroscopy and elemental analyses. The ground-state basicity constants of the two protonation steps have been determined from spectrophotometric titrations to be pK{sub b1} = 6.9 and pK{sub ...
1995-06-21
Accident analysis in research reactors
International Nuclear Information System (INIS)
Full text: Full text: The incomplete understanding of the complex mechanisms connected with the interaction between thermal-hydraulic and neutron kinetics still challenges the design and the operation of nuclear reactors and imposes the adoption of conservatism in the evaluation of safety limits. The recent availability of powerful computer and computational techniques together with the continuing increase in operational experience suggests the revisiting of those areas and the identification of design/operation requirements that can be relaxed. So far, almost all of the safety analyses of research reactors have been performed using conservative computational tools such as channel codes but, nowadays, the application of Best-Estimate (BE) methods constitutes a real necessity. The global aim of the current work is an attempt to apply the best-estimate system thermal-hydraulic code Relap5. For this purpose, the generic IAEA research reactor Benchmark problem is re-considered for proving ...
2006-10-15
A comparison study on activation safety of fusion, fission and hybrid reactor technology
Energy Technology Data Exchange (ETDEWEB)
The activation aspects of pure fusion and hybrid fusion technology is studied to assess the radioactive safety of various fusion concepts including tokamak pure fusion, fissile fuel producing hybrid and radio waste transmuting hybrid. The activation properties of breeding, coolant and structural materials in fusion reactors might be quite different from those in fission reactors because of the high energy D-T fusion neutrons from the fusion cores. A study on the involved activation reactions and the uncertainties of the associated nuclear cross-sections is carried. The activation properties of various first wall concepts and blanket concepts are discussed. The radioactive inventory during the operation lifetime and the potential hazard of the radioactive nuclides with respect to near term (reprocessing) and long term (waste disposal) aspects are calculated, with reference to ITER/NET (International Thermonuclear Experiment Reactor/Next European Torus), STARFIRE (a ...
1994-12-31
A comparison study on activation safety of fusion, fission and hybrid reactor technology
International Nuclear Information System (INIS)
The activation aspects of pure fusion and hybrid fusion technology is studied to assess the radioactive safety of various fusion concepts including tokamak pure fusion, fissile fuel producing hybrid and radio waste transmuting hybrid. The activation properties of breeding, coolant and structural materials in fusion reactors might be quite different from those in fission reactors because of the high energy D-T fusion neutrons from the fusion cores. A study on the involved activation reactions and the uncertainties of the associated nuclear cross-sections is carried. The activation properties of various first wall concepts and blanket concepts are discussed. The radioactive inventory during the operation lifetime and the potential hazard of the radioactive nuclides with respect to near term (reprocessing) and long term (waste disposal) aspects are calculated, with reference to ITER/NET (International Thermonuclear Experiment Reactor/Next European Torus), STARFIRE (a ...
XPS study of the passive films formed on nitrogen-implanted austenitic stainless steels
Energy Technology Data Exchange (ETDEWEB)
Austenitic stainless steels (304-type) have been implanted with nitrogen ions in order to investigate the effects of implanted nitrogen on their electrochemical behaviour and on the nature of the passive film formed on the steels in acid (0.5M H{sub 2}SO{sub 4}). Alloys with two nitrogen doses have been prepared (2.5x10{sup 16} and 2x10{sup 17} N atoms/cm{sup 2}). The implanted alloys have been characterized by {sup 15}N-NRA (nuclear reaction analysis) and XPS (X-ray photoelectron spectroscopy). Alloy surfaces with well-defined N concentrations were prepared, prior to the electrochemical measurements, by argon-ion sputtering of the implanted material for a fixed time in order to reach a well-defined point on the nitrogen depth profile. The samples were then transferred without exposure to air to an electrochemical cell mounted in an inert gas glove box. The implanted nitrogen modifies the electrochemical behaviour of the alloy. The anodic dissolution in the active state is enhanced, ...
1992-05-01
XPS study of the passive films formed on nitrogen-implanted austenitic stainless steels
International Nuclear Information System (INIS)
Austenitic stainless steels (304-type) have been implanted with nitrogen ions in order to investigate the effects of implanted nitrogen on their electrochemical behaviour and on the nature of the passive film formed on the steels in acid (0.5M H_2SO_4). Alloys with two nitrogen doses have been prepared (2.5x10"1"6 and 2x10"1"7 N atoms/cm"2). The implanted alloys have been characterized by "1"5N-NRA (nuclear reaction analysis) and XPS (X-ray photoelectron spectroscopy). Alloy surfaces with well-defined N concentrations were prepared, prior to the electrochemical measurements, by argon-ion sputtering of the implanted material for a fixed time in order to reach a well-defined point on the nitrogen depth profile. The samples were then transferred without exposure to air to an electrochemical cell mounted in an inert gas glove box. The implanted nitrogen modifies the electrochemical behaviour of the alloy. The anodic dissolution in the active state is enhanced, and the current density in ...
1992-01-01
Polycrystalline powders of Na{sub 2x}Mn{sub 1-x}PS{sub 3} have been synthesized from layered MnPS{sub 3} material by successive ion-exchange intercalation of potassium and sodium ions. Their x-ray photoelectron spectroscopy (XPS) and x-ray excited Auger spectroscopy spectra have been measured at room temperature using Mg K{alpha} (1253.6 eV) x-ray source. In particular, the Mn, P, and S 2p and Na 1s and 2p core-level regions and the Na Auger KL{sub 23}L{sub 23} transition have been investigated. All the analyzed XPS core-level spectra display a single-peak structure, suggesting the absence of nonequivalent atoms of Na, Mn, P, and S. The manganese XPS spectrum shows, as observed in MnPS{sub 3} and in its cesium and potassium intercalation compounds, typical shake-up satellites, suggesting that the Mn-S bond is yet mainly ionic in nature. The comparison with the XPS spectra relative to MnPS{sub 3} and its potassium intercalation compound (K{sub ...
2008-12-15
The effects of energy non-monochromaticity of "1"1B ion beams on "1"1B diffusion
International Nuclear Information System (INIS)
We have shown that energy contamination introduced by ion beam deceleration technology that is used to increase the beam currents available for low energy boron implants, can affect fabricated junctions adversely. A 4 keV "1"1B beam is extracted and retarded by a potential of -3.5 keV for 0.5 keV "1"1B implantation, or by a potential of -3.8 keV for 0.2 keV "1"1B implantation. Intentional beam contamination was introduced by turning off the retarding potential to allow the 4 keV "1"1B ions to irradiate Si wafers directly. The percentage of contamination, at levels of 0.1%, 0.2% and 0.3% was introduced. Rapid thermal annealing of all the implanted samples was performed under N_2 ambient at 1050 deg. C for 1 s. The dopant tail profiles themselves are not significant if the contamination levels are low. However, the much higher damage level coming from high energy contamination increases the transient enhanced diffusion of "1"1B more than ...
2005-08-01
The effects of a hydrogen pair in the electronic structure of the FCC iron containing a vacancy
Energy Technology Data Exchange (ETDEWEB)
Fuel cell vehicles have been identified as the personal transportation technology of the future because of their high efficiency and very low emissions. To achieve the goal of road-ready fuel cell vehicles, great strides must be made in the development of fuel cells, hydrogen production and hydrogen storage technologies, that includes metal-H interaction studies and safety considerations. The interaction between two-hydrogen atoms and a {gamma}-Fe structure containing a vacancy has been studied using a cluster model and a theoretical method. For the study of the sequential absorption, the hydrogen atoms were positioned in their energy minima configurations, near the vacancy. The interactions mainly involve Fe 4s-H 1s atomic orbitals. The contribution of Fe 4p and Fe 3d orbitals is much less important. The Fe-Fe bond is weakened as new Fe-H-H and H-H pairs were formed. The effect of H atoms is limited to its first Fe neighbors. The Fe-Fe bond ...
2010-06-15
International Nuclear Information System (INIS)
The new compounds In_3_._7Mo_1_5S_1_9, In_1_._6Rb_2Mo_1_5S_1_9, In_2_._2CsMo_1_5S_1_9, and ScTl_2Mo_1_5S_1_9 have been synthesized by solid-state reaction in sealed molybdenum crucible at about 1250 deg. C. Their crystal structures were solved and refined from X-ray single-crystal data in the hexagonal space group P63/m. Their Mo-S framework consists of an equal mixture of Mo_6S_8S_6 and Mo_9S_1_1S_6 cluster units interconnected through Mo-S bonds. In In_3_._7Mo_1_5S_1_9, the In atoms occupy crystallographically different positions depending on their formal oxidation states of +1 or +3. This was confirmed by replacing partially or totally the monovalent indium by another monovalent cation such as the rubidium, cesium or thallium and the trivalent indium by the scandium to get the new In_1_._6Rb_2Mo_1_5S_1_9, In_2_._2CsMo_1_5S_1_9, and ScTl_2Mo_1_5S_1_9 compounds, respectively.
2004-11-30
International Nuclear Information System (INIS)
The anodic reaction kinetics and interfacial mass transport of a direct polymer electrolyte membrane formic acid fuel cell have been investigated in an all solid-state electrochemical cell using a highly active nanostructured palladium-gold alloy microelectrode as an in situ probe. Well-defined 'S-shaped' steady-state cyclic voltammograms exhibiting current-rising region at lower overpotentials and limiting current region at higher overpotentials have been first obtained for the electrochemical oxidation of formic acid at varying temperature. The 'S-shaped' steady state polarization curves and chronoamperometric curves enable convenient measurements of the anodic reaction kinetics and interfacial mass transport of formic acid under real polymer electrolyte membrane conditions. It is encouragingly found that formic acid can be directly oxidized to CO2 with the first electron transfer being the likely rate-determining step and the formation of surface poison can be neglected. The ...
2009-07-30
ORALLOY (93.2 235U) METAL CYLINDER WITH BERYLLIUM TOP REFLECTOR
International Nuclear Information System (INIS)
A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, one experiment was comprised of a stack of approximately 7-inch-diameter metal discs. The bottom of the stack consisted of uranium with an approximate height of 4-1/8 inches. The top of the stack consisted of beryllium with an approximate height of 5-9/16 inches. This ...
Natural vegetation at the proposed Reference Repository Location in southeastern Washington
International Nuclear Information System (INIS)
The dominant shrubs were sagebrush and spiny hopsage; the herbs were dominated by cheatgrass and Sandberg bluegrass. Spiny hopsage appeared to be vulnerable to burning and also to damage by off-road vehicular traffic. It appears to have little or no ability to reproduce through seedlings; once the existing plants are killed they are not likely to be replaced, even if seed-producing plants are nearby. The only pure stand of spiny hopsage known to exist on the Hanford Site is on and near study plot 2H. Sagebrush, like spiny hopsage, is killed by burning and by heavy vehicles. Sagebrush is capable of reproducing via seeds, indicating that it is an inherently aggressive species with a capacity to reestablish itself if parent plants are in the vicinity to act as seed sources. Alien, annual plants, especially cheatgrass, were a major contributor to the herbaceous canopy cover in plots 3S, 4S, and 5S. However, native perennial grasses, especially Sandberg bluegrass, were a major contributor ...
Mechanistic studies of ethylene biosynthesis in higher plants
Energy Technology Data Exchange (ETDEWEB)
Ethylene is a plant hormone that elicits a wide variety of responses in plant tissue. Among these responses are the hastening of abscission, ripening and senescence. In 1979 it was discovered that 1-amino-1-cyclopropane carboxylic acid is the immediate biosynthetic precursor to ethylene. Given the obvious economic significance of ethylene production the authors concentrated their studies on the conversion of ACC to ethylene. They delved into mechanistic aspects of ACC oxidation and they studied potential inhibitors of ethylene forming enzyme (EFE). They synthesized various analogs of ACC and found that EFE shows good stereodiscrimination among alkyl substituted ACC analogs with the 1R, 2S stereoisomer being processed nine times faster than the 1S, 2R isomer in the MeACC series. They also synthesized 2-cyclopropyl ACC which is a good competitive inhibitor of EFE. This compound also causes time dependent loss of EFE activity leading us to believe ...
1986-01-01
Energy Technology Data Exchange (ETDEWEB)
Experimental studies on the heat transfer and fluid dynamics of a high heat flux fuel rod for a very high temperature reactor (VHTR) were performed using a single channel test rig of a fuel stack test section (T{sub 1-s}) installed in a helium engineering demonstration loop (HENDEL). The fuel rod has been developed in order to enhance the turbulent heat transfer coefficient than that of the standard fuel rod obtained by the previous experiment. Two-dimensional square ribs were settled on the outer surface of the fuel rod axially to improve the heat transfer. The configuration of a square rib is 0.5 mm in width(w), 0.5 mm in height(h) and 5 mm in pitch(p): p/h=10. The experiment were carried out under the helium gas conditions of high temperature and pressure simulated the VHTR operation. For the turbulent region of Reynolds number 2,500{approx}8,000 of the VHTR core flow condition, it was found that the heat transfer coefficient of the fuel rod ...
1991-10-01
Heat transfer and fluid dynamics of high heat flux fuel rod for VHTR
International Nuclear Information System (INIS)
Experimental studies on the heat transfer and fluid dynamics of a high heat flux fuel rod for a very high temperature reactor (VHTR) were performed using a single channel test rig of a fuel stack test section (T_1_-_s) installed in a helium engineering demonstration loop (HENDEL). The fuel rod has been developed in order to enhance the turbulent heat transfer coefficient than that of the standard fuel rod obtained by the previous experiment. Two-dimensional square ribs were settled on the outer surface of the fuel rod axially to improve the heat transfer. The configuration of a square rib is 0.5 mm in width(w), 0.5 mm in height(h) and 5 mm in pitch(p): p/h=10. The experiment were carried out under the helium gas conditions of high temperature and pressure simulated the VHTR operation. For the turbulent region of Reynolds number 2,500#approx#8,000 of the VHTR core flow condition, it was found that the heat transfer coefficient of the fuel rod ...
1991-01-01
Enhancement of electrical conductivity of ion-implanted polymer films
Energy Technology Data Exchange (ETDEWEB)
The electrical conductivity of ion-implanted films of Nylon 66, Polypropylene (PP), Poly(tetrafluoroethylene) (Teflon) and mainly Poly (ethylene terephthalate) (PET) was determined by DC measurements at voltages up to 4500 V and compared with the corresponding values of pristine films. Measurements were made at 21/sup 0/C +/- 1/sup 0/C and 65 +/- 2% RH. The electrical conductivity of PET films implanted with F/sup +/, Ar/sup +/, or As/sup +/ ions at energies of 50 keV increases by seven orders of magnitude as the fluence increases from 1 x 10/sup 18/ to 1 x 10/sup 20/ ions/m/sup 2/. The conductivity of films implanted with As/sup +/ was approximately one order greater than those implanted with Ar/sup +/, which in turn was approximately one-half order greater than those implanted with F/sup +/. The conductivity of the most conductive film approx.1 S/m) was almost 14 orders of magnitude greater than the pristine PET film. Except for the three PET ...
1985-01-01
Energy Technology Data Exchange (ETDEWEB)
Spin-polarized liquid helium-3 is prepared by laser optical pumping in low magnetic field and at room temperature, prior to fast liquefaction of the polarized sample. The use of a new helium-3 cryostat enabled us to obtain liquid helium-3 with polarization rates up to 25 % at well-stabilized temperatures (around 0.5 K). We could thereby study the effect of nuclear polarization on liquid-vapour equilibrium, and particularly on the saturated vapour pressure. Very sensitive capacitive gauges were developed. We estimated (to first order in M{sup 2}) the expected effects when the polarization M is suddenly destroyed. These effects were experimentally observed in helium-3/helium-4 mixtures, in pure helium-3, only a transient increase in pressure has been recorded. We then describe in a third part a preliminary experiment which aimed at determining the longitudinal relaxation time T1 in mixtures. Relaxation on the walls is efficiently reduced by a cesium coating and ...
1999-07-15
Energy Technology Data Exchange (ETDEWEB)
This paper discussed the lithological characteristics of tight gas reservoirs, including the diagenetic characteristics, diagenetic environment and diagenetic sequence. The link between porosity, the sedimentary environment, lithology, diagenesis and basin tectonics was examined in order to determine how tight reservoirs were formed. The study focused on the Changbei gas field located in Yishan Slope of the Ordos Basin in China. The main pay zone reservoir is the Upper Paleozoic Lower Permian Shanxi sandstone which lies at a depth of 2700-2950 m. This low porosity, low permeability tight gas reservoir was deposited in a coal bearing acid environment which controlled the diagenesis sequence. The early carbonate cement was not well developed because the original pore water was acidic with non saturated calcium carbonate. However, compaction has significantly reduced the original pore and pore volume. The acidic environment caused large amounts of secondary quartz cementation to fill the ...
2010-07-01
Energy Technology Data Exchange (ETDEWEB)
In the investigations reported here, a helium-jet/tape-transport system was used for the rapid transfer of fission products to a low-background environment where their aggregate beta and gamma-ray spectra were measured as a function of delay time after neutron induced fission of {sup 235}U, {sup 238}U and {sup 239}Pu. Beta and gamma-ray energy distributions have been deduced for delay times as short as 0.2 s and extending out to 100,000s. Instrumentation development during the initial phase of the project included: (1) assembly and characterization of a NaI(Tl) spectrometer for determining aggregate gamma-ray energy distributions, (2) development and characterization of a beta spectrometer (having excellent gamma-ray rejection) for measuring aggregate beta-particle energy distributions, (3) assembly and characterization of a Compton-suppressed HPGe spectrometer for determining gamma-ray intensities of individual fission products to deduce fission-product yields. Spectral decomposition ...
1997-05-01
ADVANCED CUTTINGS TRANSPORT STUDY
Energy Technology Data Exchange (ETDEWEB)
This is the third quarterly progress report for Year 3 of the ACTS Project. It includes a review of progress made in: (1) Flow Loop construction and development and (2) research tasks during the period of time between Jan. 1, 2002 and Mar. 31, 2002. This report presents a review of progress on the following specific tasks: (a) Design and development of an Advanced Cuttings Transport Facility (Task 3: Addition of a Cuttings Injection/Separation System), (b) Research project (Task 6): ''Study of Cuttings Transport with Foam Under LPAT Conditions (Joint Project with TUDRP)'', (c) Research project (Task 9b): ''Study of Foam Flow Behavior Under EPET Conditions'', (d) Research project (Task 10): ''Study of Cuttings Transport with Aerated Mud Under Elevated Pressure and Temperature Conditions'', (e) Research on three instrumentation tasks to measure: Cuttings concentration and ...
2002-04-30
International Nuclear Information System (INIS)
The High Flux Isotope Reactor (HFIR) located at Oak Ridge National Laboratory is one of the world's most powerful research reactors. In 1996, one year after the demise of the Advanced Neutron Source Project, the U.S. Department of Energy embarked on an aggressive program to upgrade the neutron scattering facilities at the HFIR. These upgrades, which are now in progress, include the installation of larger beam tubes, a high-performance hydrogen cold source, and additional neutron guides and neutron scattering instruments. An extensive analysis effort was performed over the past 4 yr to support the design of the modified beamlines and new user facilities and to assess the impact of the upgrades on the integrity of the existing reactor system. The results of three of these analyses are summarized here. Specifically, results are presented for analyses related to the design of the new cold neutron source (CNS), the assessment of beam tube changes on the anticipated pressure vessel ...
2001-06-17
Safe ageing management of nuclear power plants: An European synthesis
International Nuclear Information System (INIS)
Ageing of nuclear power plants means evolution of material or equipment properties on one side, and evolution of personnel skill and procedure adequacy on the other side, both of which, after a certain time, may not be compatible with the required safety provisions, or with an economic operation of the plant. Repair or replacement of components, as well as change in service conditions for a better compatibility with component reduced capabilities can be used to mitigate ageing effects. The paper summarises the results of a study conducted in this field with the support of the European Commission. It presents: the synthesis of the work done under international auspices, and in the European context; the comparison of ageing management approaches used in several European countries with international recommendations; the summary of the various potential phenomena and their governing parameters, the methods of in-service ageing identification and possible mitigation methods; illustrative ...
2002-11-04
REQUIREMENTS AND GUIDELINES FOR NSLS EXPERIMENTAL BEAM LINE VACUUM SYSTEMS-REVISION B.
Energy Technology Data Exchange (ETDEWEB)
Typical beam lines are comprised of an assembly of vacuum valves and shutters referred to as a ''front end'', optical elements to monochromatize, focus and split the photon beam, and an experimental area where a target sample is placed into the photon beam and data from the interaction is detected and recorded. Windows are used to separate sections of beam lines that are not compatible with storage ring ultra high vacuum. Some experimental beam lines share a common vacuum with storage rings. Sections of beam lines are only allowed to vent up to atmospheric pressure using pure nitrogen gas after a vacuum barrier is established to protect ring vacuum. The front end may only be bled up when there is no current in the machine. This is especially true on the VUV storage ring where for most experiments, windows are not used. For the shorter wavelength, more energetic photons of the x-ray ring, beryllium windows are used at various beam line locations so ...
1999-05-01
Nuclear new-build - Status and Outlook from a German utility perspective
International Nuclear Information System (INIS)
Full text: As one of the Top 5 utilities in Europe, Rheinisch-Westfaelisches Elektrizitaetswerk AG, FWB: RW, RWE, operates a diversified generating capacity of about 45 GW; RWE Power alone generates over 30 GW. Besides a share of approximately 20% nuclear power, a large proportion of the generating base is in lignite and hard coal. RWE has an ambitious, Euro10 bn newbuild program of about 10 GW modern fossil fired plants and further expansion plans across Europe. By 2012, RWE intends to invest between Euro 15 and 20 bn outside Germany.The European Union has a challenging policy to increase the share of renewables, improve energy efficiency, and reduce greenhouse gases by 2020. At the same time, ageing power plants need to be replaced. This requires an enormous investment program across Europe. Nuclear power therefore, as a proven technology with low lifecycle carbon emissions and reasonable lifecycle cost, is a crucial contributor to achieve Europe's 2020 goals. Accordingly, most ...
2009-10-12
Energy Technology Data Exchange (ETDEWEB)
The study examines the isothermal fatigue properties of novel ODS iron-base or nickel-base superalloys at temperatures of 850 C and 1050 C. The materials are different in grain structure and texture, so that particularly the effects of grain structures and textures can be studied. In order to also perform examinations of creep-fatigue interactions, various load cycles are applied. It is shown that the LCF-affected life of the grain structures of both alloy types is determined by the elastic modulus. The cyclic lifetimes determined by the conventional Manson-Coffin method for both alloy types exhibit differences of up to two orders of magnitude. Using the product of the total strain range and the elastic modulus, however, will yield precise life predictions. Under conditions of LCF stress only, the grain structure has no effect on the materials` service life, other than in the case of creep-fatigue, but the grain structure has a decisive influence on the damage ...
1995-12-31
Analysis of the Semileptonic Decay D0 --> anti-K0 pi- mu+ nu
Energy Technology Data Exchange (ETDEWEB)
This thesis describes the analysis of the semileptonic decay D{sup 0} {yields} {bar K}{sup 0} {pi}{sup -} {mu}{sup +}{nu} using FOCUS data. FOCUS is a fixed target experiment at Fermilab that studies the physics of the charm quark. Particles containing charm are produced by photon-gluon fusion from the collision of a photon beam on a BeO target. The experiment is characterized by excellent vertex resolution and particle identification. The spectrometer consists of three systems for track reconstruction (two silicon systems and one multiwire proportional chamber system) and two magnets of opposite polarity. The polarity of the magnet is such that the events of e{sup +}e{sup -} pairs produced in the target (which constitutes the main background) travel through a central opening in the detectors without interactions. Particle momentum is measured from the deflection angle in the magnets. Three multicell Cerenkov counters are used for charged particle identification (for e, {pi}, K, and ...
2004-11-01
Energy Technology Data Exchange (ETDEWEB)
Single crystals of RbBaTaS{sub 4} (1) and K{sub 2}BaTa{sub 2}S{sub 11} (2) were obtained from the reactions of Ta, with in situ formed fluxes of A{sub 2}S{sub 3} (A = K, Rb), BaS, and S at 500 C. Compound 1 crystallizes in the orthorhombic space group Pnma with a = 9.3286(5), b = 7.0391(4), c = 12.4365(7) A, V = 816.6(1) A{sup 3}, Z = 4. Compound 2 crystallizes in the monoclinic space group P2{sub 1}/c with a = 14.5280(10), b = 12.6347(7), c = 17.5148(12) A, {beta} = 94.744(8) , V = 3203.9(4) A{sup 3}, Z = 4. The structure of RbBaTaS{sub 4} (1) consists of isolated tetrahedral [TaS{sub 4}]{sup 3-} anions and Rb{sup +} and Ba{sup 2+} cations. The Ba{sup 2+} cations are surrounded by nine sulfur atoms forming distorted tricapped trigonal prisms, whereas the Rb{sup +} cations are in an irregular environment of ten sulfur atoms. The structure of K{sub 2}BaTa{sub 2}S{sub 11} (2) consists of two different dinuclear [Ta{sub 2}S{sub 11}] units which are separated by Ba{sup 2+} and K{sup +} ...
2010-10-15
ORALLOY (93.15 235U) METAL ANNULI WITH BERYLLIUM CORE
International Nuclear Information System (INIS)
A variety of critical experiments were constructed of enriched uranium metal during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, two were performed that consisted of uranium metal annuli with a solid beryllium metal core. The outer diameter of the annuli was approximately 13 or 15 inches with an inner diameter of 7 inches. The diameter of the core was approximately 7 inches. The critical height ...
Attenuated response to repeated daily ozone exposures in asthmatic subjects
Energy Technology Data Exchange (ETDEWEB)
The development of attenuated response ({open_quotes}tolerance{close_quotes}) to daily ozone (O{sub 3}) exposures in the laboratory is well established in healthy adult volunteers. However, the capability of asthmatics to develop tolerance during multiday ozone exposures in unclear. We exposed 10 adult volunteers with mild asthma to 0.4 ppm O{sub 3} in filtered air for 3 h/d on 5 consecutive d. Two similar filtered-air exposures during the preceding week served as controls. Follow-up O{sub 3} exposures were performed 4 and 7 d after the most recent consecutive exposure. All exposures were performed in an environmental chamber at 31 {degrees}C and 35% relative humidity. The subjects performed moderate exercise (mean ventilation rate of 32 l/min) for 15 min of each half-hour. Responses were measured with spirometry and symptom evaluations before and after each exposure, and a bronchial reactivity test (methacholine challenge) was conducted after each exposure. All response measurements ...
1997-01-01
Energy Technology Data Exchange (ETDEWEB)
Recently, the public has become aware of keywords like ''Quantum computer'' or ''Quantum cryptography''. Regarding their potential application in solid state based quantum information processing and their overall benefit in fundamental research quantum dots have gained more and more public interest. In this context, quantum dots are often referred to as ''artificial atoms'', a term subsuming their physical properties quite nicely and emphasizing the huge potential for further investigations. The basic mechanism to be considered is the theoretical model of a two-level system. A quantum dot itself represents this kind of system quite nicely, provided that only the presence or absence of a single exciton in the ground state of that structure is regarded. This concept can also be expanded to the presence of two excitons (bi-exciton). Transitions between the relevant levels can be ...
2009-10-15
Second international symposium on nuclear power plant life management. Book of extended synopses
International Nuclear Information System (INIS)
The world's fleet of nuclear power plants is, on average, more than 20 years old. Even though the design life of a nuclear power plant is typically 30-40 years, it is quite feasible that many plants will be able to operate in excess of their design lives, provided that nuclear power plant engineers demonstrate by analysis, trending, equipment and system upgrades, increased vigilance, testing and ageing management that the plant will operate safely. In the operation of nuclear power plants, safety should be always the prime consideration. Plant operators and regulators must always ensure that plant safety is maintained, and where possible enhanced, during a plant's operating lifetime. Nuclear power plant life management (PLiM) has gained increased attention over the past decade, and effective ageing management of systems, structures and components (SSCs) is a key element in PLiM for the safe and reliable long term operation of nuclear power plants. A PLiM programme ...
2007-10-15
Review of Constructed Subsurface Flow vs. Surface Flow Wetlands
Energy Technology Data Exchange (ETDEWEB)
The purpose of this document is to use existing documentation to review the effectiveness of subsurface flow and surface flow constructed wetlands in treating wastewater and to demonstrate the viability of treating effluent from Savannah River Site outfalls H-02 and H-04 with a subsurface flow constructed wetland to lower copper, lead and zinc concentrations to within National Pollutant Discharge Elimination System (NPDES) Permit limits. Constructed treatment wetlands are engineered systems that have been designed and constructed to use the natural functions of wetlands for wastewater treatment. Constructed wetlands have significantly lower total lifetime costs and often lower capital costs than conventional treatment systems. The two main types of constructed wetlands are surface flow and subsurface flow. In surface flow constructed wetlands, water flows above ground. Subsurface flow constructed wetlands are designed to keep the water level below the top of the ...
2004-09-01
Performance Assessment Monitoring Plan for the Hanford Site Low-Level Burial Grounds
Energy Technology Data Exchange (ETDEWEB)
The U.S. Department of Energy Order 435.1, Radioactive Waste Management, requires a disposal authorization statement authorizing operation (or continued operation) for low-level waste disposal facilities. In fulfillment of these requirements, a disposal authorization statement was issued on October 25, 1999, authorizing the Hanford Site to transfer, receive, possess, and dispose of low-level radioactive waste at the 200 East Area burial grounds and the 200 West Area burial grounds. One of the conditions is that monitoring plans for the 200 East Area and 200 West Area low-level burial grounds be written and approved by the Richland Operations Office. As a result of a record of decision for the Hanford Site Solid Waste Program and acceptance of the Hanford Site Solid Waste Environmental Impact Statement, the use of the low-level burial ground (LLBG) as a disposal facility for low-level and mixed low-level wastes has been restricted to lined trenches and the Navy reactor-compartment ...
2006-03-30
Energy Technology Data Exchange (ETDEWEB)
The US National Energy Policy of 2001 advocated the development of advanced fuel and fuel cycle technologies that are cleaner, more efficient, less waste-intensive, and more proliferation resistant. The need for advanced fuel development is emphasized in on-going DOE-supported programs, e.g., Global Nuclear Energy Initiative (GNEI), Advanced Fuel Cycle Initiative (AFCI), and GEN-IV Technology Development. The Directorates of Energy & Environment (E&E) and Chemistry & Material Sciences (C&MS) at Lawrence Livermore National Laboratory (LLNL) are interested in advanced fuel research and manufacturing using its multi-disciplinary capability and facilities to support a design concept of a small, secure, transportable, and autonomous reactor (SSTAR). The E&E and C&MS Directorates co-sponsored this Laboratory Directed Research & Development (LDRD) Project on Mono-Uranium Nitride Fuel Development for SSTAR and Space Applications. In fact, three out ...
2006-02-09
Aging of Pentaerythritol Tetranitrate (PETN)
Pentaerythritol tetranitrate (PETN) is a relatively sensitive explosive used in many electroexplosive devices as well as in medicine. Of primary interest to LLNL is its use in items such as exploding bridgewire (EBW) detonators and exploding bridge foil initiators (EFI). In these devices the crystalline powder is pressed into a granular, low-density compact that can be initiated by an exploding wire or foil. The long-term stability of this pressed compact is of interest to weapon stockpile lifetime prediction studies. Key points about potential aging mechanisms can be summarized as follows: (1) There are a number of factors that can contribute to PETN instability. These include particle size, polymorphic phase transitions, crystal structure, impurities, moisture, occlusions, chemical incompatibility and biological (microorganism) action. of these factors the most important for long-term aging of high surface area powders used in detonators appears to be that of ...
2009-04-22
European Space Agency announces contest to "Name the Cluster Quartet"
1. Contest rules The European Space Agency (ESA) is launching a public competition to find the most suitable names for its four Cluster II space weather satellites. The quartet, which are currently known as flight models 5, 6, 7 and 8, are scheduled for launch from Baikonur Space Centre in Kazakhstan in June and July 2000. Professor Roger Bonnet, ESA Director of Science Programme, announced the competition for the first time to the European Delegations on the occasion of the Science Programme Committee (SPC) meeting held in Paris on 21-22 February 2000. The competition is open to people of all the ESA member states (*). Each entry should include a set of FOUR names (places, people, or things from history, mythology, or fiction, but NOT living persons). Contestants should also describe in a few sentences why their chosen names would be appropriate for the four Cluster II satellites. The winners will be those which are considered most suitable and relevant for the Cluster II mission. ...
2000-02-01
40th Anniversary of the First Proton-Proton Collisions in the CERN Intersecting Storage Rings (ISR)
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Final Scientific EFNUDAT Workshop
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